File name: Pandora170s1_Downsview_20210331_L2Fit_fwvt1c1d20210329p1-8.txt File generation date: 20260323T064424.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v4d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210329.txt Level 1 file used: Pandora170s1_Downsview_20210331_L1_smca1c1d20210329p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210331 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0344 492.1557 492.2770 492.3982 492.5195 492.6407 492.7619 492.8831 493.0043 493.1254 493.2466 493.3677 493.4888 493.6099 493.7310 493.8520 493.9731 494.0941 494.2151 494.3361 494.4571 494.5780 494.6990 494.8199 494.9408 495.0617 495.1826 495.3034 495.4243 495.5451 495.6659 495.7867 495.9075 496.0282 496.1490 496.2697 496.3904 496.5111 496.6318 496.7524 496.8731 496.9937 497.1143 497.2349 497.3554 497.4760 497.5965 497.7171 497.8376 497.9580 498.0785 498.1990 498.3194 498.4398 498.5602 498.6806 498.8010 498.9213 499.0417 499.1620 499.2823 499.4026 499.5228 499.6431 499.7633 499.8835 500.0037 500.1239 500.2441 500.3642 500.4843 500.6044 500.7245 500.8446 500.9647 501.0847 501.2047 501.3248 501.4447 501.5647 501.6847 501.8046 501.9245 502.0445 502.1643 502.2842 502.4041 502.5239 502.6437 502.7635 502.8833 503.0031 503.1228 503.2426 503.3623 503.4820 503.6017 503.7214 503.8410 503.9606 504.0802 504.1998 504.3194 504.4390 504.5585 504.6781 504.7976 504.9171 505.0366 505.1560 505.2755 505.3949 505.5143 505.6337 505.7531 505.8724 505.9917 506.1111 506.2304 506.3497 506.4689 506.5882 506.7074 506.8266 506.9458 507.0650 507.1842 507.3033 507.4225 507.5416 507.6607 507.7798 507.8988 508.0179 508.1369 508.2559 508.3749 508.4939 508.6128 508.7318 508.8507 508.9696 509.0885 509.2074 509.3262 509.4450 509.5639 509.6827 509.8014 509.9202 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20210331T184006.8Z 7760.777857 466 1 7.66 2 42.94 209.33 148.21 319.72 0.00 1 0.00 1 0 15 2.413e-03 2.403e-03 2.655e-04 2.651e-04 7.893134e+02 1.386539e+01 5.892344e+01 -6.000000e+00 1.245479e+02 275.70 -2.00 20.00 -2.00 505.25 0.00e+00 3.654999e-04 7.037092e-06 1.938237e-05 -6.000000e+00 6.546790e-05 275.70 -2.00 20.00 -2.00 500.44 0.00e+00 2.475252e-02 5.120557e-03 6.947204e-03 -6.000000e+00 4.707423e-02 227.00 -2.00 3.57 -2.00 502.03 0.00e+00 1.364 0.000 489.00 513.00 1 3.1693e+00 3.9045e-04 2.0503e-03 -6.0000e+00 3.5894e-03 9.5994e-03 1.0325e-04 1.8596e-04 -6.0000e+00 9.4878e-04 6.7653e-02 6.0854e-04 2.2246e-05 1.0308e-05 -6.0000e+00 2.0711e-04 -6.9460e-04 -1.7779e-05 12 1 1 2 1 1 99.90 22.53 1.03 -0.00069 0.00353 137 104 1 4 0 54.230 26.51 19.98 22.53 16.56 23.1 991.69 -456 -486 -290 -201 31 284 267 367 252 262 232 73 -183 -229 -349 -275 -89 -20 -130 -89 153 198 92 243 158 266 408 238 -315 -169 -179 -218 131 198 44 226 350 120 -19 0 -88 -70 -37 168 206 142 200 203 111 -258 -389 -572 -677 -332 -281 -248 -141 121 68 224 316 321 279 211 200 56 173 136 -77 -258 -170 -170 -56 24 -43 -174 111 -76 -243 -401 -215 -304 -266 -83 -117 -73 -124 -99 -129 -106 45 248 263 89 236 303 166 -7 -406 -488 -452 -324 -141 -142 -206 87 -100 -251 -144 -152 -189 112 170 225 269 498 535 326 259 289 152 18 172 78 -45 174 117 134 403 231 -29 42 -162 -310 -240 -71 -141 -51 166 27 86 112 177 203 188 -42 -262 -399 -413 -372 -441 -476 -283 -204 32 292 280 389 268 275 239 75 -184 -234 -354 -279 -92 -20 -136 -92 158 204 95 251 164 277 422 244 -327 -168 -179 -219 134 203 46 236 361 126 -19 0 -90 -72 -38 172 213 148 206 207 114 -260 -392 -561 -654 -321 -281 -248 -145 125 70 230 323 331 280 212 206 57 172 134 -75 -256 -167 -167 -54 23 -42 -171 107 -74 -235 -388 -208 -298 -254 -80 -115 -72 -122 -97 -128 -106 45 251 263 90 235 305 164 -7 -395 -465 -428 -312 -136 -138 -206 86 -98 -248 -141 -150 -184 111 170 228 274 508 548 335 264 288 150 18 170 76 -44 170 114 130 390 224 -28 41 -155 -293 -226 -68 -134 -49 163 26 85 112 177 205 184 -43 -258 -381 -397 -357 SQ 20210331T184904.4Z 7760.784078 472 1 50.71 2 43.77 212.35 149.19 323.15 0.00 1 0.00 1 0 15 2.839e-03 2.826e-03 1.022e-03 1.020e-03 1.234936e+03 5.468470e+01 8.976657e+01 -6.000000e+00 1.465333e+02 275.70 -2.00 20.00 -2.00 505.25 0.00e+00 4.108169e-04 2.706790e-05 2.130426e-05 -6.000000e+00 7.702678e-05 275.70 -2.00 20.00 -2.00 500.42 0.00e+00 2.869422e-02 1.976049e-02 1.070138e-02 -6.000000e+00 5.537908e-02 227.00 -2.00 3.57 -2.00 502.01 0.00e+00 1.383 0.000 489.00 513.00 1 7.6753e+00 1.5062e-03 2.1944e-03 -6.0000e+00 4.2227e-03 8.4289e-03 3.9804e-04 2.6388e-04 -6.0000e+00 1.1160e-03 7.4371e-04 5.4038e-04 8.5863e-05 1.4585e-05 -6.0000e+00 2.4367e-04 -2.6838e-03 4.0022e-06 11 1 0 1 32 0 99.90 22.53 1.19 -0.00268 0.00106 16 3 1 4 0 3167.810 26.51 20.00 22.53 16.88 23.1 992.04 -490 -594 -311 -322 -52 336 487 340 154 -246 156 -83 612 -350 -224 -451 -268 190 -127 -2 356 106 35 155 -3 218 448 302 -134 -193 94 -152 62 456 -165 130 259 -66 105 -106 41 -299 43 195 152 113 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144 -209 202 -190 158 172 232 126 78 -10 -463 -310 -529 -397 SQ 20210331T185736.9Z 7760.790011 478 1 1.86 2 44.62 215.15 150.06 326.57 0.00 1 0.00 1 0 15 2.482e-03 2.483e-03 1.105e-03 1.103e-03 7.756920e+02 5.777906e+01 5.799976e+01 -6.000000e+00 1.281043e+02 275.70 -2.00 20.00 -2.00 505.25 0.00e+00 3.700674e-04 2.927267e-05 2.014996e-05 -6.000000e+00 6.733125e-05 275.70 -2.00 20.00 -2.00 500.44 0.00e+00 7.173806e-02 2.131269e-02 6.943897e-03 -6.000000e+00 4.839419e-02 227.00 -2.00 3.57 -2.00 502.03 0.00e+00 1.403 0.000 489.00 513.00 1 4.3891e+00 1.6253e-03 2.1042e-03 -6.0000e+00 3.6903e-03 1.3518e-02 4.2981e-04 1.8665e-04 -6.0000e+00 9.7496e-04 1.9800e-02 -2.3596e-04 9.2656e-05 1.0314e-05 -6.0000e+00 2.1299e-04 -1.3025e-03 1.9489e-05 12 1 1 2 1 1 77.23 22.53 1.03 -0.00130 -0.00294 7 49 1 4 0 209.690 26.51 20.00 22.53 17.36 23.1 991.48 -353 -692 -90 -352 9 323 287 547 273 117 162 28 -225 -96 -379 -223 -272 -42 -172 -19 322 223 98 223 380 291 473 33 -334 -373 -273 -127 42 361 -37 252 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