File name: Pandora170s1_Downsview_20220116_L2Fit_fout2c1d20211219p1-8.txt File generation date: 20260323T102259.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v5d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20211219.txt Level 1 file used: Pandora170s1_Downsview_20220116_L1_smca1c1d20211219p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1142 305.2554 305.3965 305.5377 305.6788 305.8199 305.9610 306.1021 306.2432 306.3843 306.5253 306.6664 306.8074 306.9485 307.0895 307.2305 307.3715 307.5124 307.6534 307.7944 307.9353 308.0763 308.2172 308.3581 308.4990 308.6399 308.7808 308.9216 309.0625 309.2033 309.3442 309.4850 309.6258 309.7666 309.9074 310.0481 310.1889 310.3297 310.4704 310.6111 310.7518 310.8925 311.0332 311.1739 311.3146 311.4552 311.5959 311.7365 311.8772 312.0178 312.1584 312.2990 312.4395 312.5801 312.7207 312.8612 313.0017 313.1422 313.2828 313.4232 313.5637 313.7042 313.8447 313.9851 314.1256 314.2660 314.4064 314.5468 314.6872 314.8276 314.9679 315.1083 315.2486 315.3890 315.5293 315.6696 315.8099 315.9502 316.0905 316.2307 316.3710 316.5112 316.6515 316.7917 316.9319 317.0721 317.2123 317.3524 317.4926 317.6327 317.7729 317.9130 318.0531 318.1932 318.3333 318.4734 318.6134 318.7535 318.8935 319.0336 319.1736 319.3136 319.4536 319.5936 319.7335 319.8735 320.0134 320.1534 320.2933 320.4332 320.5731 320.7130 320.8529 320.9927 321.1326 321.2724 321.4123 321.5521 321.6919 321.8317 321.9715 322.1112 322.2510 322.3907 322.5305 322.6702 322.8099 322.9496 323.0893 323.2290 323.3687 323.5083 323.6479 323.7876 323.9272 324.0668 324.2064 324.3460 324.4856 324.6251 324.7647 324.9042 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220116T133655.8Z 8051.567313 295 1 50.04 2 83.45 127.36 101.32 323.15 0.00 1 0.00 1 0 33 1.112e+00 6.239e-02 2.224e-01 9.273e-03 1.081858e+00 6.184037e-03 1.185400e-02 -6.000000e+00 7.168046e-01 223.44 -2.00 3.57 -2.00 322.34 0.00e+00 4.738332e-03 2.718343e-03 4.131357e-03 -6.000000e+00 4.168921e-02 271.77 -2.00 20.00 -2.00 321.94 0.00e+00 7.967 0.010 302.00 328.00 3 -1.1724e-01 2.1238e-02 1.0131e-01 -6.0000e+00 1.8151e+00 2.0403e+00 2.6225e-02 7.3475e-02 -6.0000e+00 2.0261e+00 -2.5102e+00 2.0008e-02 3.1744e-02 -6.0000e+00 1.1666e+00 9.4444e-01 1.0702e-02 1.3341e-02 -6.0000e+00 4.9938e-01 6.4887e-05 -1.2383e-03 2.6436e-04 1.5890e-04 -6.0000e+00 3.4810e-02 -8.2127e-05 8.5114e-05 12 9 8 11 32 0 93.33 22.17 0.68 -0.00008 -0.00939 45 9 1 5 0 1111.720 26.11 20.02 22.17 -5.27 19.9 1004.07 900000 900000 900000 431 900000 900000 -961 900000 900000 -75972 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 110909 -3331 20971 127260 900000 -6230 607706 900000 900000 900000 179931 900000 900000 900000 900000 900000 900000 38743 141417 49844 900000 900000 900000 -44314 900000 900000 -16087 76370 353094 900000 900000 -15588 900000 76699 63327 900000 900000 104920 127377 148633 37741 -17109 900000 23586 34464 16630 199795 135886 900000 34546 -2569 37690 51022 110530 24816 583607 4022 65977 160703 246330 -4024 91967 4498 38144 46151 66123 24744 2628 -32722 49148 24750 12480 14271 11074 989 -17747 -14212 3219 -4751 5478 -16720 4190 18934 4425 -9137 3705 -2490 -1989 -2007 -10289 -315 -1585 -1925 -4426 -7729 -229 8512 7834 -1197 -2282 -1341 12695 3868 987 5906 3983 11890 -4203 -7161 3953 -2655 1917 2766 1556 412 4528 -631 -2126 -1560 -1686 -1210 -1087 900000 900000 900000 44 900000 900000 -64 900000 900000 -8634 