File name: Pandora170s1_Downsview_20211205_L2Fit_fwvt1c1d20211109p1-8.txt File generation date: 20260323T101723.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20211109.txt Level 1 file used: Pandora170s1_Downsview_20211205_L1_smca1c1d20211109p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20211205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1633 1782 Nominal wavelengths inside fitting window [nm]: 492.0697 492.1910 492.3123 492.4335 492.5547 492.6760 492.7972 492.9183 493.0395 493.1607 493.2818 493.4029 493.5240 493.6451 493.7662 493.8872 494.0082 494.1293 494.2503 494.3712 494.4922 494.6132 494.7341 494.8550 494.9759 495.0968 495.2176 495.3385 495.4593 495.5801 495.7009 495.8217 495.9425 496.0632 496.1840 496.3047 496.4254 496.5461 496.6667 496.7874 496.9080 497.0286 497.1492 497.2698 497.3903 497.5109 497.6314 497.7519 497.8724 497.9929 498.1134 498.2338 498.3542 498.4747 498.5950 498.7154 498.8358 498.9561 499.0765 499.1968 499.3171 499.4373 499.5576 499.6778 499.7981 499.9183 500.0385 500.1586 500.2788 500.3989 500.5191 500.6392 500.7592 500.8793 500.9994 501.1194 501.2394 501.3594 501.4794 501.5994 501.7194 501.8393 501.9592 502.0791 502.1990 502.3189 502.4387 502.5586 502.6784 502.7982 502.9180 503.0377 503.1575 503.2772 503.3969 503.5166 503.6363 503.7560 503.8756 503.9953 504.1149 504.2345 504.3540 504.4736 504.5932 504.7127 504.8322 504.9517 505.0712 505.1906 505.3101 505.4295 505.5489 505.6683 505.7877 505.9070 506.0264 506.1457 506.2650 506.3843 506.5036 506.6228 506.7421 506.8613 506.9805 507.0997 507.2188 507.3380 507.4571 507.5762 507.6953 507.8144 507.9335 508.0525 508.1716 508.2906 508.4096 508.5286 508.6475 508.7665 508.8854 509.0043 509.1232 509.2421 509.3610 509.4798 509.5986 509.7175 509.8362 509.9550 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211205T134956.5Z 8009.576348 82 1 49.31 2 80.34 134.38 95.11 122.74 0.00 1 0.00 1 0 15 3.018e-03 2.994e-03 4.466e-04 4.461e-04 2.779905e+03 2.512516e+01 1.963959e+02 -6.000000e+00 1.561932e+02 274.88 -2.00 20.00 -2.00 505.31 0.00e+00 1.146963e-03 1.186669e-05 6.323650e-05 -6.000000e+00 8.186405e-05 274.88 -2.00 20.00 -2.00 500.63 0.00e+00 5.467400e-01 8.564737e-03 2.540353e-02 -6.000000e+00 5.854778e-02 222.31 -2.00 3.57 -2.00 502.20 0.00e+00 5.690 0.003 489.00 513.00 1 5.4202e+00 6.5312e-04 8.3857e-03 -6.0000e+00 4.4691e-03 3.3499e-03 1.6996e-04 7.0879e-04 -6.0000e+00 1.1737e-03 3.6989e-03 5.7352e-04 3.8159e-05 3.3833e-05 -6.0000e+00 2.6534e-04 1.3345e-03 -1.8934e-05 10 0 0 0 0 0 99.30 22.20 1.03 0.00133 0.00531 53 11 1 4 0 929.050 26.11 20.00 22.20 6.15 20.5 1003.10 -576 -523 -350 -241 42 379 370 511 256 218 221 -154 -344 -327 -464 -394 -56 33 -164 25 160 123 181 286 223 335 559 60 -301 -262 -291 -286 297 129 15 251 288 66 124 64 -119 -6 104 306 323 269 286 249 292 -204 -476 -640 -629 -319 -202 -261 -10 140 179 264 522 302 384 228 125 -1 157 66 -270 -264 -336 -301 80 -51 -233 -221 3 -260 -460 -498 -389 -550 -204 -66 -224 -21 -271 -264 -202 -229 139 373 172 123 443 244 90 -156 -600 -622 -539 -344 -55 -153 -218 25 -189 -135 -11 -65 -6 195 255 321 392 662 678 482 397 317 156 205 277 61 120 197 102 285 595 85 -47 -4 -314 -289 -136 -232 -160 -83 133 -50 178 118 146 199 124 -105 -355 -473 -468 -484 -538 -498 -346 -237 42 388 386 518 259 226 225 -155 -342 -321 -453 -387 -56 34 -167 26 164 126 185 294 231 346 574 61 -309 -259 -284 -281 298 130 16 261 296 67 125 64 -119 -6 106 316 336 281 297 254 292 -208 -470 -617 -602 -309 -202 -260 -11 143 182 267 528 309 393 234 127 -1 154 66 -270 -260 -329 -296 79 -49 -229 -215 3 -252 -444 -480 -378 -541 -201 -65 -218 -20 -265 -258 -198 -225 138 374 176 126 443 240 86 -152 -572 -583 -506 -330 -53 -153 -222 25 -189 -132 -11 -64 -6 199 254 322 395 669 690 492 401 315 158 205 276 61 122 200 103 287 599 86 -47 -4 -304 -277 -131 -228 -161 -83 133 -51 181 121 149 205 128 -107 -353 -474 -463 -481 SQ 20211205T135344.5Z 8009.578988 84 1 31.69 2 79.85 135.12 94.56 123.34 0.00 1 0.00 1 0 15 3.254e-03 3.231e-03 4.167e-04 4.162e-04 2.565755e+03 2.329219e+01 1.780481e+02 -6.000000e+00 1.683808e+02 274.88 -2.00 20.00 -2.00 505.30 0.00e+00 1.053617e-03 1.108063e-05 5.774016e-05 -6.000000e+00 8.826697e-05 274.88 -2.00 20.00 -2.00 500.60 0.00e+00 5.012346e-01 7.999777e-03 2.412732e-02 -6.000000e+00 6.314357e-02 222.31 -2.00 3.57 -2.00 502.17 0.00e+00 5.443 0.003 489.00 513.00 1 4.8641e+00 6.1027e-04 8.0015e-03 -6.0000e+00 4.8197e-03 5.8436e-03 1.5884e-04 6.6932e-04 -6.0000e+00 1.2663e-03 6.7106e-03 1.0464e-03 3.5612e-05 3.1594e-05 -6.0000e+00 2.8613e-04 4.8614e-03 -6.6215e-05 12 1 1 2 1 1 99.92 22.20 1.03 0.00486 0.01212 44 15 1 4 0 700.380 26.11 19.98 22.20 6.24 20.5 1003.22 -738 -552 -392 -256 25 357 414 477 267 282 221 -62 -339 -368 -474 -403 -144 30 -120 112 218 200 241 256 255 324 487 35 -426 -357 -426 -365 244 185 100 355 370 52 71 44 -43 94 144 336 388 342 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2 -219 -388 -208 -210 -247 -50 208 27 156 227 264 182 199 -135 -437 -574 -536 -569 SQ 20211205T135808.6Z 8009.582044 87 1 28.44 2 79.30 135.98 93.93 124.05 0.00 1 0.00 1 0 15 3.360e-03 3.341e-03 5.600e-04 5.593e-04 2.442139e+03 3.114218e+01 1.698284e+02 -6.000000e+00 1.738998e+02 274.88 -2.00 20.00 -2.00 505.28 0.00e+00 1.005522e-03 1.485401e-05 5.435588e-05 -6.000000e+00 9.116039e-05 274.88 -2.00 20.00 -2.00 500.55 0.00e+00 4.624532e-01 1.076024e-02 2.288735e-02 -6.000000e+00 6.521323e-02 222.31 -2.00 3.57 -2.00 502.13 0.00e+00 5.185 0.003 489.00 513.00 1 5.3625e+00 8.2095e-04 7.6153e-03 -6.0000e+00 4.9777e-03 8.0593e-03 2.1436e-04 6.3640e-04 -6.0000e+00 1.3078e-03 4.2418e-03 1.1308e-03 4.7875e-05 2.9895e-05 -6.0000e+00 2.9551e-04 2.6381e-03 -5.2435e-05 12 1 1 2 1 1 99.37 22.20 1.02 0.00264 0.01048 22 8 1 4 0 1227.290 26.11 20.00 22.20 6.23 20.4 1002.60 -836 -643 -477 -163 9 432 423 408 201 173 178 -148 -274 -303 -511 -455 -153 76 -65 14 330 63 237 360 210 403 456 23 -294 -249 -412 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