File name: Pandora170s1_Downsview_20210826_L2Fit_fout2c1d20210826p1-8.txt File generation date: 20260323T064809.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v4d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210826.txt Level 1 file used: Pandora170s1_Downsview_20210826_L1_smca1c1d20210826p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210826 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2804 305.4214 305.5624 305.7034 305.8444 305.9854 306.1263 306.2673 306.4082 306.5491 306.6900 306.8310 306.9718 307.1127 307.2536 307.3945 307.5353 307.6762 307.8170 307.9578 308.0986 308.2394 308.3802 308.5210 308.6617 308.8025 308.9432 309.0839 309.2247 309.3654 309.5061 309.6467 309.7874 309.9281 310.0687 310.2094 310.3500 310.4906 310.6312 310.7718 310.9124 311.0530 311.1935 311.3341 311.4746 311.6151 311.7557 311.8962 312.0367 312.1771 312.3176 312.4581 312.5985 312.7390 312.8794 313.0198 313.1602 313.3006 313.4410 313.5814 313.7217 313.8621 314.0024 314.1428 314.2831 314.4234 314.5637 314.7040 314.8442 314.9845 315.1247 315.2650 315.4052 315.5454 315.6856 315.8258 315.9660 316.1062 316.2463 316.3865 316.5266 316.6667 316.8069 316.9470 317.0871 317.2271 317.3672 317.5073 317.6473 317.7874 317.9274 318.0674 318.2074 318.3474 318.4874 318.6273 318.7673 318.9072 319.0472 319.1871 319.3270 319.4669 319.6068 319.7467 319.8866 320.0264 320.1663 320.3061 320.4459 320.5857 320.7255 320.8653 321.0051 321.1449 321.2846 321.4244 321.5641 321.7038 321.8435 321.9832 322.1229 322.2626 322.4023 322.5419 322.6816 322.8212 322.9608 323.1004 323.2400 323.3796 323.5192 323.6587 323.7983 323.9378 324.0774 324.2169 324.3564 324.4959 324.6354 324.7748 324.9143 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210826T170127.0Z 7908.709340 15 1 3.95 2 33.86 171.97 111.99 302.18 0.00 1 0.00 1 0 17 1.096e-02 8.617e-03 3.065e-03 2.241e-03 1.574903e-01 1.187455e-03 1.963432e-03 -6.000000e+00 6.468281e-03 230.89 -2.00 3.57 -2.00 314.66 0.00e+00 3.183691e-04 9.552885e-05 2.485888e-05 -6.000000e+00 2.864779e-04 286.54 -2.00 20.00 -2.00 314.03 0.00e+00 1.203 0.000 302.00 328.00 3 3.2135e+00 3.0512e-03 1.4491e-02 -6.0000e+00 1.6166e-02 9.0002e-03 3.3702e-03 8.3594e-03 -6.0000e+00 1.7471e-02 -6.1426e-03 1.9305e-03 4.0648e-03 -6.0000e+00 1.0403e-02 -2.0470e-03 8.4297e-04 1.1293e-03 -6.0000e+00 4.4259e-03 5.7548e-03 -1.4498e-05 6.5632e-05 1.6131e-05 -6.0000e+00 3.1119e-04 -1.2881e-03 4.6249e-05 12 9 1 2 9 1 97.26 22.51 0.18 -0.00129 -0.00140 6 19 1 5 0 538.770 26.41 20.00 22.51 39.94 19.4 1000.10 602 1127 -2027 -3226 -2270 -841 1360 1756 639 -2077 -2386 51 -57 777 630 -567 1020 205 1359 1328 -173 -220 1457 