File name: Pandora170s1_Downsview_20210924_L2Fit_fout2c1d20210826p1-8.txt File generation date: 20260323T100535.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210826.txt Level 1 file used: Pandora170s1_Downsview_20210924_L1_smca1c1d20210826p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20210924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2804 305.4214 305.5624 305.7034 305.8444 305.9854 306.1263 306.2673 306.4082 306.5491 306.6900 306.8310 306.9718 307.1127 307.2536 307.3945 307.5353 307.6762 307.8170 307.9578 308.0986 308.2394 308.3802 308.5210 308.6617 308.8025 308.9432 309.0839 309.2247 309.3654 309.5061 309.6467 309.7874 309.9281 310.0687 310.2094 310.3500 310.4906 310.6312 310.7718 310.9124 311.0530 311.1935 311.3341 311.4746 311.6151 311.7557 311.8962 312.0367 312.1771 312.3176 312.4581 312.5985 312.7390 312.8794 313.0198 313.1602 313.3006 313.4410 313.5814 313.7217 313.8621 314.0024 314.1428 314.2831 314.4234 314.5637 314.7040 314.8442 314.9845 315.1247 315.2650 315.4052 315.5454 315.6856 315.8258 315.9660 316.1062 316.2463 316.3865 316.5266 316.6667 316.8069 316.9470 317.0871 317.2271 317.3672 317.5073 317.6473 317.7874 317.9274 318.0674 318.2074 318.3474 318.4874 318.6273 318.7673 318.9072 319.0472 319.1871 319.3270 319.4669 319.6068 319.7467 319.8866 320.0264 320.1663 320.3061 320.4459 320.5857 320.7255 320.8653 321.0051 321.1449 321.2846 321.4244 321.5641 321.7038 321.8435 321.9832 322.1229 322.2626 322.4023 322.5419 322.6816 322.8212 322.9608 323.1004 323.2400 323.3796 323.5192 323.6587 323.7983 323.9378 324.0774 324.2169 324.3564 324.4959 324.6354 324.7748 324.9143 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210924T135359.4Z 7937.579159 313 1 24.52 2 62.25 121.55 82.53 281.38 0.00 1 0.00 1 0 17 1.878e-02 9.501e-03 9.575e-03 2.927e-03 2.794293e-01 1.505832e-03 3.403613e-03 -6.000000e+00 1.095884e-02 227.97 -2.00 3.57 -2.00 317.28 0.00e+00 1.019782e-03 2.183409e-04 7.968255e-05 -6.000000e+00 4.850880e-04 283.74 -2.00 20.00 -2.00 316.54 0.00e+00 2.136 0.000 302.00 328.00 3 4.3570e+00 3.9721e-03 2.5539e-02 -6.0000e+00 2.7223e-02 3.9709e-02 4.4611e-03 1.4672e-02 -6.0000e+00 2.9501e-02 6.9985e-03 2.6970e-03 7.1968e-03 -6.0000e+00 1.7579e-02 -1.1298e-02 1.3380e-03 2.1653e-03 -6.0000e+00 7.5029e-03 5.8962e-04 1.9611e-04 8.6980e-05 2.4506e-05 -6.0000e+00 5.3273e-04 5.7550e-04 3.3846e-05 12 9 9 2 1 1 99.98 22.38 0.47 0.00058 0.00205 12 6 1 5 0 1872.220 26.32 20.00 22.38 18.30 19.8 990.92 2525 3898 29 275 -4866 6702 7316 3089 -231 2281 -2142 -5838 1630 -2714 -2184 214 4533 -1272 1297 54 -141 -1160 2507 1306 1609 911 -1110 2744 -3872 1579 