File name: Pandora170s1_Downsview_20210311_L2Fit_fout2c1d20210130p1-8.txt File generation date: 20260323T063948.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v4d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210130.txt Level 1 file used: Pandora170s1_Downsview_20210311_L1_smca1c1d20210130p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210311 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0818 305.2228 305.3638 305.5047 305.6456 305.7865 305.9275 306.0684 306.2092 306.3501 306.4910 306.6318 306.7727 306.9135 307.0544 307.1952 307.3360 307.4768 307.6176 307.7584 307.8991 308.0399 308.1806 308.3214 308.4621 308.6028 308.7435 308.8842 309.0249 309.1656 309.3062 309.4469 309.5875 309.7281 309.8688 310.0094 310.1500 310.2906 310.4312 310.5717 310.7123 310.8528 310.9934 311.1339 311.2744 311.4149 311.5554 311.6959 311.8364 311.9769 312.1173 312.2578 312.3982 312.5386 312.6790 312.8194 312.9598 313.1002 313.2406 313.3809 313.5213 313.6616 313.8019 313.9423 314.0826 314.2229 314.3632 314.5034 314.6437 314.7839 314.9242 315.0644 315.2046 315.3449 315.4851 315.6253 315.7654 315.9056 316.0458 316.1859 316.3260 316.4662 316.6063 316.7464 316.8865 317.0266 317.1666 317.3067 317.4467 317.5868 317.7268 317.8668 318.0068 318.1468 318.2868 318.4268 318.5668 318.7067 318.8466 318.9866 319.1265 319.2664 319.4063 319.5462 319.6861 319.8259 319.9658 320.1056 320.2455 320.3853 320.5251 320.6649 320.8047 320.9445 321.0842 321.2240 321.3637 321.5035 321.6432 321.7829 321.9226 322.0623 322.2020 322.3416 322.4813 322.6209 322.7606 322.9002 323.0398 323.1794 323.3190 323.4586 323.5981 323.7377 323.8772 324.0168 324.1563 324.2958 324.4353 324.5748 324.7143 324.8538 324.9932 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210311T131645.1Z 7740.553300 88 1 50.23 2 73.29 112.08 73.12 135.61 0.00 1 0.00 1 0 25 5.807e-01 5.985e-02 1.661e-01 7.772e-03 4.297042e-01 4.296112e-03 5.400417e-03 -6.000000e+00 3.492723e-01 225.60 -2.00 3.57 -2.00 319.93 0.00e+00 1.547486e-02 1.288894e-03 4.462049e-04 -6.000000e+00 1.714518e-02 273.59 -2.00 20.00 -2.00 319.44 0.00e+00 3.424 0.001 302.00 328.00 3 5.5746e+00 1.2127e-02 4.1199e-02 -6.0000e+00 8.7333e-01 1.8089e-01 1.4404e-02 2.7732e-02 -6.0000e+00 9.5538e-01 -2.6659e-01 1.2025e-02 1.8186e-02 -6.0000e+00 5.6184e-01 1.2384e-01 6.2503e-03 1.7000e-02 -6.0000e+00 2.4145e-01 3.9205e-05 -3.2716e-03 2.4321e-04 1.4968e-04 -6.0000e+00 1.6959e-02 5.9981e-03 -3.8217e-04 12 9 8 1 32 0 99.90 22.50 3.03 0.00600 -0.01859 42 9 1 5 0 1195.920 26.41 20.00 22.50 20.21 21.8 993.23 130293 900000 900000 -91934 900000 900000 -126778 900000 10301 -126104 900000 900000 900000 900000 