File name: Pandora170s1_Downsview_20210411_L2Fit_fout2c1d20210329p1-8.txt File generation date: 20260323T064448.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v4d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210329.txt Level 1 file used: Pandora170s1_Downsview_20210411_L1_smca1c1d20210329p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 357 Nominal wavelengths inside fitting window [nm]: 305.0817 305.2226 305.3635 305.5044 305.6453 305.7862 305.9271 306.0680 306.2088 306.3497 306.4906 306.6314 306.7722 306.9130 307.0538 307.1946 307.3354 307.4762 307.6170 307.7577 307.8985 308.0392 308.1800 308.3207 308.4614 308.6021 308.7428 308.8835 309.0241 309.1648 309.3055 309.4461 309.5867 309.7274 309.8680 310.0086 310.1492 310.2897 310.4303 310.5709 310.7114 310.8520 310.9925 311.1330 311.2735 311.4140 311.5545 311.6950 311.8355 311.9759 312.1164 312.2568 312.3973 312.5377 312.6781 312.8185 312.9589 313.0993 313.2396 313.3800 313.5203 313.6607 313.8010 313.9413 314.0816 314.2219 314.3622 314.5025 314.6428 314.7830 314.9233 315.0635 315.2037 315.3439 315.4841 315.6243 315.7645 315.9047 316.0448 316.1850 316.3251 316.4653 316.6054 316.7455 316.8856 317.0257 317.1657 317.3058 317.4459 317.5859 317.7259 317.8660 318.0060 318.1460 318.2860 318.4259 318.5659 318.7059 318.8458 318.9858 319.1257 319.2656 319.4055 319.5454 319.6853 319.8252 319.9650 320.1049 320.2447 320.3845 320.5244 320.6642 320.8040 320.9437 321.0835 321.2233 321.3630 321.5028 321.6425 321.7822 321.9219 322.0616 322.2013 322.3410 322.4807 322.6203 322.7599 322.8996 323.0392 323.1788 323.3184 323.4580 323.5976 323.7371 323.8767 324.0162 324.1558 324.2953 324.4348 324.5743 324.7138 324.8532 324.9927 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210411T183142.4Z 7771.772019 306 1 0.88 2 38.60 209.72 44.74 209.56 0.00 1 0.00 1 0 17 1.231e-02 8.788e-03 4.009e-03 2.706e-03 1.923907e-01 1.378863e-03 2.358513e-03 -6.000000e+00 7.003287e-03 227.86 -2.00 3.57 -2.00 315.05 0.00e+00 5.022094e-04 1.170354e-04 2.187171e-05 -6.000000e+00 3.023255e-04 276.95 -2.00 20.00 -2.00 314.52 0.00e+00 1.278 0.000 302.00 328.00 3 1.8688e+00 3.5390e-03 1.6054e-02 -6.0000e+00 1.7437e-02 3.1123e-02 3.9425e-03 9.9492e-03 -6.0000e+00 1.8985e-02 -4.4473e-03 2.2538e-03 4.8803e-03 -6.0000e+00 1.1271e-02 -2.3997e-03 9.8591e-04 1.3984e-03 -6.0000e+00 4.7211e-03 1.8881e-02 5.4433e-04 7.6362e-05 1.7774e-05 -6.0000e+00 3.3222e-04 -2.1550e-03 2.4936e-04 12 9 1 2 1 1 -48.46 22.56 0.31 -0.00216 0.00194 4 73 1 5 0 140.580 26.51 20.00 22.56 22.22 23.3 977.88 1958 -1048 1687 -3764 -3614 -2700 -28 727 -298 -702 -5107 -1510 132 59 617 414 -94 1916 563 1248 757 -196 