1688 892 768 -392 -830 -290 2153 1159 2130 1381 -3531 -2930 -2153 -2325 -892 -209 -1016 -1128 -561 -996 -623 144 -462 -925 -127 -604 605 1007 797 1103 770 1041 897 488 -188 353 744 1163 1315 2033 794 -968 -157 -414 94 1335 -467 609 612 1098 969 -395 -524 -919 -469 488 -1773 -1300 -2551 -2050 -785 -877 -689 -21 674 481 204 651 63 566 813 312 523 1159 271 -641 -371 -529 -1074 -79 -537 -1932 -1004 -643 -724 452 398 33 426 66 180 234 888 64 540 344 -494 -180 837 447 277 980 -283 1708 974 140 234 -428 -37 259 433 -470 -331 336 -159 -561 8 -496 -708 230 441 -788 -1175 -768 -282 474 665 255 -851 -959 21 -25 365 317 -295 530 109 731 724 -96 -121 810 970 525 455 -229 -463 -154 1134 632 1194 800 -2049 -1645 -1226 -1443 -606 -155 -812 -929 -468 -838 -524 121 -384 -755 -101 -476 478 815 670 949 674 923 802 439 -168 313 668 1069 1259 2001 794 -944 -145 -367 84 1254 -470 629 638 1134 971 -380 -476 -794 -402 438 -1705 -1320 -2713 -2228 -881 -1023 -832 -25 831 589 241 731 67 579 838 335 591 1372 336 -801 -451 -618 -1222 -90 -637 -2394 -1275 -832 -956 613 550 46 586 88 228 285 1058 78 681 452 -666 -245 1114 586 354 1213 -343 2022 1179 177 303 -562 -49 345 594 -666 -477 489 -235 -824 11 -707 -998 SS 20210826T170713.1Z 7908.713346 18 1 50.17 2 33.74 174.51 112.81 303.38 0.00 1 0.00 1 0 17 1.078e-02 8.336e-03 3.553e-04 2.593e-04 1.567425e-01 1.374438e-04 1.947258e-03 -6.000000e+00 6.361097e-03 230.89 -2.00 3.57 -2.00 314.66 0.00e+00 3.707618e-04 1.112393e-05 2.560425e-05 -6.000000e+00 2.816737e-04 286.54 -2.00 20.00 -2.00 314.04 0.00e+00 1.202 0.000 302.00 328.00 3 1.6468e+00 3.5304e-04 1.4445e-02 -6.0000e+00 1.5898e-02 2.1891e-03 3.8974e-04 8.3063e-03 -6.0000e+00 1.7180e-02 -6.0986e-03 2.2327e-04 4.0331e-03 -6.0000e+00 1.0230e-02 -1.8511e-03 9.7568e-05 1.1243e-03 -6.0000e+00 4.3531e-03 2.7723e-02 2.2066e-04 7.6165e-06 1.5746e-05 -6.0000e+00 3.0596e-04 -1.3922e-03 9.1432e-05 11 8 0 0 0 0 99.95 22.50 0.22 -0.00139 0.00027 521 108 1 5 0 95.180 26.41 20.00 22.50 40.39 19.4 1000.89 814 918 -824 -3950 -1898 -595 904 1484 557 -2164 -2318 -167 -291 548 855 -263 439 966 1038 1452 -343 942 1536 998 1085 1146 -515 -687 -64 1367 1159 1888 1128 -3960 -3023 -2366 -2626 -962 -309 -1150 -1179 -513 -767 -686 131 -726 -587 -621 -747 712 896 496 1464 855 924 1280 517 134 346 586 1205 1568 2027 971 -874 82 -751 217 1495 153 501 461 754 497 -250 -330 -1095 -686 -349 -1520 -1308 -2094 -2252 -795 -718 -422 181 676 477 296 691 -185 266 606 93 266 1032 389 -708 -222 -708 -967 23 -309 -1862 -850 -814 -609 412 423 386 243 269 142 240 626 91 341 258 -420 -113 536 456 533 815 -152 1375 1026 -4 214 -222 -142 20 307 -152 -420 523 -37 -443 -106 -521 -746 305 354 -312 -1486 -634 -195 317 577 217 -863 -905 -67 -128 268 424 -137 231 518 571 814 -195 527 877 562 633 672 -293 -386 -33 703 626 1071 668 -2375 -1698 -1362 -1607 -645 -228 -900 -973 -432 -656 -584 110 -602 -468 -502 -590 563 744 412 1259 762 835 1111 454 116 312 537 1098 1529 1984 970 -835 74 -671 195 1391 152 526 470 788 494 -240 -299 -967 -597 -310 -1448 -1302 -2255 -2432 -897 -831 -497 221 831 574 350 776 -199 277 637 101 301 1218 474 -878 -272 -845 -1092 26 -360 -2358 -1069 -1067 -795 560 577 535 339 351 176 287 760 109 436 341 -561 -152 730 599 693 1003 -187 1628 1263 -5 282 -288 -186 26 416 -218 -602 761 -55 -654 -151 -754 -1058 SS 20210826T172907.0Z 7908.728554 30 1 50.06 2 33.70 184.23 115.85 308.09 0.00 1 0.00 1 0 17 1.086e-02 8.345e-03 2.954e-04 2.155e-04 1.567999e-01 1.143083e-04 1.946483e-03 -6.000000e+00 6.408828e-03 230.89 -2.00 3.57 -2.00 314.66 0.00e+00 3.624371e-04 9.232462e-06 2.267894e-05 -6.000000e+00 2.838775e-04 286.54 -2.00 20.00 -2.00 314.04 0.00e+00 1.201 0.000 302.00 328.00 3 1.2788e+00 2.9365e-04 1.4439e-02 -6.0000e+00 1.6017e-02 8.6473e-04 3.2421e-04 8.3033e-03 -6.0000e+00 1.7311e-02 -5.7303e-03 1.8565e-04 4.0311e-03 -6.0000e+00 1.0307e-02 -1.7437e-03 8.1118e-05 1.1232e-03 -6.0000e+00 4.3850e-03 4.0077e-02 -1.3582e-04 6.3306e-06 1.5828e-05 -6.0000e+00 3.0836e-04 -1.1319e-03 2.8812e-05 11 8 0 0 0 0 90.92 22.49 0.24 -0.00113 -0.00215 755 157 1 5 0 65.600 26.41 20.00 22.49 41.53 19.3 998.00 825 831 -874 -4006 -2003 -665 867 1542 529 -2275 -2468 -198 -473 680 872 -332 519 1099 1011 1475 -258 1010 1537 1078 1104 1144 -465 -716 -4 1347 1157 1948 1135 -3960 -3032 -2303 -2535 -912 -245 -1149 -1165 -531 -714 -695 164 -724 -581 -628 -700 712 925 548 1439 886 933 1303 504 155 327 582 1188 1519 1975 1007 -957 35 -796 104 1502 108 488 430 705 525 -214 -303 -1092 -596 -323 -1504 -1304 -2089 -2262 -797 -706 -454 197 627 499 259 728 -166 269 615 142 298 1047 400 -716 -208 -688 -969 -10 -277 -1865 -902 -861 -621 383 409 361 239 282 145 266 652 97 366 255 -427 -86 570 423 529 886 -158 1399 1012 -5 209 -251 -142 22 265 -152 -444 475 -12 -435 -79 -496 -736 310 322 -331 -1510 -671 -218 305 601 206 -910 -967 -79 -210 311 434 -174 274 590 557 828 -147 565 879 608 645 672 -265 -403 -2 695 626 1106 673 -2380 -1707 -1329 -1555 -613 -181 -901 -964 -448 -611 -593 138 -603 -464 -510 -553 564 730 457 1241 791 804 1135 443 135 296 508 1086 1487 1940 1009 -917 32 -714 93 1402 108 514 441 739 524 -206 -275 -968 -520 -288 -1437 -1303 -2257 -2451 -903 -821 -537 241 774 604 308 821 -179 281 648 154 339 1240 489 -892 -257 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