900000 900000 900000 900000 63980 324481 71636 -8001 -14813 72177 353069 -26095 28186 68183 900000 900000 71131 66847 900000 75262 65538 900000 199081 -27516 15179 -7907 75312 46120 57911 -20571 30682 50294 -16478 -1006 12773 45668 10713 -18076 46046 2542 -3806 25128 47885 -6249 -3839 5429 2205 -13297 47532 -1603 9683 -8317 23650 11746 22454 -2018 -11831 -922 721 9309 -18 17389 -7251 1087 16439 -6174 -8191 11359 -4516 2755 5483 5806 159 -2831 -15336 9540 -71 348 2948 191 -1628 -9378 -6526 2474 -1679 -1344 -7364 5997 5887 7354 -2876 1457 -12469 1699 -594 -2917 594 520 -1544 -1304 -4146 -80 6877 -620 3095 -1785 -2441 8540 3154 1651 5209 2001 9725 -137 -4810 6286 -1656 2644 4282 1764 1140 4215 -1604 -4543 -2150 -3497 -1194 -226 900000 1121 900000 900000 -7530 900000 900000 -11799 900000 272 -12242 900000 900000 900000 900000 900000 900000 900000 900000 3081 2450 3287 -762 -1469 3080 2666 -2837 1817 2946 900000 900000 3794 4257 900000 5004 4494 900000 3987 -5504 2347 -1707 7955 6749 7961 -6110 5816 8115 -5060 -271 3064 8317 2900 -6886 10231 884 -1430 7247 11118 -2373 -1405 1849 821 -6273 14158 -812 4471 -4310 8759 4896 9177 -1159 -7958 -577 436 4953 -9 7217 -3534 493 7153 -3792 -5780 7385 -3604 2157 4445 4966 150 -2802 -16892 8133 -62 279 2191 148 -1400 -9710 -7388 2866 -2113 -1664 -9016 6010 5633 7175 -3277 1673 -16908 2149 -820 -4408 923 821 -2427 -1940 -5974 -108 8823 -890 4552 -2833 -3904 12175 4578 2351 6931 2630 11680 -186 -7379 9466 -2805 4453 7341 3223 2196 8202 -3323 -9746 -4500 -7214 -2323 -419 900000 SS 20210311T134630.9Z 7740.573969 103 1 49.85 2 68.41 118.02 69.59 141.94 0.00 1 0.00 1 0 17 1.928e-02 7.476e-03 1.724e-03 3.576e-04 3.596077e-01 1.786629e-04 4.269386e-03 -6.000000e+00 1.097496e-02 225.60 -2.00 3.57 -2.00 317.95 0.00e+00 1.142323e-03 3.040123e-05 2.380692e-04 -6.000000e+00 4.722822e-04 273.59 -2.00 20.00 -2.00 317.37 0.00e+00 2.694 0.000 302.00 328.00 3 1.2711e+00 4.7582e-04 3.2056e-02 -6.0000e+00 2.7203e-02 7.4213e-03 5.3800e-04 1.8374e-02 -6.0000e+00 2.9685e-02 -1.4935e-02 3.4491e-04 9.1248e-03 -6.0000e+00 1.7622e-02 3.3552e-04 1.7696e-04 2.7698e-03 -6.0000e+00 7.3654e-03 6.9981e-03 3.1833e-04 1.0367e-05 2.9685e-05 -6.0000e+00 5.3517e-04 -3.1109e-04 1.3219e-04 11 8 0 0 0 0 99.99 22.51 0.23 -0.00031 0.00208 781 162 1 5 0 63.090 26.41 20.01 22.51 20.83 21.9 994.45 -1792 -1455 -1494 -8412 -6969 -5273 -5646 -2659 -3828 -7321 -7040 -5007 -2211 374 1634 245 480 2165 1246 2278 187 -37 1066 1186 790 -339 -1404 -2379 -1351 -23 1064 1459 2739 -2326 -4851 -2953 -3201 -1845 -524 -942 -880 -730 -205 -904 456 87 -369 -461 -1042 301 1599 694 1335 1407 710 1636 695 81 20 166 1073 1697 2464 