File name: Pandora122s1_Downsview_20241128_L2Fit_fwvt1c2d20240229p1-8.txt File generation date: 20241129T051422.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 122 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora122_OF_v2d20240108.txt Instrument calibration file used: Pandora122s1_CF_v2d20240229.txt Level 1 file used: Pandora122s1_Downsview_20241128_L1_smca1c2d20240229p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20241128 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1652 1801 Nominal wavelengths inside fitting window [nm]: 492.0395 492.1607 492.2819 492.4031 492.5242 492.6454 492.7665 492.8876 493.0087 493.1298 493.2508 493.3718 493.4929 493.6139 493.7348 493.8558 493.9768 494.0977 494.2186 494.3395 494.4604 494.5813 494.7021 494.8229 494.9438 495.0646 495.1853 495.3061 495.4268 495.5476 495.6683 495.7890 495.9097 496.0303 496.1510 496.2716 496.3922 496.5128 496.6334 496.7539 496.8745 496.9950 497.1155 497.2360 497.3565 497.4770 497.5974 497.7178 497.8382 497.9586 498.0790 498.1994 498.3197 498.4400 498.5603 498.6806 498.8009 498.9212 499.0414 499.1616 499.2818 499.4020 499.5222 499.6423 499.7625 499.8826 500.0027 500.1228 500.2428 500.3629 500.4829 500.6029 500.7229 500.8429 500.9629 501.0828 501.2028 501.3227 501.4426 501.5625 501.6823 501.8022 501.9220 502.0418 502.1616 502.2814 502.4012 502.5209 502.6406 502.7603 502.8800 502.9997 503.1194 503.2390 503.3586 503.4782 503.5978 503.7174 503.8370 503.9565 504.0760 504.1955 504.3150 504.4345 504.5539 504.6734 504.7928 504.9122 505.0316 505.1510 505.2703 505.3896 505.5090 505.6283 505.7475 505.8668 505.9861 506.1053 506.2245 506.3437 506.4629 506.5820 506.7012 506.8203 506.9394 507.0585 507.1776 507.2966 507.4157 507.5347 507.6537 507.7727 507.8917 508.0106 508.1296 508.2485 508.3674 508.4863 508.6052 508.7240 508.8428 508.9617 509.0805 509.1992 509.3180 509.4368 509.5555 509.6742 509.7929 509.9116 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241128T143805.7Z 9098.609788 245 1 30.77 2 73.52 144.27 61.24 173.59 0.00 1 0.00 1 0 15 3.586e-03 3.574e-03 1.031e-03 1.030e-03 1.898021e+03 6.010704e+01 1.416168e+02 -6.000000e+00 1.966746e+02 275.55 -2.00 20.00 -2.00 505.27 0.00e+00 1.332625e-03 2.800638e-05 6.511066e-05 -6.000000e+00 9.956422e-05 275.55 -2.00 20.00 -2.00 500.45 0.00e+00 3.008739e-01 2.041985e-02 1.739208e-02 -6.000000e+00 7.156123e-02 222.38 -2.00 3.57 -2.00 502.04 0.00e+00 3.470 0.001 489.00 513.00 1 7.2282e+00 1.5624e-03 5.3050e-03 -6.0000e+00 5.4790e-03 2.1925e-03 4.0270e-04 4.5281e-04 -6.0000e+00 1.4181e-03 8.4044e-04 9.9320e-04 1.0669e-04 3.0125e-05 -6.0000e+00 3.8214e-04 1.0448e-02 -1.4863e-05 12 1 1 12 1 1 99.66 22.32 1.61 0.01045 0.01734 10 11 1 4 0 2797.070 27.05 20.00 22.32 8.34 2.3 890.62 -764 -560 -174 5 34 29 247 144 142 86 -298 -243 -1 -104 -351 -7 249 -132 232 504 177 531 531 371 656 643 137 -21 -253 -282 -72 -346 -57 -194 129 31 -530 -292 -86 -161 21 263 -32 190 348 -51 287 -243 -79 -134 -434 -398 -336 -242 -128 11 493 113 349 64 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269 