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 3436 -270 1304 2847 900000 -444 5440 900000 900000 900000 2313 900000 900000 900000 900000 900000 900000 2174 3390 3111 900000 900000 900000 -6352 900000 900000 -1678 3483 3161 900000 900000 -2232 900000 5173 4907 900000 900000 4933 4421 3976 2940 -2452 900000 2942 4011 2276 5070 6809 900000 5456 -593 5903 6548 7263 3145 5225 561 5800 7000 5728 -1128 12052 1411 9194 10785 13309 7435 963 -16044 10735 6380 3528 4162 3784 441 -11178 -10163 2231 -3737 3818 -12953 2369 8706 2386 -5905 2243 -1716 -1521 -1779 -11386 -359 -1943 -2414 -5608 -9868 -274 9775 9484 -1617 -3065 -1696 13452 4312 1106 6209 4181 12079 -5629 -11547 6610 -5169 3862 5921 3587 1007 10940 -1599 -5428 -3836 -3885 -2568 -2173 SS 20220116T135827.2Z 8051.582259 301 1 49.72 2 80.44 131.43 103.46 327.37 0.00 1 0.00 1 0 17 7.271e-01 1.666e-02 2.124e-01 2.205e-03 8.531157e-01 1.232328e-03 9.986168e-03 -6.000000e+00 4.203598e-01 223.44 -2.00 3.57 -2.00 321.47 0.00e+00 6.818928e-03 5.972026e-04 4.590180e-03 -6.000000e+00 2.012524e-02 271.77 -2.00 20.00 -2.00 321.07 0.00e+00 5.746 0.004 302.00 328.00 3 9.4798e-02 4.0834e-03 7.3512e-02 -6.0000e+00 1.0379e+00 1.6398e-01 6.3768e-03 5.0240e-02 -6.0000e+00 1.1331e+00 -2.3670e-01 7.5192e-03 3.5462e-02 -6.0000e+00 6.7146e-01 9.5034e-02 3.5200e-03 1.6736e-02 -6.0000e+00 2.9107e-01 7.5762e-04 1.8841e-04 5.8960e-05 2.2703e-04 -6.0000e+00 2.0564e-02 6.5153e-04 -2.5973e-05 12 8 8 10 0 0 99.80 22.19 0.33 0.00065 0.00207 166 34 1 5 0 299.430 26.11 19.99 22.19 -4.01 19.9 1001.35 -213698 900000 900000 -336377 900000 900000 -313829 -216220 -142623 -325711 900000 37366 900000 900000 900000 19883 111956 900000 -6766 -21798 -55073 -132745 -106011 -7675 32456 -92856 -72869 68235 900000 209876 -19210 -1309 98773 828 37537 304716 34431 -28788 -9484 -3810 53668 33798 32203 -17510 14091 32649 -16446 1496 11029 23874 55880 -5590 26869 630 1166 19274 22749 3553 1818 3624 2631 -3886 22733 4440 1786 2777 4737 6636 10505 1692 -192 1636 1288 3510 -511 2120 -4909 84 3035 3567 -2458 737 -3477 -288 1580 2920 1512 585 -2208 2421 793 -1788 -2073 -2239 -2262 -2555 -764 1256 -50 -205 -2610 -1554 641 7 -2862 -1138 -3235 -599 383 28 652 249 -123 -774 -1444 -216 1062 1369 958 96 714 2339 1288 502 804 -905 1246 254 -588 496 -631 -172 -29 -3 -252 -56 781 203 -35 -248 -597 -701 -1052 900000 900000 -6261 900000 900000 -5068 -1571 -565 -7823 900000 80 900000 900000 900000 77 240 900000 -48 -189 -658 -3301 -2214 -70 216 -2084 -1376 342 900000 450 -368 -26 884 19 595 654 667 -1190 -397 -175 1628 1314 1334 -1162 728 1493 -1231 103 755 1624 3242 -627 2481 79 154 2246 2599 472 239 473 373 -666 3543 908 387 601 1045 1564 2725 532 -65 550 415 1024 -140 528 -1312 24 993 1378 -1155 376 -1968 -167 953 1824 987 387 -1466 1473 464 -1041 -1243 -1488 -1732 -2259 -757 1350 -56 -223 -2673 -1435 559 6 -2807 -1150 -3521 -691 487 40 984 389 -192 -1180 -2149 -318 1589 2125 1534 154 1100 3431 1858 711 1111 -1238 1716 387 -1008 922 -1257 -358 -62 -7 -597 -135 1887 492 -83 -562 -1290 -1462 SS 20220116T140709.9Z 8051.588309 306 1 1.27 2 79.28 133.12 104.25 329.12 0.00 1 0.00 1 0 25 6.428e-01 2.826e-02 3.879e-01 1.931e-02 7.870834e-01 1.082967e-02 9.569753e-03 -6.000000e+00 3.770576e-01 223.44 -2.00 3.57 -2.00 321.42 0.00e+00 8.904400e-03 4.880449e-03 7.048998e-04 -6.000000e+00 1.740483e-02 271.77 -2.00 20.00 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