File name: Pandora170s1_Downsview_20220124_L2Fit_fout2c1d20211219p1-8.txt File generation date: 20260323T102300.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v6d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20211219.txt Level 1 file used: Pandora170s1_Downsview_20220124_L1_smca1c1d20211219p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220124 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1142 305.2554 305.3965 305.5377 305.6788 305.8199 305.9610 306.1021 306.2432 306.3843 306.5253 306.6664 306.8074 306.9485 307.0895 307.2305 307.3715 307.5124 307.6534 307.7944 307.9353 308.0763 308.2172 308.3581 308.4990 308.6399 308.7808 308.9216 309.0625 309.2033 309.3442 309.4850 309.6258 309.7666 309.9074 310.0481 310.1889 310.3297 310.4704 310.6111 310.7518 310.8925 311.0332 311.1739 311.3146 311.4552 311.5959 311.7365 311.8772 312.0178 312.1584 312.2990 312.4395 312.5801 312.7207 312.8612 313.0017 313.1422 313.2828 313.4232 313.5637 313.7042 313.8447 313.9851 314.1256 314.2660 314.4064 314.5468 314.6872 314.8276 314.9679 315.1083 315.2486 315.3890 315.5293 315.6696 315.8099 315.9502 316.0905 316.2307 316.3710 316.5112 316.6515 316.7917 316.9319 317.0721 317.2123 317.3524 317.4926 317.6327 317.7729 317.9130 318.0531 318.1932 318.3333 318.4734 318.6134 318.7535 318.8935 319.0336 319.1736 319.3136 319.4536 319.5936 319.7335 319.8735 320.0134 320.1534 320.2933 320.4332 320.5731 320.7130 320.8529 320.9927 321.1326 321.2724 321.4123 321.5521 321.6919 321.8317 321.9715 322.1112 322.2510 322.3907 322.5305 322.6702 322.8099 322.9496 323.0893 323.2290 323.3687 323.5083 323.6479 323.7876 323.9272 324.0668 324.2064 324.3460 324.4856 324.6251 324.7647 324.9042 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220124T163732.6Z 8059.692738 448 1 49.36 2 64.02 166.20 96.10 266.03 0.00 1 0.00 1 0 17 1.584e-01 1.813e-02 1.954e-02 2.450e-03 3.518185e-01 1.229905e-03 4.253939e-03 -6.000000e+00 9.011811e-02 223.77 -2.00 3.57 -2.00 318.17 0.00e+00 1.815887e-03 2.228876e-04 1.125572e-04 -6.000000e+00 3.849991e-03 271.77 -2.00 20.00 -2.00 317.66 0.00e+00 2.269 0.000 302.00 328.00 3 4.2321e+00 3.2699e-03 2.8556e-02 -6.0000e+00 2.2271e-01 2.7768e-02 3.7079e-03 1.8123e-02 -6.0000e+00 2.4252e-01 1.5459e-02 2.5404e-03 9.1183e-03 -6.0000e+00 1.4394e-01 -1.8782e-02 1.3449e-03 3.1605e-03 -6.0000e+00 6.1618e-02 5.2824e-04 1.1869e-04 7.0829e-05 3.1785e-05 -6.0000e+00 4.3537e-03 -4.2065e-03 -6.0236e-05 12 9 9 12 32 32 99.66 22.54 1.00 -0.00421 -0.00331 20 4 1 5 0 2467.170 26.51 20.00 22.54 -0.25 29.10 20.4 984.34 5752 32835 51196 -47613 97332 30334 -38176 -2346 9670 -44229 88544 -2899 