File name: Pandora170s1_Downsview_20211120_L2Fit_fout2c1d20211109p1-8.txt File generation date: 20260323T101414.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20211109.txt Level 1 file used: Pandora170s1_Downsview_20211120_L1_smca1c1d20211109p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1150 305.2561 305.3971 305.5381 305.6791 305.8201 305.9611 306.1020 306.2430 306.3839 306.5249 306.6658 306.8067 306.9476 307.0885 307.2294 307.3702 307.5111 307.6519 307.7928 307.9336 308.0744 308.2152 308.3560 308.4968 308.6375 308.7783 308.9190 309.0598 309.2005 309.3412 309.4819 309.6226 309.7633 309.9039 310.0446 310.1852 310.3259 310.4665 310.6071 310.7477 310.8883 311.0289 311.1694 311.3100 311.4505 311.5911 311.7316 311.8721 312.0126 312.1531 312.2936 312.4340 312.5745 312.7149 312.8554 312.9958 313.1362 313.2766 313.4170 313.5574 313.6977 313.8381 313.9784 314.1188 314.2591 314.3994 314.5397 314.6800 314.8203 314.9605 315.1008 315.2410 315.3813 315.5215 315.6617 315.8019 315.9421 316.0822 316.2224 316.3626 316.5027 316.6428 316.7830 316.9231 317.0632 317.2032 317.3433 317.4834 317.6234 317.7635 317.9035 318.0435 318.1835 318.3235 318.4635 318.6035 318.7434 318.8834 319.0233 319.1633 319.3032 319.4431 319.5830 319.7229 319.8627 320.0026 320.1424 320.2823 320.4221 320.5619 320.7017 320.8415 320.9813 321.1211 321.2608 321.4006 321.5403 321.6800 321.8197 321.9594 322.0991 322.2388 322.3785 322.5181 322.6578 322.7974 322.9370 323.0767 323.2163 323.3558 323.4954 323.6350 323.7745 323.9141 324.0536 324.1931 324.3326 324.4721 324.6116 324.7511 324.8906 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211120T133501.5Z 7994.565989 308 1 21.54 2 79.50 130.94 91.14 303.07 0.00 1 0.00 1 0 17 5.906e-01 1.291e-02 2.334e-01 5.640e-03 6.615575e-01 3.055013e-03 7.619451e-03 -6.000000e+00 3.423488e-01 222.50 -2.00 3.57 -2.00 320.92 0.00e+00 3.244876e-03 1.333246e-03 7.951937e-04 -6.000000e+00 1.627300e-02 276.58 -2.00 20.00 -2.00 320.44 0.00e+00 5.273 0.003 302.00 328.00 3 1.9487e+00 9.6616e-03 6.1992e-02 -6.0000e+00 8.4266e-01 5.5425e-02 1.3154e-02 3.5731e-02 -6.0000e+00 9.1858e-01 -7.8794e-02 1.3966e-02 2.0058e-02 -6.0000e+00 5.4304e-01 2.4821e-02 6.8245e-03 7.9946e-03 -6.0000e+00 2.3588e-01 2.2669e-04 -5.5996e-04 1.6300e-04 9.0283e-05 -6.0000e+00 1.7153e-02 3.2491e-03 -1.8857e-06 12 9 9 2 1 1 99.92 22.29 0.41 0.00325 -0.00096 18 9 1 5 0 1124.410 26.21 20.00 22.29 8.79 20.5 1005.73 196557 900000 900000 -202564 900000 -148848 900000 -192858 276367 900000 -178756 -155210 -74236 -47606 -88539 82781 57240 -38863 -34749 -37635 371312 21662 7155 -19310 54699 -33640 