2791 2841 -924 -4998 -2326 -5756 -1194 -3877 141 -1791 -988 -2127 277 -79 -96 -1502 -1664 372 118 617 1478 1448 1519 50 846 740 -414 237 1275 818 2920 1856 1398 1069 -1563 11 -1037 290 1181 455 1020 1286 1543 562 -147 -348 -2036 -165 71 -1737 -1217 -3122 -2277 -386 -1294 -84 723 808 677 -38 647 -264 75 1034 -220 25 1855 719 -412 -72 -267 -957 -360 -538 -2130 -1312 -870 -818 798 366 126 504 -156 5 -382 1006 -147 384 152 -951 113 256 954 505 848 -587 1365 1276 663 47 -422 -478 -217 294 -58 -349 858 -28 -507 149 -623 -577 260 419 3 28 -480 600 714 351 -29 285 -281 -859 257 -507 -453 46 986 -304 313 14 -36 -298 647 360 461 267 -321 730 -1058 424 799 878 -309 -1694 -743 -1964 -439 -1689 68 -958 -554 -1236 161 -46 -56 -887 -968 211 67 360 900 930 1017 35 597 531 -301 170 901 588 2156 1468 1173 913 -1320 9 -802 228 995 415 967 1227 1445 509 -126 -276 -1565 -126 59 -1577 -1183 -3241 -2438 -425 -1500 -101 884 993 820 -45 714 -277 76 1063 -242 30 2310 946 -550 -94 -327 -1130 -425 -667 -2774 -1754 -1194 -1157 1164 555 194 768 -230 8 -514 1327 -200 540 224 -1433 169 377 1369 706 1149 -777 1772 1713 938 69 -636 -730 -339 471 -96 -593 1467 -48 -870 250 -1026 -936 SS 20210924T143906.2Z 7937.610488 341 1 8.35 2 55.75 132.32 90.07 288.90 0.00 1 0.00 1 0 17 1.289e-02 8.574e-03 3.896e-03 2.002e-03 2.341756e-01 1.038119e-03 2.892885e-03 -6.000000e+00 7.522317e-03 227.96 -2.00 3.57 -2.00 316.08 0.00e+00 5.572222e-04 1.118739e-04 8.130788e-05 -6.000000e+00 3.330161e-04 283.73 -2.00 20.00 -2.00 315.38 0.00e+00 1.771 0.000 302.00 328.00 3 3.1106e+00 2.6885e-03 2.1238e-02 -6.0000e+00 1.8686e-02 3.2061e-02 2.9973e-03 1.2236e-02 -6.0000e+00 2.0251e-02 -6.1644e-03 1.7323e-03 6.0028e-03 -6.0000e+00 1.2067e-02 -3.0148e-03 8.0322e-04 1.7033e-03 -6.0000e+00 5.1497e-03 3.1652e-03 -5.1091e-05 5.8966e-05 2.1559e-05 -6.0000e+00 3.6572e-04 1.1496e-03 2.6911e-05 12 9 1 2 1 1 99.46 22.38 0.28 0.00115 0.00077 12 16 1 5 0 628.530 26.32 20.00 22.38 19.16 19.8 989.03 918 1330 -636 -6604 -1972 -314 566 -146 -969 -3239 -3290 189 -1456 761 -606 617 473 1923 1204 1413 -277 681 2252 222 1472 919 -12 -1407 659 1711 812 2071 1016 -3785 -3570 -2698 -3082 -745 -619 -724 -1213 -575 -802 -243 -44 -875 -132 -626 -845 748 1244 510 1435 798 900 1553 616 511 298 916 1568 1827 2442 865 -1087 292 -711 -286 1596 445 482 419 979 614 -358 -697 -1767 -816 -484 -1459 -1138 -2171 -2583 -1366 -772 -167 252 505 386 153 591 -286 -88 622 290 242 986 738 -1154 -102 -764 -627 64 -655 -2006 -907 -518 -550 671 401 559 206 537 10 144 606 33 540 -39 -274 106 420 359 862 860 -218 1198 1150 -25 56 -88 -369 216 338 -302 -604 651 22 -453 -203 -729 -486 