File name: Pandora170s1_Downsview_20211107_L2Fit_fout2c1d20210826p1-8.txt File generation date: 20260323T101312.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20210826.txt Level 1 file used: Pandora170s1_Downsview_20211107_L1_smca1c1d20210826p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1394 305.2804 305.4214 305.5624 305.7034 305.8444 305.9854 306.1263 306.2673 306.4082 306.5491 306.6900 306.8310 306.9718 307.1127 307.2536 307.3945 307.5353 307.6762 307.8170 307.9578 308.0986 308.2394 308.3802 308.5210 308.6617 308.8025 308.9432 309.0839 309.2247 309.3654 309.5061 309.6467 309.7874 309.9281 310.0687 310.2094 310.3500 310.4906 310.6312 310.7718 310.9124 311.0530 311.1935 311.3341 311.4746 311.6151 311.7557 311.8962 312.0367 312.1771 312.3176 312.4581 312.5985 312.7390 312.8794 313.0198 313.1602 313.3006 313.4410 313.5814 313.7217 313.8621 314.0024 314.1428 314.2831 314.4234 314.5637 314.7040 314.8442 314.9845 315.1247 315.2650 315.4052 315.5454 315.6856 315.8258 315.9660 316.1062 316.2463 316.3865 316.5266 316.6667 316.8069 316.9470 317.0871 317.2271 317.3672 317.5073 317.6473 317.7874 317.9274 318.0674 318.2074 318.3474 318.4874 318.6273 318.7673 318.9072 319.0472 319.1871 319.3270 319.4669 319.6068 319.7467 319.8866 320.0264 320.1663 320.3061 320.4459 320.5857 320.7255 320.8653 321.0051 321.1449 321.2846 321.4244 321.5641 321.7038 321.8435 321.9832 322.1229 322.2626 322.4023 322.5419 322.6816 322.8212 322.9608 323.1004 323.2400 323.3796 323.5192 323.6587 323.7983 323.9378 324.0774 324.2169 324.3564 324.4959 324.6354 324.7748 324.9143 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211107T124952.1Z 7981.534631 60 1 49.16 2 83.15 120.66 116.10 101.38 0.00 1 0.00 1 0 17 4.664e-01 3.730e-02 3.069e-01 1.372e-02 8.262551e-01 8.312241e-03 1.043584e-02 -6.000000e+00 2.806085e-01 223.30 -2.00 3.57 -2.00 321.99 0.00e+00 1.770304e-02 4.523079e-03 5.795637e-03 -6.000000e+00 1.461654e-02 278.17 -2.00 20.00 -2.00 321.56 0.00e+00 7.668 0.009 302.00 328.00 3 1.4254e+00 3.0102e-02 8.8327e-02 -6.0000e+00 6.9287e-01 1.0185e+00 3.8068e-02 4.5718e-02 -6.0000e+00 7.5750e-01 -1.3816e+00 3.5067e-02 2.6671e-02 -6.0000e+00 4.4461e-01 5.6647e-01 1.7048e-02 1.5158e-02 -6.0000e+00 1.9413e-01 2.9710e-05 -1.6891e-03 4.1229e-04 3.3676e-04 -6.0000e+00 1.4752e-02 -2.1323e-02 1.0626e-04 12 8 8 0 0 0 16.67 22.31 0.80 -0.02132 -0.03401 21 4 1 5 0 2340.390 26.21 20.00 22.31 11.16 20.5 998.82 900000 900000 66771 -76465 165152 900000 900000 900000 -4170 900000 -134561 126479 900000 -53571 68246 19751 900000 -101755 900000 -40281 900000 900000 900000 100919 900000 900000 97141 900000 43039 900000 23713 900000 36903 -28463 51610 -57573 900000 64621 900000 106395 67338 30257 81014 900000 28572 120509 43606 900000 99914 117932 2995 92679 -1193 40747 68715 99779 7041 44622 63690 -34599 47475 70594 38414 53021 -14261 23045 5863 71501 2619 35397 30942 29851 49381 21295 -616 4291 -1113 -7169 20549 -1042 9990 -9126 5133 -382 3457 -9381 6369 -2342 10003 9936 386 1197 -22069 1768 -8491 -29 -4051 1684 -1270 -581 -773 -7433 975 -5366 -2484 -4698 -7029 -4468 2038 -1892 -1396 3315 -439 -4234 -1248 2668 791 1134 1060 2312 3618 85 3568 2347 -177 -1999 3288 450 3225 1568 759 644 -110 -1387 -3086 -37 1304 1964 1 645 -1796 -2130 900000 900000 889 -2838 2200 900000 900000 900000 -56 900000 -5483 1685 900000 -2042 988 531 900000 -10075 900000 -2207 900000 900000 900000 1344 900000 900000 1294 900000 761 900000 732 900000 1315 -1879 1459 -4487 900000 1878 900000 2584 2534 1694 2866 900000 1727 3072 2413 900000 3569 3797 317 4567 -153 3685 4862 5229 872 3719 4253 -5800 3921 5279 4477 5949 -3104 3522 1063 7415 577 6411 6166 6019 7901 4075 -130 789 -212 -1578 4114 -305 3069 -3764 1993 -165 1519 -4873 2954 -1192 4467 4240 169 502 -11627 822 -5061 -19 -3177 1415 -1162 -519 -639 -5879 673 -4044 -1943 -3960 -6448 -4387 2128 -2317 -1870 4485 -616 -5980 -1668 3420 1065 1602 1563 