18001 40332 30461 11324 7930 15274 3436 5654 -5650 -13850 -9508 -1440 8183 -11610 -6903 4774 23326 24191 -2969 4811 15163 -1048 -739 13671 1717 -7590 -5020 -5641 3200 1969 3654 -8459 499 2509 -6587 -3612 -924 4405 94 -4674 5670 556 -675 4113 6144 -792 -1405 -719 16 -1696 3451 -79 -1880 -906 517 1066 4807 -1083 -1593 196 1779 2197 309 2047 -2472 -769 2224 2649 -3094 -2312 -3388 -1058 -362 2214 927 104 1475 878 1472 338 403 -328 -701 -2695 -605 1480 448 529 -2884 -563 875 -76 -2708 -1256 -983 -596 486 -477 894 379 -36 -622 -2131 568 1138 1403 377 -488 -606 1997 771 309 773 -548 2144 197 -1107 1205 -972 120 649 898 134 -617 476 -317 -462 -223 -583 -453 278 1338 1778 -3861 1874 1099 -2863 -142 573 -4468 2634 -223 1336 2873 2744 1338 1024 1950 512 857 -958 -2538 -1746 -261 1434 -2497 -1400 831 3346 3597 -623 1038 3217 -255 -171 2861 447 -2510 -1896 -2393 1345 868 1628 -4191 232 1148 -3225 -1720 -433 2052 48 -2656 3123 332 -416 2495 3697 -497 -875 -450 10 -1200 2516 -61 -1448 -657 361 757 3613 -924 -1430 176 1553 1833 244 1478 -1757 -547 1677 2199 -2909 -2302 -3534 -1130 -404 2530 1100 125 1738 997 1575 344 396 -332 -762 -3211 -766 1959 606 695 -3663 -668 1019 -93 -3532 -1673 -1351 -846 717 -740 1413 598 -56 -913 -3021 779 1585 2026 570 -758 -938 2991 1140 445 1078 -747 2847 275 -1647 1846 -1552 193 1067 1525 237 -1116 868 -585 -844 -398 -1016 -772 SS 20220124T171432.2Z 8059.718428 467 1 49.14 2 62.97 175.89 102.65 272.11 0.00 1 0.00 1 0 17 5.398e-02 1.257e-02 7.941e-03 1.671e-03 3.317816e-01 8.388413e-04 4.059341e-03 -6.000000e+00 3.070096e-02 223.77 -2.00 3.57 -2.00 317.81 0.00e+00 1.251602e-03 1.366956e-04 1.595915e-04 -6.000000e+00 1.311929e-03 271.77 -2.00 20.00 -2.00 317.29 0.00e+00 2.189 0.000 302.00 328.00 3 3.6760e+00 2.2128e-03 2.7300e-02 -6.0000e+00 7.5871e-02 6.3459e-03 2.4961e-03 1.7032e-02 -6.0000e+00 8.2638e-02 1.1441e-02 1.6223e-03 8.5820e-03 -6.0000e+00 4.9047e-02 -1.2717e-02 8.4485e-04 2.6768e-03 -6.0000e+00 2.0983e-02 1.0405e-03 -4.9244e-04 4.8240e-05 2.8630e-05 -6.0000e+00 1.4846e-03 -2.8491e-03 -2.0002e-04 12 9 8 11 32 0 99.73 22.53 0.46 -0.00285 -0.00655 33 7 1 5 0 1488.560 26.51 20.00 22.53 -0.70 27.30 20.5 984.83 378 14476 12919 2902 23711 2940 -25932 -7008 -312 -26072 19334 -4252 6393 14594 11535 2939 1385 6904 1394 4503 -3864 -7066 -5666 -2213 4343 -5359 -3127 987 9159 8674 -846 2904 7717 -3114 -3339 -5957 -2061 -5891 -2971 -3427 1299 1144 1562 -4963 776 1205 -3130 -2035 -907 2099 1219 -2567 4059 -162 -593 3046 3423 25 -574 -344 666 -581 5464 1561 -524 -999 -568 69 2918 21 -497 393 1602 1974 92 997 -2497 -1200 15 -1948 -2118 -909 -2861 -757 44 1090 346 