81 -39 63 402 -51 31 SQ 20241128T145826.9Z 9098.623923 257 1 30.02 2 71.50 148.76 61.08 179.04 0.00 1 0.00 1 0 15 3.680e-03 3.669e-03 1.453e-03 1.451e-03 1.852551e+03 8.472328e+01 1.270302e+02 -6.000000e+00 2.018801e+02 275.55 -2.00 20.00 -2.00 505.26 0.00e+00 1.054886e-03 3.945871e-05 5.198389e-05 -6.000000e+00 1.021929e-04 275.55 -2.00 20.00 -2.00 500.41 0.00e+00 2.511630e-01 2.882140e-02 1.822098e-02 -6.000000e+00 7.343982e-02 222.38 -2.00 3.57 -2.00 502.01 0.00e+00 3.112 0.001 489.00 513.00 1 7.9740e+00 2.2070e-03 4.7730e-03 -6.0000e+00 5.6231e-03 1.0933e-02 5.6806e-04 4.4947e-04 -6.0000e+00 1.4550e-03 4.2226e-04 6.8684e-04 1.5009e-04 2.4435e-05 -6.0000e+00 3.9223e-04 7.0594e-03 2.1297e-05 10 0 0 10 0 0 90.27 22.30 1.74 0.00706 0.01182 9 9 1 4 0 3334.880 27.05 20.00 22.30 8.81 2.3 893.85 -625 -692 -71 -113 35 273 297 142 205 2 -342 -783 -2 -235 -33 -236 328 -319 30 277 370 343 545 567 442 640 101 252 -397 -284 -180 152 161 -274 76 -155 -352 153 -134 29 204 395 -79 68 226 -111 237 -291 135 -386 -440 -148 -590 47 -27 -147 402 -88 400 -318 605 359 254 108 42 -12 -145 -256 128 -501 -188 167 269 63 -423 -254 -339 -29 155 84 -310 -448 -330 -7 205 -214 -113 135 244 214 245 460 90 -75 39 276 184 94 -235 -162 20 -447 -411 -539 -561 -823 -525 -280 -237 -401 -461 152 31 266 440 485 947 918 902 702 519 890 734 312 217 -284 272 -2 -174 -170 242 -545 -789 -318 -621 -432 -403 -420 -567 413 -296 254 300 164 -215 -258 170 277 -74 -72 -619 -695 -71 -116 35 283 314 151 218 2 -357 -808 -2 -243 -34 -243 330 -330 32 296 395 355 564 588 461 667 105 267 -413 -287 -178 150 163 -287 79 -162 -367 157 -137 31 212 400 -82 70 236 -116 247 -300 136 -394 -437 -143 -568 45 -27 -150 403 -90 405 -325 612 366 259 110 43 -12 -148 -257 127 -493 -184 163 264 63 -426 -253 -334 -28 148 80 -298 -435 -323 -7 203 -208 -110 131 237 209 240 457 91 -76 39 271 178 91 -224 -151 18 -426 -391 -530 -562 -828 -521 -274 -230 -393 -458 153 30 265 440 487 950 919 896 689 502 875 720 308 216 -275 270 -2 -167 -163 236 -528 -756 -300 -589 -415 -394 -405 -556 405 -294 252 299 164 -216 -256 165 262 -71 -69 SQ 20241128T151055.8Z 9098.632590 264 1 30.16 2 70.38 151.59 61.15 182.38 0.00 1 0.00 1 0 15 3.123e-03 3.118e-03 7.401e-04 7.389e-04 1.631528e+03 4.277390e+01 1.210553e+02 -6.000000e+00 1.713192e+02 275.55 -2.00 20.00 -2.00 505.25 0.00e+00 1.106017e-03 2.011751e-05 5.412202e-05 -6.000000e+00 8.672454e-05 275.55 -2.00 20.00 -2.00 500.42 0.00e+00 2.372331e-01 1.466719e-02 1.502628e-02 -6.000000e+00 6.232705e-02 222.38 -2.00 3.57 -2.00 502.01 0.00e+00 2.945 0.000 489.00 513.00 1 6.7397e+00 1.1231e-03 4.5002e-03 -6.0000e+00 4.7721e-03 1.2308e-02 2.8952e-04 3.8929e-04 -6.0000e+00 1.2350e-03 1.4862e-03 6.5917e-04 7.6653e-05 2.5259e-05 -6.0000e+00 3.3286e-04 9.7156e-03 -6.9462e-08 10 0 0 10 0 0 99.17 22.27 1.71 0.00972 0.01429 20 20 1 4 0 1507.710 26.94 20.00 22.27 8.93 2.3 895.57 -559 -457 -270 -238 -19 129 322 178 110 109 -226 -225 -102 -132 -118 -168 243 -47 246 161 213 426 419 473 526 715 78 7 -143 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