File name: Pandora122s1_Downsview_20240812_L2Fit_fout2c2d20240229p1-8.txt File generation date: 20240813T052742.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora122_OF_v2d20240108.txt Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt Level 1 file used: Pandora122s1_Downsview_20240812_L1_smca1c2d20240229p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20240812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.0696 305.2108 305.3519 305.4931 305.6342 305.7753 305.9165 306.0576 306.1986 306.3397 306.4808 306.6218 306.7629 306.9039 307.0449 307.1859 307.3269 307.4679 307.6089 307.7499 307.8908 308.0317 308.1727 308.3136 308.4545 308.5954 308.7363 308.8771 309.0180 309.1589 309.2997 309.4405 309.5813 309.7221 309.8629 310.0037 310.1445 310.2852 310.4260 310.5667 310.7074 310.8481 310.9888 311.1295 311.2702 311.4109 311.5515 311.6922 311.8328 311.9734 312.1140 312.2546 312.3952 312.5358 312.6763 312.8169 312.9574 313.0980 313.2385 313.3790 313.5195 313.6600 313.8004 313.9409 314.0813 314.2218 314.3622 314.5026 314.6430 314.7834 314.9238 315.0641 315.2045 315.3448 315.4852 315.6255 315.7658 315.9061 316.0464 316.1866 316.3269 316.4671 316.6074 316.7476 316.8878 317.0280 317.1682 317.3084 317.4486 317.5887 317.7289 317.8690 318.0091 318.1492 318.2893 318.4294 318.5695 318.7096 318.8496 318.9897 319.1297 319.2697 319.4097 319.5497 319.6897 319.8297 319.9696 320.1096 320.2495 320.3894 320.5294 320.6693 320.8092 320.9490 321.0889 321.2288 321.3686 321.5084 321.6482 321.7881 321.9279 322.0676 322.2074 322.3472 322.4869 322.6267 322.7664 322.9061 323.0458 323.1855 323.3252 323.4648 323.6045 323.7441 323.8838 324.0234 324.1630 324.3026 324.4422 324.5818 324.7213 324.8609 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240812T132812.3Z 8990.561253 204 1 29.98 2 57.40 101.28 141.63 66.41 0.00 1 0.00 1 0 17 1.101e-02 5.407e-03 1.551e-03 4.786e-04 3.062294e-01 2.460427e-04 3.707930e-03 -6.000000e+00 6.379091e-03 231.97 -2.00 3.57 -2.00 317.25 0.00e+00 3.855228e-04 3.523202e-05 1.099782e-04 -6.000000e+00 2.820425e-04 287.40 -2.00 20.00 -2.00 316.45 0.00e+00 1.849 0.000 302.00 328.00 3 2.1616e+00 6.5351e-04 2.4605e-02 -6.0000e+00 1.5995e-02 2.6072e-02 7.3166e-04 1.6270e-02 -6.0000e+00 1.7267e-02 -7.0171e-03 4.3933e-04 7.9018e-03 -6.0000e+00 1.0273e-02 -1.4926e-03 2.1888e-04 2.1800e-03 -6.0000e+00 4.4102e-03 6.5859e-03 7.6728e-05 1.3321e-05 2.3264e-05 -6.0000e+00 2.9133e-04 3.0972e-02 0.0000e+00 11 1 0 11 16 0 99.84 22.28 0.20 0.03097 0.03155 233 233 1 5 0 128.630 26.94 20.00 22.28 25.33 2.0 1024.73 -748 -1601 -1439 -4644 -4754 -3325 -2473 -712 -2125 -1841 -3409 -2227 -1903 -1623 -221 -1055 -79 264 454 538 -147 450 652 384 256 19 -256 -1156 -831 326 836 967 916 -1550 -3027 -2421 -1857 -908 -283 -73 -188 -131 -43 52 233 -133 -218 -413 -564 661 886 1116 1005 1119 1143 1106 934 366 524 568 1138 1506 1793 1218 -3 -314 -639 -359 300 19 232 21 53 -66 -368 -413 -1066 -632 -563 -665 -861 -1379 -1583 -1411 -944 -528 -131 392 460 291 181 23 -94 8 -28 84 724 679 251 -182 -452 -575 -161 -413 -801 -816 -550 -325 144 136 201 66 117 -23 185 254 386 378 207 54 37 208 412 461 509 416 771 639 411 228 -27 -219 -234 -152 -112 -32 163 81 -105 -341 -429 -564 -75 -175 -159 -483 -443 -331 -267 -78 -263 -235 -436 -301 -296 -293 -45 -238 -18 64 115 141 -39 118 179 104 73 6 -74 -314 -231 92 235 298 307 -529 -972 -788 -678 -391 -136 -37 -104 -75 -25 30 137 -78 -125 -233 -316 377 544 733 657 768 804 798 683 265 371 404 845 1214 1478 1061 -3 -246 -504 -285 248 17 220 20 51 -59 -321 -342 -819 -480 -470 -598 -820 -1445 -1657 -1556 -1060 -629 -162 491 569 339 203 25 -95 8 -29 100 910 893 339 -236 -569 -699 -192 -502 -1053 -1067 -752 -444 208 202 310 100 177 -32 249 331 515 536 302 83 56 307 586 652 686 557 998 872 582 329 -40 -337 -355 -243 -182 -55 280 141 -182 -566 -714 -905 SS 20240812T133330.2Z 8990.564933 207 1 5.81 2 56.46 102.32 140.80 67.75 0.00 1 0.00 1 0 17 1.007e-02 5.671e-03 1.288e-03 4.968e-04 2.993185e-01 2.555189e-04 3.628036e-03 -6.000000e+00 5.831616e-03 231.97 -2.00 3.57 -2.00 316.80 0.00e+00 4.188542e-04 3.241921e-05 8.194365e-05 -6.000000e+00 2.578546e-04 287.40 -2.00 20.00 -2.00 316.01 0.00e+00 1.804 0.000 302.00 328.00 3 7.5730e-01 6.7361e-04 2.3991e-02 -6.0000e+00 1.4623e-02 1.8011e-02 7.5201e-04 1.5846e-02 -6.0000e+00 1.5785e-02 -9.5725e-03 4.4263e-04 7.7044e-03 -6.0000e+00 9.3915e-03 7.4772e-04 2.1500e-04 2.1334e-03 -6.0000e+00 4.0314e-03 2.8450e-02 3.6818e-05 1.3721e-05 2.2690e-05 -6.0000e+00 2.6636e-04 3.1430e-02 0.0000e+00 12 1 1 12 17 1 97.33 22.28 0.23 0.03143 0.03171 188 975 1 5 0 30.710 26.94 20.00 22.28 25.97 1.9 1027.46 -70 -616 -1100 -4195 -4068 -2787 -1755 489 -1118 -1691 -3336 -2059 -1772 -1195 -76 -568 334 503 538 786 46 785 724 531 179 242 -49 -1081 -598 380 1037 1080 630 -1557 -2952 -2317 -1736 -1053 -129 -61 -20 -155 -135 23 106 -156 -379 -467 -488 493 1017 1161 1074 1091 1190 1013 798 405 521 566 1083 1549 1688 1268 -107 -391 -784 -409 238 40 240 -11 72 -26 -357 -318 -1087 -725 -571 -596 -786 -1475 -1590 -1398 -941 -522 -136 357 448 348 162 31 -101 56 4 88 817 615 264 -164 -355 -642 -279 -518 -777 -776 -606 -303 92 123 247 53 125 -59 173 332 510 390 213 -19 66 279 436 536 625 427 774 660 427 249 -55 -264 -305 -135 -88 -7 193 85 -174 -366 -429 -635 -10 -91 -165 -591 -512 -344 -234 72 -186 -291 -576 -346 -342 -266 -19 -146 89 140 156 235 14 235 226 177 63 88 -17 -361 -188 121 357 406 242 -605 -1078 -857 -719 -484 -67 -36 -12 -97 -87 15 67 -100 -237 -287 -297 306 675 782 766 818 868 758 606 304 403 417 834 1294 1460 1157 -95 -320 -640 -336 206 38 230 -10 69 -25 -326 -272 -861 -568 -491 -557 -787 -1556 -1693 -1568 -1087 -615 -167 443 548 417 186 34 -102 58 4 102 1013 807 355 -212 -439 -761 -323 -623 -1008 -1013 -828 -416 129 180 374 80 183 -83 231 430 676 530 301 -29 97 400 624 728 839 564 988 888 601 360 -81 -394 -470 -211 -141 -12 317 143 -289 -602 -677 -1001 SS 20240812T133816.1Z 8990.568242 210 1 19.36 2 55.62 103.28 140.04 68.93 0.00 1 0.00 1 0 17 9.610e-03 5.543e-03 2.188e-03 8.727e-04 2.940718e-01 4.496694e-04 3.570274e-03 -6.000000e+00 5.565498e-03 231.97 -2.00 3.57 -2.00 316.68 0.00e+00 3.589150e-04 5.590502e-05 8.194489e-05 -6.000000e+00 2.460743e-04 287.40 -2.00 20.00 -2.00 315.90 0.00e+00 1.766 0.000 302.00 328.00 3 3.1138e+00 1.1841e-03 2.3531e-02 -6.0000e+00 1.3955e-02 2.7607e-02 1.3211e-03 1.5577e-02 -6.0000e+00 1.5065e-02 -7.0280e-03 7.7435e-04 7.5685e-03 -6.0000e+00 8.9628e-03 -6.8394e-04 3.7451e-04 2.0869e-03 -6.0000e+00 3.8476e-03 2.8042e-03 5.9573e-05 2.4090e-05 2.2633e-05 -6.0000e+00 2.5418e-04 3.1060e-02 0.0000e+00 12 1 1 12 1 1 99.46 22.28 0.20 0.03106 0.03151 59 93 1 5 0 322.510 27.05 20.00 22.28 26.40 1.9 1031.41 -473 -535 -1912 -3872 -3951 -2541 -1976 958 -883 -1655 -2276 -1680 -1866 -957 354 -450 -154 747 439 553 -60 1543 687 111 688 33 -163 -1106 -888 882 912 1327 398 -1417 -2203 -2269 -1884 -738 -328 -276 -198 -335 220 180 152 -248 -586 -228 -600 650 889 1022 994 1146 1034 1198 653 486 521 568 899 1484 1759 1048 61 -421 -615 -374 194 -115 207 -17 56 -102 -240 -202 -1122 -675 -614 -627 -892 -1304 -1626 -1459 -869 -426 -103 403 296 339 36 13 -100 31 26 274 730 632 243 -135 -349 -550 -221 -514 -795 -872 -489 -380 102 200 310 189 91 -102 60 352 447 408 133 -38 47 290 545 517 510 289 769 683 454 236 -147 -231 -271 -150 -85 -66 164 95 -147 -306 -400 -631 -69 -78 -285 -582 -531 -334 -281 150 -144 -281 -383 -299 -383 -226 88 -122 -43 218 134 175 -19 482 225 39 236 12 -57 -388 -293 292 328 484 159 -572 -831 -872 -813 -351 -176 -161 -123 -217 145 119 100 -164 -380 -145 -377 415 609 709 730 838 776 919 510 374 393 430 712 1211 1558 936 55 -351 -511 -313 171 -110 202 -17 54 -99 -223 -176 -904 -537 -536 -567 -866 -1390 -1753 -1590 -1015 -507 -128 506 366 410 41 14 -103 32 29 319 909 833 318 -175 -434 -653 -256 -620 -997 -1143 -645 -525 144 292 470 283 133 -143 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