766 -640 1736 1118 -395 122 -267 -347 -1567 949 1038 -160 201 -1877 -1182 589 279 -1887 -599 -2287 -520 515 46 841 331 113 -747 -973 64 602 995 683 -117 -161 435 965 507 752 -526 1700 498 -432 748 -798 -270 135 413 34 294 426 -182 -323 -231 -559 -666 26 927 845 193 1200 181 -2269 -581 -27 -2888 1432 -426 674 1668 1547 463 233 1164 257 838 -780 -1472 -1214 -488 951 -1308 -735 213 1790 1766 -204 743 2029 -890 -913 -1710 -638 -2186 -1247 -1600 620 565 786 -2640 397 615 -1638 -1050 -465 1087 675 -1546 2438 -104 -390 1991 2248 16 -380 -230 460 -432 4140 1255 -418 -760 -418 52 2316 18 -456 363 1447 1710 76 759 -1858 -893 12 -1720 -2023 -912 -3018 -818 50 1268 416 925 -771 1984 1217 -410 123 -274 -380 -1858 1188 1370 -216 263 -2362 -1410 692 341 -2449 -794 -3157 -733 754 70 1310 514 171 -1082 -1353 88 831 1422 1017 -178 -246 650 1410 723 1041 -712 2251 687 -631 1129 -1248 -426 217 686 59 516 756 -327 -574 -401 -951 -1113 SS 20220124T172711.2Z 8059.727213 476 1 49.62 2 62.87 179.25 104.88 274.22 0.00 1 0.00 1 0 17 5.767e-02 1.199e-02 7.551e-03 1.593e-03 3.352655e-01 8.000362e-04 4.065723e-03 -6.000000e+00 3.282913e-02 223.77 -2.00 3.57 -2.00 317.77 0.00e+00 1.118856e-03 1.293428e-04 1.631245e-04 -6.000000e+00 1.402243e-03 271.77 -2.00 20.00 -2.00 317.26 0.00e+00 2.181 0.000 302.00 328.00 3 3.6022e+00 2.1102e-03 2.7309e-02 -6.0000e+00 8.1133e-02 1.0792e-02 2.3801e-03 1.7116e-02 -6.0000e+00 8.8336e-02 1.2004e-02 1.5427e-03 8.6230e-03 -6.0000e+00 5.2427e-02 -1.2985e-02 8.0238e-04 2.7305e-03 -6.0000e+00 2.2452e-02 1.1183e-03 6.2686e-04 4.5927e-05 2.8598e-05 -6.0000e+00 1.5852e-03 -5.1623e-03 1.2710e-05 12 9 8 11 32 0 99.91 22.53 0.47 -0.00516 -0.00045 34 7 1 5 0 1459.080 26.51 20.00 22.53 -0.38 28.10 20.4 985.44 -571 14777 13569 -27629 28731 6686 -19539 -1263 -47 -24083 18317 -4949 6967 14780 12828 704 3304 7298 2687 2996 -3846 -6861 -4843 -2345 3999 -5131 -2832 376 8004 8848 -1596 1686 5851 -2672 -2908 3074 -3144 -6292 -2928 -3461 1445 -150 1492 -4272 453 518 -3546 -2161 -1235 1901 5992 -2453 3522 -283 -462 2351 3353 -180 -866 63 432 1531 2029 1018 -1202 -837 -681 -199 2351 -173 1291 706 1439 1802 -117 1008 -2500 -1135 25 144 -2076 -857 -3017 -831 -25 848 599 418 -598 1297 1155 -52 -112 -303 -226 -1330 257 1232 41 18 -1946 -1289 274 54 -1858 -714 -2198 -468 743 -75 704 399 -9 -443 -237 -23 -220 871 644 -274 -230 1418 758 542 1147 -353 1324 731 -424 669 -792 -247 168 335 -111 185 367 -45 -239 -350 -608 -649 -39 943 882 -2431 1390 397 -1612 -99 -4 -2631 1375 -500 733 1691 1706 114 549 1232 493 568 -780 -1435 -1036 -521 885 -1260 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