71034 28413 6147 11616 -19808 -5508 -21933 1100 80 -20084 -14367 6282 15573 -1474 6565 -12911 -5631 12603 11273 8281 2989 13518 6425 -3597 1523 3372 6306 -1415 -97 8182 -4232 6913 6974 1444 -365 6088 866 3329 -2805 -3009 529 5892 1467 1750 3360 1973 7013 1157 -2429 -3191 -2008 -2761 375 -2484 -1069 -3644 -3194 -2152 689 -31 1597 -839 2487 1149 2641 -1736 -1144 -993 -1865 679 208 1297 -32 907 -1956 -195 -396 295 -1753 -2587 -1638 -930 768 378 550 238 -56 -850 -193 1419 8 609 -321 -281 -72 1018 1076 653 297 -1564 1588 1392 577 -372 -381 -240 -26 -181 -10 -725 852 209 -505 371 -399 -345 1080 900000 900000 -3301 900000 -1411 900000 -3566 1518 900000 -3773 -3156 -907 -580 -1976 455 422 -795 -735 -861 2040 295 120 -456 691 -1021 804 478 133 269 -743 -214 -1113 46 3 -1045 -804 349 964 -123 561 -1407 -601 1163 1078 840 329 1413 757 -507 230 554 1096 -285 -20 1642 -970 1413 1391 307 -84 1480 248 1017 -924 -980 169 1912 556 739 1489 902 2977 486 -962 -1178 -719 -1061 161 -1267 -612 -2359 -2194 -1547 512 -24 1281 -694 1971 884 1903 -1239 -815 -757 -1598 645 222 1501 -39 1061 -2186 -199 -392 300 -1914 -2973 -1964 -1182 1050 562 868 384 -90 -1322 -288 2067 12 952 -522 -461 -116 1580 1631 968 430 -2237 2242 2106 964 -676 -730 -477 -55 -389 -23 -1673 1967 486 -1167 822 -851 -715 SS 20211120T134106.0Z 7994.570208 311 1 49.73 2 78.68 132.13 92.01 304.10 0.00 1 0.00 1 0 17 3.473e-01 9.955e-03 2.201e-01 4.572e-03 6.211938e-01 2.487755e-03 7.132150e-03 -6.000000e+00 2.025816e-01 222.50 -2.00 3.57 -2.00 320.92 0.00e+00 3.098620e-03 1.078647e-03 9.135098e-04 -6.000000e+00 9.610637e-03 276.58 -2.00 20.00 -2.00 320.44 0.00e+00 4.922 0.002 302.00 328.00 3 2.4828e+00 7.8818e-03 5.7950e-02 -6.0000e+00 4.9866e-01 -9.2314e-03 1.0719e-02 3.3537e-02 -6.0000e+00 5.4410e-01 2.8949e-02 1.1406e-02 1.9394e-02 -6.0000e+00 3.2045e-01 -2.1154e-02 5.5833e-03 8.1665e-03 -6.0000e+00 1.4063e-01 1.9134e-04 2.9249e-04 1.3684e-04 9.0925e-05 -6.0000e+00 1.0118e-02 1.4415e-03 1.5523e-04 12 9 8 1 8 0 99.99 22.30 0.40 0.00144 0.00364 80 17 1 5 0 621.460 26.21 20.00 22.30 9.02 20.6 1007.10 900000 900000 900000 -70786 36137 900000 900000 -73026 -93906 900000 -135515 -158388 230375 -15623 -5616 52100 109139 -25947 -22308 -46695 74411 39893 -23280 -17685 46680 -39433 58879 35327 13156 -17171 10558 13800 -9433 -26162 9077 -33583 11776 7759 9609 4368 -333 -9397 -7929 379 4196 14281 6966 6687 -348 923 2040 2773 3510 2872 -214 6114 -6932 4223 5425 -1281 5746 5246 1963 4331 -6029 -2853 -2885 5624 2003 1500 2080 -905 2811 901 -2524 78 -2621 604 -353 -1047 -2930 -2418 -2894 -917 -150 1591 986 -1601 1343 405 1909 -554 -488 424 -495 212 987 1365 -144 368 -603 -758 339 -542 -903 -1710 -1262 -1507 1065 210 301 353 162 -737 -113 625 368 159 -468 -387 516 229 1333 583 -270 -800 1207 693 -91 -105 -842 -142 -14 146 -115 -470 707 148 -475 529 -371 -136 900000 900000 900000 -350 161 900000 900000 -471 -826 900000 -2075 -3554 1026 -152 -62 391 533 -500 -448 -1234 657 501 -562 -444 702 -1356 834 613 289 -560 318 471 -446 -1482 366 -2063 549 449 653 358 -31 -1023 -892 40 446 1422 765 769 -45 127 310 464 634 559 -45 1265 -1640 894 1118 -283 1265 1299 563 1319 -2058 -927 -943 1811 745 630 927 -420 1234 378 -999 28 -937 221 -149 -518 -1675 -1530 -1955 -646 -111 1223 795 -1332 1071 313 1371 -385 -338 311 -411 198 1034 1558 -173 429 -656 -762 326 -547 -973 -1934 -1500 -1918 1441 313 475 570 257 -1131 -166 900 544 245 -757 -633 825 356 2003 854 -386 -1121 1665 1030 -150 -188 -1604 -280 -30 314 -260 -1091 1650 350 -1109 1180 -800 -283 SS 20211120T134538.3Z 7994.573360 314 1 19.45 2 78.07 133.03 92.66 304.88 0.00 1 0.00 1 0 17 2.678e-01 9.545e-03 1.956e-01 4.126e-03 5.857311e-01 2.184344e-03 6.867039e-03 -6.000000e+00 1.544020e-01 222.50 -2.00 3.57 -2.00 320.54 0.00e+00 3.024529e-03 8.416125e-04 9.516309e-04 -6.000000e+00 6.867553e-03 276.58 -2.00 20.00 -2.00 320.04 0.00e+00 4.692 0.002 302.00 328.00 3 1.8497e+00 6.5907e-03 5.4931e-02 -6.0000e+00 3.7955e-01 1.6319e-02 8.5124e-03 3.1157e-02 -6.0000e+00 4.1323e-01 -1.7167e-02 8.5764e-03 1.7362e-02 -6.0000e+00 2.4553e-01 -2.7393e-03 4.3130e-03 6.6930e-03 -6.0000e+00 1.0594e-01 4.6365e-04 -4.9137e-04 1.2033e-04 7.7549e-05 -6.0000e+00 7.6015e-03 3.9368e-03 -1.7030e-05 12 9 9 2 1 1 99.13 22.30 0.43 0.00394 0.00024 39 21 1 5 0 481.790 26.21 19.99 22.30 9.25 20.6 1007.31 -14601 900000 -88090 33697 -116265 900000 -108133 66589 -95282 -17065 -83239 -87338 84975 -61652 43604 -22355 73518 -45894 51948 -26255 30973 7260 -6573 35487 -27237 41165 -15329 34683 -14387 5544 -1844 11728 -2243 -13941 4907 -23495 14232 -4764 16330 -6496 1415 149 -9002 4160 3024 4995 -2105 7860 -3045 6758 714 5054 1446 -383 3997 1240 -1066 -4054 1687 -2445 6044 1293 2952 2956 -2337 -1601 -1365 4535 795 2549 1733 1360 729 -479 -2184 -1332 -457 -1473 -635 -2779 394 -2914 -1971 -2053 -520 92 1097 895 1595 1863 99 -127 -881 1057 -881 399 1126 467 411 -245 -949 -1877 433 -674 -1541 -1409 -1400 -154 792 828 -398 262 9 -65 -243 902 868 -187 406 -567 88 227 1329 419 87 -524 988 763 -738 -40 -398 -164 -725 214 -463 55 580 191 150 141 -270 -425 -64 900000 -945 136 -1481 900000 -1450 268 -1437 -126 -1283 -1668 404 -1488 453 -524 806 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