1715 1980 1615 654 1099 -1098 173 155 1614 1991 1916 -968 -4292 -1786 -2913 -1217 -643 -926 -1117 -336 -406 -768 -79 -126 -792 -460 -953 -296 1202 900 839 1506 499 1954 555 719 -93 821 1017 1491 1780 2125 -727 -668 -150 -721 1485 -55 77 594 533 169 -564 -424 -579 -676 -440 -1480 -1377 -1704 -2773 -1856 -392 -889 6 124 1027 313 643 459 174 947 553 323 506 777 -436 -39 -385 -699 -735 348 -1467 -1389 -965 -839 -26 96 350 356 289 102 -18 424 245 309 609 133 -306 246 696 606 1128 36 743 1864 402 174 -329 -328 34 91 296 -570 95 227 -196 -378 -322 -687 -602 619 -342 575 -1247 -1052 -798 -9 228 -104 -255 -1883 -543 48 24 266 192 -45 919 282 639 371 -101 886 1005 860 362 595 -565 87 75 808 1058 1024 -536 -2274 -963 -1636 -742 -441 -696 -863 -267 -330 -629 -64 -101 -622 -364 -734 -226 947 720 704 1251 427 1676 488 626 -80 700 896 1403 1720 2053 -704 -614 -131 -650 1340 -54 79 628 560 172 -557 -391 -504 -589 -382 -1389 -1375 -1786 -2980 -2070 -445 -1044 7 155 1274 374 730 512 185 972 578 357 593 957 -547 -49 -469 -821 -833 411 -1840 -1764 -1229 -1111 -34 135 490 495 396 133 -23 513 299 398 809 182 -414 339 925 797 1452 44 903 2273 509 225 -444 -433 46 127 422 -826 141 341 -296 -558 -475 -983 -853 SS 20210411T185637.5Z 7771.789323 321 1 39.06 2 41.12 218.50 47.10 217.42 0.00 1 0.00 1 0 17 1.171e-02 7.972e-03 1.961e-03 1.130e-03 2.010593e-01 5.721921e-04 2.443613e-03 -6.000000e+00 6.657343e-03 227.86 -2.00 3.57 -2.00 315.67 0.00e+00 3.943307e-04 5.512866e-05 3.341972e-05 -6.000000e+00 2.873859e-04 276.95 -2.00 20.00 -2.00 315.09 0.00e+00 1.326 0.000 302.00 328.00 3 4.1288e+00 1.4781e-03 1.6686e-02 -6.0000e+00 1.6576e-02 4.5608e-02 1.6515e-03 1.0356e-02 -6.0000e+00 1.8048e-02 -3.8154e-03 9.4636e-04 5.0876e-03 -6.0000e+00 1.0715e-02 -2.9015e-03 4.2470e-04 1.4377e-03 -6.0000e+00 4.4878e-03 1.8392e-03 3.9904e-04 3.2110e-05 1.7502e-05 -6.0000e+00 3.1590e-04 -3.8663e-03 1.4598e-04 12 9 1 2 1 1 99.99 22.57 0.27 -0.00387 -0.00087 56 15 1 5 0 682.120 26.51 19.99 22.57 23.58 23.6 977.95 56 899 -105 -3798 -3888 -2490 503 1962 1203 -1941 -3196 -2422 -583 -244 549 -121 -344 1231 214 1492 1046 453 1240 1755 433 781 478 -1186 -54 241 2317 2037 3054 -1674 -3912 -1828 -2257 -1149 -495 -697 -935 -495 -635 -828 109 -319 -571 -383 -1150 -342 1614 425 1050 1024 984 1369 845 242 253 277 662 1623 1669 2011 -608 -624 -787 -492 1281 404 124 433 722 856 353 -481 -800 -1403 -288 -1243 -1489 -1639 -2781 -1384 -815 -576 -38 368 949 338 501 84 -84 571 110 -33 462 1014 -24 -688 -540 -286 -340 266 -1269 -1170 -967 -703 134 280 489 214 352 86 164 491 409 103 576 -236 -283 197 768 447 899 -179 572 1525 546 -209 -188 -276 75 271 -76 -528 