2146 -213 -741 -475 -619 1659 736 444 839 328 942 -239 -402 -1199 -1624 -483 -1305 -1480 -1444 -2619 -1509 -552 -399 355 453 899 669 653 -152 -319 243 -45 -256 486 1102 -183 -466 -671 -1099 -106 264 -1366 -1488 -906 -836 297 415 606 102 247 -19 -84 391 456 503 596 3 -167 547 903 352 765 -379 382 1169 106 -261 -483 -587 -160 204 -98 -252 354 526 -104 -116 -217 -522 -393 -106 -95 -100 -569 -463 -336 -388 -183 -296 -616 -597 -446 -223 44 221 38 78 368 225 424 36 -7 211 250 163 -73 -305 -496 -291 -5 230 351 714 -652 -1323 -789 -947 -639 -200 -418 -397 -346 -100 -449 224 43 -182 -227 -515 151 854 405 773 861 453 1065 464 54 13 108 722 1158 1833 1711 -163 -568 -344 -451 1295 618 382 745 289 832 -196 -316 -875 -1174 -375 -1098 -1335 -1439 -2674 -1608 -593 -457 424 527 1084 772 734 -158 -328 251 -48 -291 587 1395 -247 -613 -861 -1297 -125 323 -1746 -1916 -1218 -1183 425 614 946 162 377 -28 -115 539 635 705 892 4 -255 809 1345 506 1090 -520 504 1586 152 -387 -758 -914 -255 342 -168 -452 623 938 -185 -208 -372 -863 -670 SS 20210311T135658.4Z 7740.581232 110 1 4.89 2 66.76 120.20 68.46 144.26 0.00 1 0.00 1 0 17 1.380e-01 1.755e-02 6.514e-02 9.797e-03 3.339381e-01 4.890664e-03 4.020241e-03 -6.000000e+00 7.852680e-02 225.60 -2.00 3.57 -2.00 318.06 0.00e+00 1.180260e-03 8.618291e-04 1.215050e-04 -6.000000e+00 3.379439e-03 273.59 -2.00 20.00 -2.00 317.49 0.00e+00 2.515 0.000 302.00 328.00 3 4.8906e+00 1.3053e-02 2.9990e-02 -6.0000e+00 1.9464e-01 3.4284e-03 1.4804e-02 1.7354e-02 -6.0000e+00 2.1243e-01 2.2210e-02 9.7408e-03 8.5509e-03 -6.0000e+00 1.2610e-01 -1.7567e-02 5.0350e-03 2.6842e-03 -6.0000e+00 5.2684e-02 2.2732e-04 5.9006e-04 2.8682e-04 2.8597e-05 -6.0000e+00 3.8312e-03 9.5600e-04 7.1293e-05 12 9 9 2 33 33 999.00 22.52 0.78 0.00096 0.00539 1 4 1 5 0 2359.350 26.51 20.00 22.52 21.57 21.8 995.12 60480 48695 45967 -47795 52591 -25507 -12002 19741 4331 -39850 74704 2224 18825 27014 -1775 3585 4400 21891 -7129 8310 -6266 -12547 4158 -2956 17759 -7389 -3537 -8344 23206 19358 -1238 10533 7294 3672 5113 19072 249 -3690 -5038 -4642 888 2574 6782 -8560 1808 1676 -2279 -6148 3250 1134 2761 -5542 1854 1374 -1523 3504 310 -234 -1456 731 -3191 985 83 -1041 474 -3298 -74 -1705 4636 112 -967 1165 893 206 -268 -250 -2002 -1888 257 1939 -1846 1742 -2558 -407 1348 706 2723 -965 216 1184 1661 1465 1148 206 -133 -2179 -1624 2334 -830 -12 -2394 514 890 1673 -1988 -1387 -3061 -472 1007 -177 1660 117 528 551 -512 -468 -94 -593 747 -40 -1572 -196 1253 993 553 -208 -334 1094 -425 1737 -1430 295 612 345 -347 -918 -45 -120 219 -334 -650 779 126 1922 1905 1891 -4478 1755 -1747 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