File name: Pandora122s1_Downsview_20240627_L2Fit_fout2c2d20240229p1-8.txt File generation date: 20260427T053217.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora122_OF_v2d20240108.txt Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt Level 1 file used: Pandora122s1_Downsview_20240627_L1_smca1c2d20240229p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T102232.0Z 8944.432315 260 1 29.60 2 83.92 63.35 51.85 184.58 0.00 1 0.00 1 0 17 5.971e-01 2.686e-02 4.299e-01 1.703e-02 1.065752e+00 1.104441e-02 1.203780e-02 -6.000000e+00 3.667563e-01 232.96 -2.00 3.57 -2.00 322.47 0.00e+00 -2.358925e-02 7.317074e-03 2.199276e-03 -6.000000e+00 1.990592e-02 285.24 -2.00 20.00 -2.00 322.05 0.00e+00 8.440 0.012 302.00 328.00 3 1.1095e+00 4.9622e-02 1.0471e-01 -6.0000e+00 9.2394e-01 1.2341e+00 7.1675e-02 6.9621e-02 -6.0000e+00 1.0061e+00 -1.6965e+00 6.4748e-02 3.5150e-02 -6.0000e+00 5.9035e-01 6.6590e-01 2.8504e-02 1.8163e-02 -6.0000e+00 2.5525e-01 1.6735e-05 1.3310e-05 4.7960e-04 2.8088e-04 -6.0000e+00 1.8189e-02 4.1365e-02 0.0000e+00 12 8 8 10 0 0 26.08 22.33 0.84 0.04136 0.04147 26 26 1 5 0 1138.000 27.05 19.99 22.33 18.85 1.8 975.88 900000 -63647 -76809 900000 -94421 900000 -112395 900000 -174252 58705 900000 900000 -55267 900000 900000 900000 63057 61015 -17426 -21126 -82779 900000 900000 900000 900000 900000 -10321 900000 267597 900000 -52814 900000 -40253 900000 900000 34884 900000 900000 73410 31073 154190 65527 900000 900000 900000 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1205 1326 1206 713 3380 -1992 -1481 -1072 -6062 3764 2247 -3521 -235 580 -2931 73 -749 -929 2783 -3549 -4637 2578 -1534 -2861 -4093 3705 -6004 -3481 -2456 5154 -2315 284 -196 356 64 -23 -707 2736 -2082 2490 3911 2268 4400 -620 -1000 2019 2514 2412 -813 -281 155 -324 416 1383 -1458 -1412 765 431 -3886 311 SS 20240627T103326.1Z 8944.439885 263 1 29.91 2 82.15 65.13 52.01 187.94 0.00 1 0.00 1 0 17 8.401e-01 1.354e-02 3.503e-01 4.941e-03 9.198976e-01 2.833813e-03 1.060853e-02 -6.000000e+00 4.905617e-01 232.96 -2.00 3.57 -2.00 321.91 0.00e+00 6.519648e-04 1.687419e-03 7.126441e-03 -6.000000e+00 2.199057e-02 285.24 -2.00 20.00 -2.00 321.43 0.00e+00 6.822 0.006 302.00 328.00 3 8.7659e-01 1.1244e-02 9.2538e-02 -6.0000e+00 1.2341e+00 3.1688e-01 1.7854e-02 7.2261e-02 -6.0000e+00 1.3327e+00 -4.3658e-01 1.9327e-02 3.5040e-02 -6.0000e+00 7.9223e-01 1.6776e-01 8.6071e-03 9.2077e-03 -6.0000e+00 3.3910e-01 1.1632e-04 7.4987e-06 1.2681e-04 1.5898e-04 -6.0000e+00 2.2350e-02 4.1198e-02 0.0000e+00 12 8 8 10 0 0 36.36 22.32 0.40 0.04120 0.04125 76 76 1 5 0 393.510 27.05 19.99 22.32 19.38 1.8 979.07 -322057 -124251 -220070 -347762 -293241 -237802 -319996 -218220 -143372 -134718 -213485 900000 -242665 900000 -61126 900000 -146240 -109046 -45346 -76977 -52018 900000 87986 -94638 159606 80115 -112696 7366 -133988 900000 -35629 110606 -4589 -37858 159877 -50614 103013 12425 -12578 -2783 -13150 25620 32624 77982 17442 -3349 -1022 -1146 15881 2830 5916 16794 13072 24917 585 23164 11597 18366 -319 16203 9713 20 9520 11930 19398 5091 9451 9570 9889 9939 5495 7713 785 7058 1215 738 5172 -739 2524 -262 -724 -1741 -3035 -965 -883 1307 1219 288 203 -1527 -42 -2068 -1377 -2908 -2081 -352 -746 358 -414 -123 -1207 -2723 -1777 -2006 -406 -2980 -1093 -522 -12 269 -119 905 -697 -104 -153 717 744 533 440 250 754 966 872 796 -129 635 -223 874 493 358 -279 -484 -57 -624 325 -262 255 74 164 -45 -566 -218 -3523 -598 -1059 -5161 -2566 -1249 -4341 -1241 -690 -648 -1588 900000 -4141 900000 -294 900000 -2304 -1336 -317 -775 -410 900000 424 -1449 768 386 -2367 45 -3518 900000 -546 532 -74 -878 770 -1329 744 250 -407 -97 -570 807 999 1536 641 -157 -49 -60 764 161 380 1098 991 1849 59 1970 1130 1628 -33 1391 951 2 1264 1756 2747 835 1558 1731 1922 2215 1375 1910 198 1526 247 149 1006 -157 633 -82 -271 -753 -1442 -479 -435 665 644 155 115 -829 -21 -1027 -701 -1701 -1336 -264 -664 361 -412 -126 -1128 -2273 -1388 -1658 -354 -2803 -1086 -571 -14 363 -179 1331 -1042 -160 -225 1044 1129 857 694 392 1189 1441 1262 1114 -177 834 -303 1348 842 698 -566 -1059 -133 -1586 826 -687 674 195 419 -113 -1322 -478 SS 20240627T104348.5Z 8944.447089 266 1 29.98 2 80.44 66.81 52.26 191.11 0.00 1 0.00 1 0 17 6.246e-01 9.165e-03 2.130e-01 2.296e-03 7.994737e-01 1.266187e-03 9.137555e-03 -6.000000e+00 3.644237e-01 232.96 -2.00 3.57 -2.00 321.37 0.00e+00 4.144360e-04 6.551896e-04 3.408045e-03 -6.000000e+00 1.589417e-02 285.24 -2.00 20.00 -2.00 320.83 0.00e+00 5.735 0.004 302.00 328.00 3 7.5422e-01 4.4902e-03 7.3457e-02 -6.0000e+00 9.1852e-01 6.6887e-02 6.6425e-03 4.9867e-02 -6.0000e+00 9.9243e-01 -1.0403e-01 7.0860e-03 2.5556e-02 -6.0000e+00 5.8656e-01 3.5123e-02 3.2837e-03 7.2547e-03 -6.0000e+00 2.4948e-01 4.1321e-04 2.1733e-04 5.9224e-05 9.9171e-05 -6.0000e+00 1.6748e-02 4.0426e-02 0.0000e+00 11 8 0 10 0 0 33.58 22.31 0.27 0.04043 0.04206 154 154 1 5 0 194.630 26.94 20.00 22.31 19.71 1.8 982.01 -122979 -240246 -208288 -306431 38460 -80847 -279817 900000 -244139 -140430 -192511 -75613 -149060 -140897 39179 -87978 -23939 -77248 -16151 -62995 -84875 126137 -94503 -19548 -38816 -33034 -14781 -66946 -9726 -6260 7442 3138 -21480 -17980 -2162 -7918 -14597 -522 -7160 5641 5173 -978 20274 4459 2143 -3795 7594 5009 -3524 6227 2358 10573 4939 6430 5582 4859 6364 2720 2245 890 2454 5015 4723 5765 3775 2581 977 721 2987 1608 2651 968 1663 1769 114 -343 -1730 550 -1343 103 -1287 -1328 -1487 -1581 -14 -476 923 256 649 138 -728 -352 -2096 -888 -922 76 340 264 467 -631 -484 -1657 -507 -717 -1486 -833 -1183 -129 47 350 324 329 147 -391 94 173 502 367 160 97 102 505 729 441 170 -14 564 481 354 53 -106 -427 -478 -289 -162 75 270 328 153 -164 -197 -415 -275 -1823 -1246 -4440 86 -181 -3671 900000 -3099 -732 -1818 -288 -1523 -1738 110 -1010 -172 -1037 -133 -854 -1441 294 -1996 -233 -606 -519 -198 -1417 -126 -92 120 63 -628 -525 -53 -214 -484 -19 -333 275 281 -60 1076 277 139 -269 506 364 -298 535 240 1118 606 849 790 727 963 419 337 135 392 887 962 1295 884 606 240 191 893 551 964 363 599 592 35 -98 -495 168 -490 44 -639 -739 -885 -993 -9 -331 659 186 462 94 -471 -219 -1342 -616 -733 69 348 299 545 -720 -511 -1608 -469 -698 -1538 -893 -1345 -156 62 513 510 531 236 -611 142 259 773 590 267 161 165 787 1109 654 247 -20 803 751 615 101 -213 -900 -1053 -670 -391 183 670 817 372 -382 -439 -894 SS 20240627T105224.8Z 8944.453065 271 1 30.03 2 79.00 68.19 52.55 193.72 0.00 1 0.00 1 0 17 4.011e-01 5.514e-03 7.658e-02 1.390e-03 7.171610e-01 7.508476e-04 8.185761e-03 -6.000000e+00 2.328182e-01 232.96 -2.00 3.57 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