322 368 -155 -405 -316 -562 -468 14 233 -28 -965 -892 -545 113 481 323 -552 -901 -689 -178 -82 202 -48 -138 500 90 637 453 196 540 791 205 377 229 -546 -23 102 1001 929 1455 -831 -1870 -851 -1130 -641 -313 -485 -688 -373 -486 -637 83 -243 -428 -281 -830 -246 1184 328 835 838 818 1149 719 206 213 232 568 1451 1566 1941 -588 -570 -683 -419 1133 389 125 448 743 860 339 -434 -678 -1156 -244 -1142 -1468 -1709 -3024 -1537 -942 -693 -46 462 1184 412 581 92 -87 582 116 -37 550 1274 -31 -880 -662 -334 -389 313 -1583 -1504 -1275 -948 185 400 712 312 497 116 210 608 509 133 772 -329 -400 275 1052 597 1161 -226 699 1872 700 -278 -256 -381 104 385 -112 -801 494 570 -240 -621 -476 -831 -689 SS 20210411T195318.7Z 7771.828688 355 1 23.36 2 48.59 235.38 54.06 233.03 0.00 1 0.00 1 0 17 1.471e-02 8.195e-03 5.943e-03 2.641e-03 2.333997e-01 1.330388e-03 2.819013e-03 -6.000000e+00 8.366680e-03 227.86 -2.00 3.57 -2.00 316.46 0.00e+00 3.342621e-04 1.528517e-04 7.383556e-05 -6.000000e+00 3.611784e-04 276.96 -2.00 20.00 -2.00 315.84 0.00e+00 1.509 0.000 302.00 328.00 3 4.9216e+00 3.4705e-03 1.9151e-02 -6.0000e+00 2.0832e-02 4.3600e-02 3.8904e-03 1.2019e-02 -6.0000e+00 2.2682e-02 3.0856e-03 2.2608e-03 5.9108e-03 -6.0000e+00 1.3466e-02 -8.6457e-03 1.0563e-03 1.6596e-03 -6.0000e+00 5.6401e-03 6.5534e-04 3.3088e-04 7.5579e-05 1.9146e-05 -6.0000e+00 3.9700e-04 -3.6039e-03 1.5855e-04 12 9 1 2 9 1 99.99 22.59 0.36 -0.00360 -0.00112 12 6 1 5 0 1783.380 26.51 19.99 22.59 24.89 23.7 976.18 -914 1581 -835 -2036 -5519 -550 -2017 5771 2104 -276 -5710 -3934 -201 -833 -576 -2479 649 -239 454 -1390 2299 -1550 1311 1791 832 1424 437 -1176 516 2312 1928 2253 5146 -857 -3524 -1939 -981 -2270 -97 -1526 -810 -1629 -547 -764 512 -784 -164 533 -1803 305 2024 411 817 453 1119 1363 1164 -10 -101 943 868 1161 1909 1763 -614 -830 -784 -467 1277 524 -7 805 712 984 396 -499 -1299 -1757 -5 -1087 -1622 -1908 -2142 -1246 -513 -616 -81 581 819 351 298 358 -393 839 65 -460 203 1029 496 -756 -253 -1073 -553 308 -1103 -1295 -544 -857 -192 313 438 360 157 393 -410 369 421 256 463 -323 -133 263 1326 249 1027 -455 463 1359 824 -397 -272 -27 -58 108 182 -469 252 472 -154 -262 -447 -491 -597 -153 279 -152 -351 -884 -81 -321 957 397 -55 -1180 -820 -45 -210 -162 -762 201 -77 150 -479 779 -539 454 647 316 554 170 -439 179 783 687 852 2023 -357 -1419 -763 -414 -1100 -53 -946 -530 -1106 -375 -528 350 -539 -110 350 -1184 199 1354 292 602 346 867 1071 926 -8 -80 738 697 980 1695 1625 -568 -725 -650 -381 1086 487 -7 809 714 959 368 -433 -1060 -1397 -4 -972 -1572 -1969 -2301 -1374 -589 -740 -100 728 1023 428 344 389 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