File name: Pandora170s1_Downsview_20211013_L2Fit_fwvt1c1d20210826p1-8.txt File generation date: 20260323T101016.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210826.txt Level 1 file used: Pandora170s1_Downsview_20211013_L1_smca1c1d20210826p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211013 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0792 492.2005 492.3217 492.4430 492.5642 492.6854 492.8066 492.9278 493.0489 493.1701 493.2912 493.4123 493.5334 493.6545 493.7755 493.8965 494.0176 494.1386 494.2596 494.3805 494.5015 494.6224 494.7433 494.8643 494.9851 495.1060 495.2269 495.3477 495.4685 495.5893 495.7101 495.8309 495.9516 496.0724 496.1931 496.3138 496.4345 496.5552 496.6758 496.7964 496.9171 497.0377 497.1583 497.2788 497.3994 497.5199 497.6404 497.7609 497.8814 498.0019 498.1223 498.2428 498.3632 498.4836 498.6040 498.7243 498.8447 498.9650 499.0853 499.2056 499.3259 499.4462 499.5664 499.6867 499.8069 499.9271 500.0473 500.1674 500.2876 500.4077 500.5278 500.6479 500.7680 500.8880 501.0081 501.1281 501.2481 501.3681 501.4881 501.6081 501.7280 501.8479 501.9679 502.0877 502.2076 502.3275 502.4473 502.5671 502.6870 502.8067 502.9265 503.0463 503.1660 503.2857 503.4054 503.5251 503.6448 503.7645 503.8841 504.0037 504.1233 504.2429 504.3625 504.4820 504.6016 504.7211 504.8406 504.9601 505.0796 505.1990 505.3184 505.4379 505.5573 505.6766 505.7960 505.9154 506.0347 506.1540 506.2733 506.3926 506.5118 506.6311 506.7503 506.8695 506.9887 507.1079 507.2271 507.3462 507.4653 507.5844 507.7035 507.8226 507.9417 508.0607 508.1797 508.2987 508.4177 508.5367 508.6557 508.7746 508.8935 509.0124 509.1313 509.2502 509.3690 509.4879 509.6067 509.7255 509.8443 509.9630 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211013T150003.8Z 7956.625044 156 1 5.82 2 58.91 143.45 137.30 80.52 0.00 1 0.00 1 0 15 2.887e-03 2.866e-03 7.653e-04 7.640e-04 2.902636e+03 4.428214e+01 2.078786e+02 -6.000000e+00 1.533672e+02 281.35 -2.00 20.00 -2.00 505.27 0.00e+00 8.149796e-04 2.061629e-05 4.772848e-05 -6.000000e+00 7.955883e-05 281.35 -2.00 20.00 -2.00 500.48 0.00e+00 1.767648e-03 1.474077e-02 2.237424e-02 -6.000000e+00 5.594416e-02 225.67 -2.00 3.57 -2.00 502.06 0.00e+00 1.929 0.000 489.00 513.00 1 4.7034e+00 1.1272e-03 3.4819e-03 -6.0000e+00 4.2801e-03 1.3616e-02 2.9398e-04 5.3711e-04 -6.0000e+00 1.1205e-03 1.3367e-02 7.3738e-04 6.5285e-05 3.0116e-05 -6.0000e+00 2.5379e-04 -5.5192e-03 9.5035e-05 12 1 1 2 1 1 78.56 22.46 1.02 -0.00552 -0.00040 14 27 1 4 0 376.190 26.41 20.01 22.46 26.97 20.9 994.29 -564 -476 -70 51 110 452 478 443 257 343 237 -69 -407 -147 -121 -292 -167 72 -147 68 267 117 130 228 148 230 407 -96 -507 -82 -160 -478 202 174 72 262 299 80 20 -23 14 78 79 177 189 71 241 118 43 -484 -415 -647 -560 -358 -328 -303 88 69 109 139 410 391 114 234 147 -55 140 -57 -441 -112 -99 -178 -21 -105 -45 -118 114 -384 -553 -315 -331 -420 -219 -17 -92 -183 -299 19 -150 -92 33 415 185 143 464 226 17 -447 -516 -450 -557 -343 -116 -331 -219 172 -280 -298 -200 -176 -245 92 291 326 484 771 591 325 360 420 137 335 337 15 125 300 179 134 474 61 -68 184 -160 -440 -67 -11 -72 -278 204 271 120 122 184 198 75 -177 -372 -315 -264 -450 -552 -466 -70 53 113 471 506 463 267 358 244 -71 -417 -148 -122 -296 -172 74 -153 71 279 122 136 239 156 242 424 -99 -519 -82 -160 -481 204 179 76 275 310 82 20 -23 15 79 82 184 199 74 250 121 44 -485 -410 -628 -539 -350 -325 -310 89 71 111 141 415 398 116 239 148 -56 140 -56 -431 -110 -97 -175 -21 -104 -45 -116 112 -372 -534 -304 -321 -412 -211 -17 -90 -181 -297 19 -148 -92 32 414 187 144 457 224 17 -431 -486 -427 -521 -328 -113 -329 -220 171 -275 -293 -196 -171 -243 93 289 325 484 774 598 329 358 419 135 324 327 15 123 295 176 131 462 60 -65 177 -152 -416 -63 -10 -70 -276 200 267 119 121 183 198 74 -175 -365 -300 -254 -428 SQ 20211013T150425.3Z 7956.628070 159 1 6.51 2 58.45 144.59 136.56 81.36 0.00 1 0.00 1 0 15 2.602e-03 2.587e-03 1.515e-04 1.512e-04 2.725041e+03 8.702768e+00 1.969863e+02 -6.000000e+00 1.381848e+02 281.35 -2.00 20.00 -2.00 505.27 0.00e+00 8.091011e-04 4.076153e-06 4.729420e-05 -6.000000e+00 7.168936e-05 281.35 -2.00 20.00 -2.00 500.49 0.00e+00 2.263617e-02 2.918200e-03 2.091176e-02 -6.000000e+00 5.041624e-02 225.67 -2.00 3.57 -2.00 502.08 0.00e+00 1.904 0.000 489.00 513.00 1 1.6359e+00 2.2308e-04 3.3859e-03 -6.0000e+00 3.8570e-03 4.5659e-03 5.8183e-05 5.0520e-04 -6.0000e+00 1.0099e-03 2.8791e-01 8.2513e-04 1.2924e-05 2.9005e-05 -6.0000e+00 2.2873e-04 -4.2973e-03 7.7820e-05 10 0 0 0 0 0 97.14 22.46 1.00 -0.00430 0.00143 546 113 1 4 0 11.420 26.41 20.00 22.46 27.13 20.9 993.64 -536 -384 -27 41 208 466 383 395 181 338 288 -130 -335 -174 -195 -223 -114 4 -144 4 211 92 120 196 117 315 355 -186 -416 11 -64 -411 153 193 18 215 306 11 -80 10 -49 1 44 210 234 131 202 184 -113 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-400 -133 39 -120 72 244 65 144 173 165 203 118 -179 -323 -288 -280 -454 SQ 20211013T150432.1Z 7956.628149 159 2 6.54 2 58.43 144.62 136.54 81.38 0.00 1 0.00 1 0 15 2.530e-03 2.513e-03 2.470e-04 2.466e-04 2.749808e+03 1.424239e+01 2.000971e+02 -6.000000e+00 1.343725e+02 281.35 -2.00 20.00 -2.00 505.27 0.00e+00 8.231788e-04 6.646157e-06 4.790980e-05 -6.000000e+00 6.971266e-05 281.35 -2.00 20.00 -2.00 500.48 0.00e+00 2.176275e-02 4.762290e-03 2.075542e-02 -6.000000e+00 4.902701e-02 225.67 -2.00 3.57 -2.00 502.06 0.00e+00 1.903 0.000 489.00 513.00 1 2.5639e+00 3.6410e-04 3.3856e-03 -6.0000e+00 3.7508e-03 5.9706e-03 9.5031e-05 5.0438e-04 -6.0000e+00 9.8214e-04 1.1381e-01 8.4611e-04 2.1111e-05 2.9626e-05 -6.0000e+00 2.2243e-04 -4.2692e-03 7.6063e-05 10 0 0 0 0 0 98.96 22.46 0.94 -0.00427 0.00160 546 113 1 4 0 11.420 26.41 20.00 22.46 27.13 20.9 993.64 -519 -359 7 28 174 443 352 337 196 297 348 -158 -310 -210 -177 -191 -136 -8 -135 20 229 90 72 201 128 304 330 -209 -423 -12 -11 -400 165 197 3 215 268 12 -94 81 -76 -14 60 235 203 143 180 211 -99 -385 -450 -530 -502 -308 -340 -257 -18 161 169 188 366 227 253 135 101 83 137 -56 -367 -168 -42 -209 -149 -127 -137 -132 134 -302 -443 -301 -161 -424 -313 -17 -158 -191 -260 -52 -31 -96 135 293 77 123 422 292 -46 -300 -432 -380 -404 -427 -192 -328 -169 109 -163 -181 -45 -88 -139 163 230 299 407 590 497 231 342 321 111 68 223 0 22 261 177 226 456 -9 -83 153 -120 -391 -103 29 -153 52 274 55 194 174 169 196 85 -162 -332 -314 -301 -442 -498 -352 7 29 181 454 367 354 204 305 364 -163 -316 -211 -177 -192 -140 -8 -141 21 240 95 76 212 136 322 347 -218 -427 -12 -11 -402 170 204 3 228 281 12 -96 83 -77 -14 62 247 209 147 189 218 -100 -381 -445 -513 -483 -301 -333 -260 -18 166 174 193 375 235 262 139 103 83 135 -55 -355 -165 -41 -206 -145 -125 -136 -129 132 -294 -428 -291 -157 -417 -300 -16 -155 -188 -257 -51 -30 -95 135 297 77 122 423 288 -45 -291 -409 -354 -379 -412 -186 -322 -168 107 -163 -178 -44 -87 -136 162 230 302 412 599 508 236 344 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