3388 5108 118 4703 3038 -230 -2566 4102 635 5095 2806 1491 1343 -244 -3290 -7829 -95 3314 4972 2 1536 -4101 -4641 SS 20211107T130109.0Z 7981.542465 63 1 50.01 2 81.41 122.76 114.22 103.08 0.00 1 0.00 1 0 25 5.310e-01 1.195e-02 3.112e-01 4.614e-03 7.475469e-01 2.649378e-03 8.808101e-03 -6.000000e+00 3.137268e-01 223.30 -2.00 3.57 -2.00 321.48 0.00e+00 5.951041e-03 1.370086e-03 3.807430e-03 -6.000000e+00 1.588745e-02 278.17 -2.00 20.00 -2.00 321.02 0.00e+00 6.319 0.005 302.00 328.00 3 1.2808e+00 9.2537e-03 7.4691e-02 -6.0000e+00 7.7887e-01 4.1837e-02 1.4170e-02 4.5028e-02 -6.0000e+00 8.5205e-01 -6.2283e-02 1.6165e-02 2.9562e-02 -6.0000e+00 5.0372e-01 1.6868e-02 7.5057e-03 1.2679e-02 -6.0000e+00 2.2127e-01 1.5678e-04 -2.6988e-04 1.3587e-04 1.8068e-04 -6.0000e+00 1.5647e-02 -2.1599e-02 8.9458e-05 12 8 8 0 0 0 17.29 22.32 0.54 -0.02160 -0.02363 60 12 1 5 0 833.420 26.21 20.00 22.32 11.80 20.5 999.23 900000 900000 900000 -294384 900000 -160271 900000 -110772 900000 900000 -280964 24202 900000 900000 -67001 900000 900000 -41581 900000 -83288 900000 237149 116637 58372 75760 11480 2065 99623 113835 49708 95707 22612 -41575 -51322 -14660 -51984 36286 -10112 27497 4861 2721 -9661 -13331 30096 -6606 -2602 3624 7392 15356 1659 5727 16720 3954 -6967 9009 3235 -5984 6441 5350 -43 17163 12830 1683 12615 -5734 -3125 -2513 9976 -458 3732 5606 1721 5342 -34 -2895 -2076 -1598 -3606 1143 -3629 -902 -1983 -1968 574 -1324 -620 2104 -821 2711 478 1206 -3048 -2231 -79 -1964 -405 1316 772 -317 349 -1538 -1342 789 -734 -1642 -1036 -326 -1480 921 64 352 413 239 -1525 378 738 686 943 215 794 -338 711 1058 350 -360 -1471 799 700 -200 321 -398 -640 -111 -180 -872 -530 969 579 -50 590 -708 -127 900000 900000 900000 -3594 900000 -719 900000 -497 900000 900000 -5182 109 900000 900000 -453 900000 900000 -352 900000 -1225 900000 1064 523 269 340 95 19 447 511 367 563 333 -1297 -1818 -361 -1893 655 -347 802 206 131 -559 -847 1313 -420 -166 231 484 1006 137 512 1510 442 -938 1104 435 -891 848 696 -6 2179 1915 320 2402 -1339 -708 -580 2216 -128 1123 1768 574 1668 -11 -832 -547 -417 -1039 366 -1444 -403 -998 -1065 323 -805 -394 1355 -548 1725 297 708 -1783 -1309 -49 -1429 -334 1226 799 -343 369 -1530 -1212 674 -658 -1577 -1038 -343 -1699 1142 88 521 630 364 -2283 539 1039 992 1417 339 1251 -524 1056 1526 494 -498 -2005 1087 1032 -332 582 -772 -1302 -237 -405 -2050 -1276 2340 1409 -119 1351 -1563 -270 SS 20211107T131627.3Z 7981.553094 68 1 49.76 2 79.13 125.67 111.69 105.37 0.00 1 0.00 1 0 25 2.904e-01 8.446e-03 7.187e-02 1.898e-03 6.243478e-01 1.004472e-03 7.354636e-03 -6.000000e+00 1.669240e-01 223.29 -2.00 3.57 -2.00 320.64 0.00e+00 3.775624e-03 4.082620e-04 1.863888e-03 -6.000000e+00 7.331542e-03 278.17 -2.00 20.00 -2.00 320.12 0.00e+00 5.111 0.003 302.00 328.00 3 9.4008e-01 3.1014e-03 5.9773e-02 -6.0000e+00 4.1110e-01 4.9222e-02 4.0603e-03 3.3972e-02 -6.0000e+00 4.4691e-01 -5.5087e-02 4.0852e-03 1.9785e-02 -6.0000e+00 2.6636e-01 1.0921e-02 2.0293e-03 7.8178e-03 -6.0000e+00 1.1466e-01 7.4611e-04 -3.7855e-04 5.3903e-05 9.6912e-05 -6.0000e+00 8.2168e-03 -2.1598e-02 7.3849e-05 11 8 0 0 0 0 99.58 22.32 0.30 -0.02160 -0.02444 149 31 1 5 0 333.910 26.32 20.00 22.32 12.58 20.6 998.77 -109743 -9550 -103091 -83636 -125524 -96379 -95780 -82286 -100686 -86506 -100201 -71778 -21701 -58137 -25331 -30983 -1030 -32429 -12492 -18718 7713 -908 -18728 -4400 -21154 -655 -18600 -6760 -19347 -22098 -1186 -924 1515 -12253 -6359 -22981 -7830 -2786 3593 1061 -1128 -2150 -1386 5458 786 5363 2002 5306 1815 3470 3557 2763 2807 1644 3789 2435 1155 -368 -571 -979 3028 3218 3762 3656 -873 -316 -1310 1706 1410 1843 1427 954 1292 347 -1377 -2394 -2494 -2158 -1239 -2356 -928 -2301 -2454 -932 -1077 613 1027 1092 1183 749 590 -835 -1003 -403 -716 -97 1247 865 125 -40 -1141 -1293 72 -90 -1564 -1271 -1200 -726 551 612 562 227 130 -533 -207 502 561 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