File name: Pandora122s1_Downsview_20240618_L2Fit_fout2c2d20240229p1-8.txt File generation date: 20260427T053021.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora122_OF_v2d20240108.txt Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt Level 1 file used: Pandora122s1_Downsview_20240618_L1_smca1c2d20240229p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240618 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240618T132027.4Z 8935.555873 296 1 12.66 2 52.45 92.43 152.96 329.20 0.00 1 0.00 1 0 17 8.184e-03 5.707e-03 1.341e-03 7.153e-04 2.323174e-01 3.695400e-04 2.822577e-03 -6.000000e+00 4.748244e-03 232.91 -2.00 3.57 -2.00 315.96 0.00e+00 4.775494e-04 3.801421e-05 4.881301e-05 -6.000000e+00 2.068677e-04 284.43 -2.00 20.00 -2.00 315.26 0.00e+00 1.637 0.000 302.00 328.00 3 2.5524e+00 9.6615e-04 2.0365e-02 -6.0000e+00 1.1946e-02 2.2003e-03 1.0717e-03 1.2336e-02 -6.0000e+00 1.2900e-02 -4.7476e-03 6.1687e-04 5.9708e-03 -6.0000e+00 7.6551e-03 -1.7453e-03 2.8483e-04 1.6630e-03 -6.0000e+00 3.2642e-03 6.3240e-03 2.6474e-04 1.9813e-05 1.8536e-05 -6.0000e+00 2.1664e-04 4.2076e-02 0.0000e+00 12 1 1 12 1 1 99.79 22.36 0.22 0.04208 0.04407 86 206 1 5 0 145.500 27.05 20.00 22.36 28.31 1.5 1047.48 4 21 -493 -2612 -3386 -672 -701 1407 -153 -502 -2116 -1149 -687 -634 279 -490 30 463 556 1036 75 991 833 654 358 514 72 -970 90 915 898 1364 606 -1403 -2708 -2068 -1751 -701 -325 -302 -399 -408 -137 -144 -132 -457 -703 -450 -823 444 771 997 1062 890 1047 791 659 295 287 606 955 1440 1614 1243 27 -232 -507 -285 428 161 389 134 180 162 -288 -307 -1085 -574 -656 -652 -950 -1571 -1524 -1367 -717 -478 43 330 515 266 125 5 -238 -88 -83 86 802 619 179 -165 -389 -607 -350 -454 -825 -805 -606 -279 178 225 280 97 148 -216 50 237 384 476 262 -27 66 356 538 536 608 409 736 601 419 139 -5 -279 -120 -64 -74 11 169 -26 -127 -387 -436 -672 1 5 -113 -551 -697 -134 -140 312 -38 -126 -526 -299 -202 -197 97 -183 11 182 212 405 30 385 337 280 161 236 32 -403 37 381 374 608 292 -672 -1217 -949 -849 -376 -197 -207 -275 -291 -99 -104 -95 -328 -492 -322 -579 315 553 759 808 708 846 654 551 243 233 496 820 1270 1463 1171 24 -200 -432 -244 388 157 386 136 179 160 -272 -272 -887 -462 -580 -621 -963 -1664 -1620 -1535 -828 -564 52 411 628 318 142 5 -250 -89 -92 101 998 808 228 -209 -474 -714 -409 -553 -1043 -1062 -804 -385 249 323 414 141 208 -289 64 294 490 623 358 -39 95 496 750 708 795 526 917 757 569 193 -7 -392 -173 -94 -116 17 270 -43 -203 -600 -675 -1010 SS 20240618T132552.0Z 8935.559630 299 1 30.01 2 51.48 93.40 153.43 331.69 0.00 1 0.00 1 0 17 8.007e-03 5.477e-03 5.271e-04 2.500e-04 2.287062e-01 1.284483e-04 2.769833e-03 -6.000000e+00 4.645470e-03 232.91 -2.00 3.57 -2.00 316.31 0.00e+00 3.590990e-04 1.431771e-05 6.051865e-05 -6.000000e+00 2.023978e-04 284.43 -2.00 20.00 -2.00 315.57 0.00e+00 1.602 0.000 302.00 328.00 3 1.2508e+00 3.3747e-04 1.9978e-02 -6.0000e+00 1.1687e-02 -2.3595e-03 3.7539e-04 1.2143e-02 -6.0000e+00 1.2621e-02 -6.1372e-03 2.1757e-04 5.8745e-03 -6.0000e+00 7.4896e-03 -1.0634e-03 1.0206e-04 1.6214e-03 -6.0000e+00 3.1933e-03 2.4258e-02 1.9380e-04 6.9647e-06 1.8317e-05 -6.0000e+00 2.1198e-04 4.2806e-02 0.0000e+00 11 1 0 11 16 0 97.10 22.36 0.22 0.04281 0.04426 837 837 1 5 0 35.850 27.05 19.99 22.36 28.55 1.5 1049.86 -117 -138 -684 -2682 -3113 -1308 -187 750 362 -1033 -1788 -1271 -677 -645 -16 -325 -50 479 677 848 -5 671 892 615 476 283 84 -726 -267 792 1091 1448 724 -1460 -2616 -2182 -1569 -855 -129 -393 -409 -394 -243 -331 -174 -419 -645 -640 -726 417 806 907 1016 940 1011 865 705 366 311 629 1009 1474 1695 1109 -12 -375 -534 -223 449 229 326 117 159 95 -322 -260 -932 -635 -477 -756 -904 -1501 -1468 -1284 -763 -379 -14 443 471 354 98 -62 -166 -112 -51 99 752 614 139 -156 -447 -574 -292 -504 -810 -778 -563 -367 176 179 245 53 72 -149 125 233 382 328 256 -33 96 308 486 490 576 414 785 609 332 201 -31 -209 -196 -124 -28 -7 216 37 -106 -369 -416 -675 -22 -27 -136 -487 -507 -227 -32 144 76 -224 -381 -284 -170 -185 -5 -103 -16 160 233 301 -2 237 326 239 194 118 34 -273 -94 278 409 581 314 -629 -1056 -902 -729 -435 -78 -252 -278 -276 -174 -236 -124 -297 -444 -427 -475 276 568 678 749 723 791 692 570 293 244 497 837 1243 1538 1046 -11 -327 -439 -184 387 223 319 117 156 93 -290 -222 -734 -493 -406 -687 -914 -1564 -1601 -1401 -894 -448 -18 551 576 427 109 -66 -173 -119 -55 113 947 800 185 -197 -551 -657 -332 -622 -1024 -1026 -776 -501 253 260 366 78 104 -207 160 304 487 446 358 -48 141 440 670 672 752 538 989 807 450 275 -43 -300 -289 -184 -44 -11 344 60 -170 -599 -652 -1027 SS 20240618T133106.2Z 8935.563266 302 1 30.00 2 50.54 94.36 153.86 334.17 0.00 1 0.00 1 0 17 7.936e-03 5.506e-03 5.039e-04 2.481e-04 2.235224e-01 1.277611e-04 2.716858e-03 -6.000000e+00 4.604166e-03 232.91 -2.00 3.57 -2.00 316.20 0.00e+00 3.581918e-04 1.384914e-05 5.776010e-05 -6.000000e+00 2.005994e-04 284.43 -2.00 20.00 -2.00 315.47 0.00e+00 1.570 0.000 302.00 328.00 3 1.2833e+00 3.3533e-04 1.9567e-02 -6.0000e+00 1.1583e-02 -2.2332e-03 3.7264e-04 1.1887e-02 -6.0000e+00 1.2509e-02 -5.3935e-03 2.1543e-04 5.7517e-03 -6.0000e+00 7.4231e-03 -1.1409e-03 1.0041e-04 1.5861e-03 -6.0000e+00 3.1649e-03 2.4436e-02 1.9810e-04 6.9247e-06 1.8092e-05 -6.0000e+00 2.1010e-04 4.2888e-02 0.0000e+00 11 1 0 11 16 0 79.08 22.36 0.22 0.04289 0.04438 801 801 1 5 0 37.440 27.05 20.00 22.36 29.09 1.6 1054.91 -46 95 -912 -2647 -3060 -1375 -328 823 604 -913 -1744 -1260 -623 -552 73 -344 25 553 595 852 89 615 840 568 530 219 151 -628 -219 780 979 1441 666 -1437 -2609 -2145 -1587 -902 -123 -461 -383 -414 -296 -295 -150 -331 -587 -693 -714 416 768 918 1063 973 978 824 635 351 337 594 947 1390 1666 1062 13 -382 -479 -252 493 208 361 116 187 94 -310 -289 -1012 -628 -464 -720 -845 -1494 -1445 -1280 -743 -395 -9 477 433 336 89 -58 -197 -85 -17 82 743 612 179 -156 -454 -577 -323 -486 -808 -796 -549 -380 144 202 242 79 62 -169 86 196 363 393 239 -31 132 253 520 498 610 419 815 618 359 227 -75 -232 -225 -122 -24 27 236 76 -91 -375 -462 -702 -9 20 -191 -507 -525 -252 -59 166 133 -208 -390 -295 -164 -165 22 -113 8 192 213 315 33 226 320 229 223 95 63 -244 -79 283 379 596 297 -637 -1083 -911 -758 -472 -71 -303 -267 -298 -204 -203 -110 -240 -413 -474 -477 281 553 656 798 762 780 671 523 285 269 478 801 1194 1537 1019 12 -319 -399 -211 430 205 358 118 186 93 -283 -250 -807 -493 -399 -660 -862 -1570 -1588 -1408 -877 -471 -12 599 534 409 99 -61 -195 -86 -18 94 893 800 238 -199 -562 -663 -368 -603 -1027 -1055 -724 -522 208 295 363 115 89 -224 110 243 463 534 335 -45 194 362 718 684 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