File name: Pandora170s1_Downsview_20210209_L2Fit_fout2c1d20210130p1-8.txt File generation date: 20260323T063429.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v2d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210130.txt Level 1 file used: Pandora170s1_Downsview_20210209_L1_smca1c1d20210130p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0818 305.2228 305.3638 305.5047 305.6456 305.7865 305.9275 306.0684 306.2092 306.3501 306.4910 306.6318 306.7727 306.9135 307.0544 307.1952 307.3360 307.4768 307.6176 307.7584 307.8991 308.0399 308.1806 308.3214 308.4621 308.6028 308.7435 308.8842 309.0249 309.1656 309.3062 309.4469 309.5875 309.7281 309.8688 310.0094 310.1500 310.2906 310.4312 310.5717 310.7123 310.8528 310.9934 311.1339 311.2744 311.4149 311.5554 311.6959 311.8364 311.9769 312.1173 312.2578 312.3982 312.5386 312.6790 312.8194 312.9598 313.1002 313.2406 313.3809 313.5213 313.6616 313.8019 313.9423 314.0826 314.2229 314.3632 314.5034 314.6437 314.7839 314.9242 315.0644 315.2046 315.3449 315.4851 315.6253 315.7654 315.9056 316.0458 316.1859 316.3260 316.4662 316.6063 316.7464 316.8865 317.0266 317.1666 317.3067 317.4467 317.5868 317.7268 317.8668 318.0068 318.1468 318.2868 318.4268 318.5668 318.7067 318.8466 318.9866 319.1265 319.2664 319.4063 319.5462 319.6861 319.8259 319.9658 320.1056 320.2455 320.3853 320.5251 320.6649 320.8047 320.9445 321.0842 321.2240 321.3637 321.5035 321.6432 321.7829 321.9226 322.0623 322.2020 322.3416 322.4813 322.6209 322.7606 322.9002 323.0398 323.1794 323.3190 323.4586 323.5981 323.7377 323.8772 324.0168 324.1563 324.2958 324.4353 324.5748 324.7143 324.8538 324.9932 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210209T132124.1Z 7710.556529 140 1 30.21 2 81.50 119.58 76.16 147.41 0.00 1 0.00 1 0 33 6.123e-01 1.886e-02 4.466e-01 1.438e-02 9.909723e-01 8.415004e-03 1.088977e-02 -6.000000e+00 3.521297e-01 224.40 -2.00 3.57 -2.00 322.22 0.00e+00 1.045873e-02 4.593397e-03 2.422370e-03 -6.000000e+00 1.657460e-02 271.77 -2.00 20.00 -2.00 321.81 0.00e+00 6.380 0.005 302.00 328.00 3 2.4156e+00 3.0484e-02 8.2712e-02 -6.0000e+00 8.7237e-01 7.2352e-01 4.7626e-02 5.7604e-02 -6.0000e+00 9.5832e-01 -9.3361e-01 5.2757e-02 3.2385e-02 -6.0000e+00 5.6445e-01 3.7123e-01 2.3938e-02 1.5662e-02 -6.0000e+00 2.3512e-01 3.2164e-05 -1.0050e-03 3.8583e-04 2.3543e-04 -6.0000e+00 1.7481e-02 4.8973e-03 2.0941e-05 12 8 8 0 0 0 99.92 22.62 0.24 0.00490 -0.00265 33 33 1 5 0 915.160 26.62 20.00 22.62 -2.05 18.8 1006.33 -70967 -185889 900000 -277363 900000 900000 -219041 -71545 71622 -266469 -233333 79003 900000 -174186 900000 -87657 40833 4236 900000 900000 -42922 900000 27195 -63398 -100285 -115581 -109158 900000 -37362 -21977 -63416 900000 -2164 78262 12703 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190 148 980 931 -128 -350 -834 -790 1602 -82 -193 -2530 -295 -2451 -772 -2979 1973 1721 -1674 -1996 -2889 68 -1228 -3313 -990 -1688 -1771 -914 -1119 1241 -789 -3201 1143 -1554 523 914 1247 1819 2841 -107 1640 2347 1512 150 -891 1618 5092 90 -450 1619 -517 -3526 -52 -43 -489 1026 1631 223 33 392 -2870 -1329 SS 20210209T133632.8Z 7710.567047 146 1 29.67 2 79.16 122.44 74.79 150.55 0.00 1 0.00 1 0 25 5.909e-01 1.910e-02 3.338e-01 1.059e-02 8.231955e-01 5.866774e-03 9.594645e-03 -6.000000e+00 3.403349e-01 224.40 -2.00 3.57 -2.00 321.46 0.00e+00 1.061972e-02 2.666963e-03 1.929342e-03 -6.000000e+00 1.444871e-02 271.77 -2.00 20.00 -2.00 321.06 0.00e+00 5.123 0.003 302.00 328.00 3 3.4865e+00 1.9027e-02 6.6955e-02 -6.0000e+00 8.4233e-01 5.3340e-01 2.6130e-02 4.5571e-02 -6.0000e+00 9.1501e-01 -6.6052e-01 2.7441e-02 2.7617e-02 -6.0000e+00 5.4273e-01 2.7409e-01 1.3277e-02 1.3598e-02 -6.0000e+00 2.3331e-01 4.0109e-05 -2.1810e-03 2.8256e-04 1.7711e-04 -6.0000e+00 1.6444e-02 6.4795e-03 -1.0797e-04 12 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4.2607e+00 2.0334e-02 5.7743e-02 -6.0000e+00 6.8615e-01 1.2040e-01 2.8684e-02 4.0499e-02 -6.0000e+00 7.4798e-01 -1.9767e-01 3.1742e-02 2.2462e-02 -6.0000e+00 4.4335e-01 8.6290e-02 1.5354e-02 8.8285e-03 -6.0000e+00 1.9210e-01 4.7358e-05 -2.2833e-03 3.2708e-04 1.0059e-04 -6.0000e+00 1.3486e-02 1.0283e-02 -3.1462e-04 12 8 8 0 0 0 99.99 22.60 0.22 0.01028 -0.00687 34 34 1 5 0 883.770 26.51 20.00 22.60 -1.39 18.8 1003.49 900000 -201008 900000 -68033 -239555 -80311 -225032 -52384 -176762 900000 900000 -15468 -150385 164361 -60650 -88843 900000 63829 900000 -20797 -32943 -39465 -15754 -83065 47689 -84478 48724 -20513 -20051 20489 31168 15965 -19260 41 -2597 8246 -27912 -17137 31948 19454 2688 -15638 21022 7542 46282 3714 25021 5608 14181 10698 -191 12147 6216 5627 17296 8962 2021 -3218 -7425 8876 9161 2728 1745 4260 7715 -484 7505 -1247 2333 -1342 4726 2182 -69 2707 -2210 -1753 3204 -61 -1240 -1152 -2154 -846 961 -205 -637 -1746 -675 -1531 1231 772 727 859 -2160 367 -3697 -220 737 1124 -234 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