File name: Pandora122s1_Downsview_20230211_L2Fit_fwvt1c1d20220801p1-8.txt File generation date: 20260318T011349.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora122_OF_v6d20161030.txt Instrument calibration file used: Pandora122s1_CF_v1d20220801.txt Level 1 file used: Pandora122s1_Downsview_20230211_L1_smca1c1d20220801p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230211 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.1089 492.2301 492.3513 492.4725 492.5936 492.7148 492.8359 492.9570 493.0781 493.1992 493.3202 493.4412 493.5623 493.6833 493.8043 493.9252 494.0462 494.1671 494.2880 494.4090 494.5298 494.6507 494.7716 494.8924 495.0132 495.1340 495.2548 495.3756 495.4963 495.6171 495.7378 495.8585 495.9792 496.0998 496.2205 496.3411 496.4617 496.5823 496.7029 496.8235 496.9440 497.0646 497.1851 497.3056 497.4261 497.5465 497.6670 497.7874 497.9078 498.0282 498.1486 498.2690 498.3893 498.5096 498.6300 498.7502 498.8705 498.9908 499.1110 499.2313 499.3515 499.4717 499.5918 499.7120 499.8321 499.9523 500.0724 500.1925 500.3125 500.4326 500.5526 500.6726 500.7927 500.9126 501.0326 501.1526 501.2725 501.3924 501.5123 501.6322 501.7521 501.8719 501.9918 502.1116 502.2314 502.3512 502.4709 502.5907 502.7104 502.8301 502.9498 503.0695 503.1892 503.3088 503.4284 503.5481 503.6677 503.7872 503.9068 504.0263 504.1459 504.2654 504.3849 504.5043 504.6238 504.7432 504.8627 504.9821 505.1014 505.2208 505.3402 505.4595 505.5788 505.6981 505.8174 505.9367 506.0559 506.1752 506.2944 506.4136 506.5328 506.6519 506.7711 506.8902 507.0093 507.1284 507.2475 507.3665 507.4856 507.6046 507.7236 507.8426 507.9616 508.0805 508.1995 508.3184 508.4373 508.5562 508.6751 508.7939 508.9128 509.0316 509.1504 509.2692 509.3879 509.5067 509.6254 509.7441 509.8628 509.9815 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-247: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 248-397: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20230211T125513.5Z 8442.538351 272 1 18.80 2 85.35 114.47 71.03 233.78 0.00 1 0.00 1 0 15 3.005e-03 2.993e-03 1.166e-04 1.165e-04 2.850747e+03 6.797909e+00 2.094115e+02 -6.000000e+00 1.615731e+02 271.77 -2.00 20.00 -2.00 505.32 0.00e+00 1.470512e-03 3.143132e-06 8.278334e-05 -6.000000e+00 8.243705e-05 271.77 -2.00 20.00 -2.00 500.70 0.00e+00 1.053052e+00 2.291825e-03 2.758242e-02 -6.000000e+00 6.003154e-02 224.48 -2.00 3.57 -2.00 502.26 0.00e+00 10.375 0.022 489.00 513.00 1 -7.5994e+00 1.7499e-04 1.5099e-02 -6.0000e+00 4.5882e-03 -1.2103e-02 4.4830e-05 1.0050e-03 -6.0000e+00 1.1896e-03 8.3720e+02 2.9574e-04 1.1853e-05 4.2973e-05 -6.0000e+00 3.1421e-04 -1.1299e-03 -2.4531e-04 10 0 0 10 0 0 96.70 21.61 1.55 -0.00113 0.00092 605 114 1 4 0 31.062 26.73 20.00 21.61 -499 -321 -160 108 205 410 627 486 499 447 200 128 41 -95 -210 -230 -88 11 162 48 -8 161 214 252 398 333 32 17 32 -365 -406 -205 -34 131 80 -151 -98 -129 -119 -166 -9 242 279 313 217 317 210 47 -174 -363 -669 -847 -778 -550 -197 0 -4 -4 45 221 349 459 356 208 58 -107 -258 -311 -107 -182 -407 -375 -301 -224 -17 -10 -54 -85 -111 -362 -429 -277 -197 -134 -101 -212 -130 -93 -187 -110 14 48 168 269 211 126 -62 -171 -211 -489 -605 -513 -424 -308 -298 -444 -340 -239 -234 -92 8 112 278 466 574 559 559 555 451 332 398 418 422 487 438 115 221 261 92 167 190 -125 -212 -282 -263 -200 -143 -222 -63 58 87 198 339 245 107 17 -19 -174 -329 -334 -473 -304 -154 105 203 408 633 496 508 451 199 128 41 -92 -205 -225 -87 11 164 49 -8 163 218 257 408 342 33 18 32 -363 -397 -201 -34 132 82 -155 -101 -130 -121 -168 -10 243 284 322 223 325 215 48 -175 -362 -662 -822 -760 -536 -194 0 -4 -4 45 223 353 467 363 212 58 -107 -259 -308 -106 -179 -398 -368 -299 -222 -17 -10 -53 -82 -107 -349 -416 -270 -192 -131 -100 -209 -128 -92 -185 -109 14 48 168 269 211 124 -60 -166 -203 -465 -577 -492 -414 -307 -299 -445 -338 -238 -232 -91 8 114 282 477 583 572 575 570 460 334 401 416 420 487 441 116 224 263 93 168 190 -123 -209 -278 -260 -199 -143 -226 -64 59 89 204 350 255 111 18 -20 -174 -330 -335 SQ 20230211T125532.5Z 8442.538571 272 2 18.80 2 85.29 114.53 71.07 233.85 0.00 1 0.00 1 0 15 3.040e-03 3.025e-03 1.150e-04 1.149e-04 2.825826e+03 6.702645e+00 2.070112e+02 -6.000000e+00 1.634272e+02 271.77 -2.00 20.00 -2.00 505.32 0.00e+00 1.476434e-03 3.099414e-06 8.314389e-05 -6.000000e+00 8.338285e-05 271.77 -2.00 20.00 -2.00 500.70 0.00e+00 1.046429e+00 2.259588e-03 2.747106e-02 -6.000000e+00 6.071945e-02 224.48 -2.00 3.57 -2.00 502.26 0.00e+00 10.292 0.021 489.00 513.00 1 -7.6174e+00 1.7251e-04 1.4974e-02 -6.0000e+00 4.6408e-03 -1.1985e-02 4.4199e-05 9.9657e-04 -6.0000e+00 1.2032e-03 8.6262e+02 2.4152e-04 1.1690e-05 4.2738e-05 -6.0000e+00 3.1781e-04 -2.0591e-03 -2.3835e-04 10 0 0 10 0 0 97.08 21.61 1.54 -0.00206 -0.00038 605 114 1 4 0 31.062 26.73 20.00 21.61 -527 -350 -148 115 203 430 613 490 511 447 163 119 35 -85 -184 -200 -59 34 140 57 -19 140 210 256 430 337 69 30 41 -346 -425 -202 -49 102 58 -127 -111 -114 -89 -183 6 228 282 329 227 287 189 21 -190 -361 -659 -869 -805 -567 -195 -4 -1 35 73 244 366 488 366 190 33 -118 -268 -309 -94 -197 -405 -388 -292 -215 -60 -1 -51 -72 -125 -341 -437 -278 -210 -137 -99 -221 -147 -109 -192 -108 12 34 149 272 233 143 -84 -194 -214 -490 -607 -534 -439 -293 -318 -454 -312 -246 -220 -90 -7 101 304 459 571 582 572 559 441 355 437 425 436 495 442 109 206 242 99 186 181 -78 -220 -259 -262 -184 -157 -203 -57 92 90 183 331 245 83 -7 -42 -165 -327 -348 -497 -331 -142 112 200 433 617 498 519 450 162 119 34 -84 -182 -195 -59 34 141 58 -19 142 213 261 441 345 71 30 40 -342 -415 -198 -49 103 59 -130 -113 -116 -91 -185 6 232 286 338 232 294 193 21 -191 -360 -650 -854 -785 -551 -194 -4 -1 36 74 246 370 495 373 193 33 -120 -268 -305 -93 -192 -395 -380 -289 -212 -60 -1 -50 -70 -121 -333 -423 -271 -207 -134 -98 -220 -145 -107 -189 -107 12 34 150 274 233 143 -82 -188 -206 -465 -578 -511 -429 -291 -318 -455 -314 -244 -218 -89 -7 102 308 468 579 594 587 574 449 357 439 422 433 494 444 110 208 244 100 187 181 -78 -217 -254 -258 -183 -158 -207 -58 94 93 188 341 254 86 -7 -43 -167 -327 -349 SQ 20230211T125551.4Z 8442.538789 272 3 18.80 2 85.24 114.58 71.12 233.91 0.00 1 0.00 1 0 15 2.997e-03 2.983e-03 1.138e-04 1.137e-04 2.826103e+03 6.629175e+00 2.071104e+02 -6.000000e+00 1.611388e+02 271.77 -2.00 20.00 -2.00 505.32 0.00e+00 1.454055e-03 3.065629e-06 8.190909e-05 -6.000000e+00 8.221549e-05 271.77 -2.00 20.00 -2.00 500.70 0.00e+00 1.031619e+00 2.236520e-03 2.738563e-02 -6.000000e+00 5.987056e-02 224.48 -2.00 3.57 -2.00 502.26 0.00e+00 10.212 0.021 489.00 513.00 1 -7.6241e+00 1.7076e-04 1.4848e-02 -6.0000e+00 4.5759e-03 -1.1761e-02 4.3750e-05 9.9096e-04 -6.0000e+00 1.1864e-03 8.7934e+02 3.2761e-04 1.1562e-05 4.2609e-05 -6.0000e+00 3.1337e-04 -4.0611e-03 -2.2812e-04 10 0 0 10 0 0 92.65 21.61 1.55 -0.00406 -0.00179 605 114 1 4 0 31.062 26.73 20.00 21.61 -527 -325 -139 99 212 405 608 466 489 454 177 105 30 -82 -201 -207 -58 1 127 76 -34 143 196 264 388 348 56 23 33 -327 -394 -202 -50 147 69 -128 -106 -108 -91 -157 -5 228 294 351 236 302 193 35 -185 -371 -674 -842 -802 -545 -217 -5 -18 43 75 251 360 463 352 182 54 -118 -289 -325 -125 -185 -394 -353 -296 -210 -35 12 -55 -106 -126 -338 -425 -241 -210 -119 -79 -207 -135 -107 -204 -112 14 68 123 246 221 137 -60 -187 -204 -468 -595 -522 -447 -290 -290 -454 -313 -238 -213 -116 -2 95 303 444 547 582 588 586 445 348 406 421 430 486 424 100 202 245 115 180 190 -94 -225 -272 -263 -186 -137 -233 -83 91 92 160 334 240 79 -5 -29 -160 -332 -336 -500 -309 -134 97 210 404 616 470 491 458 176 105 30 -80 -196 -203 -57 1 129 77 -35 146 200 267 394 354 57 23 33 -326 -387 -199 -50 149 71 -132 -108 -110 -92 -159 -5 230 300 357 243 311 197 35 -187 -372 -668 -818 -774 -532 -214 -5 -18 43 76 254 366 472 360 186 55 -118 -290 -322 -124 -182 -386 -347 -290 -209 -35 12 -54 -103 -122 -327 -413 -236 -205 -117 -78 -204 -133 -105 -202 -112 14 69 123 246 222 135 -59 -182 -194 -447 -569 -502 -438 -289 -291 -456 -311 -237 -211 -115 -2 96 308 449 557 596 598 596 456 351 409 420 429 487 428 102 205 248 115 182 190 -93 -223 -268 -261 -185 -137 -234 -85 94 95 165 345 249 81 -5 -29 -160 -333 -338 SQ 20230211T130955.2Z 8442.548556 275 1 6.50 2 82.96 117.13 73.20 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