189 284 -135 -1370 -365 -57 113 -32 -226 -778 -788 47 -407 233 -201 214 170 705 450 542 -108 263 888 92 632 393 -5 -573 256 668 337 896 457 -1731 -1579 -1228 -1545 -412 -383 -478 -842 -409 -573 -172 -32 -624 -92 -428 -582 522 891 385 1111 635 720 1257 505 413 242 750 1312 1604 2247 814 -1001 253 -599 -243 1440 433 483 426 980 590 -329 -602 -1472 -676 -427 -1380 -1141 -2283 -2835 -1534 -902 -201 312 621 470 182 660 -305 -90 650 319 283 1209 943 -1498 -128 -928 -731 75 -803 -2577 -1181 -694 -755 944 584 823 300 754 14 185 766 43 725 -54 -390 150 593 495 1161 1126 -277 1512 1485 -34 77 -124 -529 315 502 -467 -949 1034 34 -725 -317 -1126 -736 SS 20210924T144341.2Z 7937.613671 344 1 49.59 2 55.14 133.51 90.82 289.68 0.00 1 0.00 1 0 17 2.630e-02 1.042e-02 1.503e-02 4.517e-03 2.353478e-01 2.315674e-03 2.844590e-03 -6.000000e+00 1.534739e-02 227.96 -2.00 3.57 -2.00 317.59 0.00e+00 3.773029e-04 3.569570e-04 5.671676e-05 -6.000000e+00 6.793751e-04 283.73 -2.00 20.00 -2.00 316.83 0.00e+00 1.744 0.000 302.00 328.00 3 5.4958e+00 6.1414e-03 2.1060e-02 -6.0000e+00 3.8124e-02 2.0550e-02 6.9167e-03 1.2287e-02 -6.0000e+00 4.1316e-02 3.5986e-02 4.2045e-03 6.0286e-03 -6.0000e+00 2.4619e-02 -2.4905e-02 2.0854e-03 1.7289e-03 -6.0000e+00 1.0507e-02 2.9538e-04 2.0852e-04 1.3757e-04 2.0045e-05 -6.0000e+00 7.4610e-04 5.8444e-04 2.5717e-05 12 8 8 0 0 0 99.99 22.38 0.75 0.00058 0.00215 152 32 1 5 0 326.200 26.32 20.00 22.38 19.33 19.8 990.46 1566 17502 3117 3015 -3983 9154 3354 3757 3020 4415 -4120 -2684 6836 -2325 -2671 2618 4222 -2559 1683 133 1352 -2099 1868 828 301 4868 735 4347 -836 -255 1358 3897 -1584 -6970 -517 -4617 -215 -4295 1506 -3863 -2700 -2856 -3464 727 -1218 -1016 -3849 623 -909 -173 1817 1331 1511 -406 907 1640 -1378 1546 2096 430 3088 2451 911 2008 -1728 -104 -1598 2264 983 61 396 810 1901 195 -230 -170 -751 -297 859 -2273 -850 -2584 -2334 -688 -1194 738 1111 1078 588 532 770 298 5 1229 -439 81 1516 397 -1044 537 -389 -1488 526 -132 -1482 -1320 -985 -1002 749 -100 -273 169 207 76 -594 1258 -202 163 242 -12 -245 -61 608 -44 799 -1211 1586 657 538 -138 -372 -573 -48 432 -73 -681 986 926 -283 164 -753 -605 171 1738 344 306 -401 832 352 437 379 552 -558 -383 1008 -419 -532 529 869 -579 380 31 316 -511 455 216 82 1289 196 1058 -205 -63 357 1072 -480 -2162 -145 -1398 -71 -1713 661 -1976 -1442 -1579 -1959 396 -676 -559 -2121 324 -475 -93 1010 785 936 -265 596 1090 -948 1023 1371 289 2141 1841 734 1631 -1387 -77 -1143 1602 775 53 362 748 1705 169 -184 -124 -519 -206 641 -1933 -779 -2568 -2420 -745 -1378 881 1368 1340 720 619 830 297 5 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