File name: Pandora170s1_Downsview_20220131_L2Fit_fout2c1d20211219p1-8.txt File generation date: 20260323T102356.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 170 Spectrometer number: 1 Processing software version used: BlickP v1.8.88 Instrument operation file used: Pandora170_OF_v6d20200302.txt Instrument calibration file used: Pandora170s1_CF_v1d20211219.txt Level 1 file used: Pandora170s1_Downsview_20220131_L1_smca1c1d20211219p1-8.txt.bz2 Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20220131 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 215 356 Nominal wavelengths inside fitting window [nm]: 305.1142 305.2554 305.3965 305.5377 305.6788 305.8199 305.9610 306.1021 306.2432 306.3843 306.5253 306.6664 306.8074 306.9485 307.0895 307.2305 307.3715 307.5124 307.6534 307.7944 307.9353 308.0763 308.2172 308.3581 308.4990 308.6399 308.7808 308.9216 309.0625 309.2033 309.3442 309.4850 309.6258 309.7666 309.9074 310.0481 310.1889 310.3297 310.4704 310.6111 310.7518 310.8925 311.0332 311.1739 311.3146 311.4552 311.5959 311.7365 311.8772 312.0178 312.1584 312.2990 312.4395 312.5801 312.7207 312.8612 313.0017 313.1422 313.2828 313.4232 313.5637 313.7042 313.8447 313.9851 314.1256 314.2660 314.4064 314.5468 314.6872 314.8276 314.9679 315.1083 315.2486 315.3890 315.5293 315.6696 315.8099 315.9502 316.0905 316.2307 316.3710 316.5112 316.6515 316.7917 316.9319 317.0721 317.2123 317.3524 317.4926 317.6327 317.7729 317.9130 318.0531 318.1932 318.3333 318.4734 318.6134 318.7535 318.8935 319.0336 319.1736 319.3136 319.4536 319.5936 319.7335 319.8735 320.0134 320.1534 320.2933 320.4332 320.5731 320.7130 320.8529 320.9927 321.1326 321.2724 321.4123 321.5521 321.6919 321.8317 321.9715 322.1112 322.2510 322.3907 322.5305 322.6702 322.8099 322.9496 323.0893 323.2290 323.3687 323.5083 323.6479 323.7876 323.9272 324.0668 324.2064 324.3460 324.4856 324.6251 324.7647 324.9042 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220131T174102.3Z 8066.736832 260 1 50.56 2 61.06 182.64 68.62 188.12 0.00 1 0.00 1 0 17 4.041e-02 1.131e-02 5.285e-03 1.523e-03 2.998844e-01 7.654718e-04 3.683213e-03 -6.000000e+00 2.301709e-02 224.05 -2.00 3.57 -2.00 317.35 0.00e+00 1.253039e-03 1.096175e-04 7.325561e-05 -6.000000e+00 9.823768e-04 271.77 -2.00 20.00 -2.00 316.83 0.00e+00 2.057 0.000 302.00 328.00 3 3.7020e+00 2.0045e-03 2.5281e-02 -6.0000e+00 5.6918e-02 2.1434e-02 2.2530e-03 1.5443e-02 -6.0000e+00 6.1973e-02 4.4157e-04 1.3948e-03 7.7181e-03 -6.0000e+00 3.6774e-02 -8.1276e-03 7.0571e-04 2.4624e-03 -6.0000e+00 1.5729e-02 1.2033e-03 2.8446e-04 4.3939e-05 2.6645e-05 -6.0000e+00 1.1112e-03 -2.6779e-03 -6.5023e-05 12 9 8 11 32 0 99.78 22.55 0.42 -0.00268 -0.00054 36 7 1 5 0 1404.360 26.51 20.00 22.55 6.86 33.30 21.2 1001.88 2777 4836 12181 -21575 14710 986 -15263 -2983 -784 -18840 8818 -2655 -253 10861 6627 2067 4193 5053 1600 2641 -2601 -6462 -2735 -1133 3645 -4783 -1337 -824 6415 6542 902 3117 4905 -2652 -4266 2768 -3950 -3933 -1960 -3011 1048 297 1490 -3689 440 508 -2923 -1908 -1576 2400 1348 -735 3013 -105 -429 3000 3165 654 -1015 468 307 -136 3207 1284 -1261 -1609 -525 -334 2682 -106 -130 860 1339 1558 101 600 -2713 -1207 50 298 -2201 -673 -2568 -1011 -59 400 581 563 -441 1091 1347 -571 -269 -163 -304 -998 200 1359 -343 177 -1295 -962 89 -63 -1678 -665 -1928 -390 835 119 947 649 260 -423 -1046 40 -565 286 383 -96 -213 1197 653 634 1144 -473 820 714 -30 773 -441 -175 306 384 99 -446 466 -192 -343 -118 -503 -687 261 478 1127 -2503 1128 86 -1671 -327 -92 -2652 971 -350 -37 1679 1200 420 873 1092 370 625 -647 -1664 -707 -305 984 -1416 -377 -219 1556 1630 255 937 1544 -878 -1366 857 -1432 -1645 -927 -1582 563 166 839 -2167 251 290 -1691 -1085 -893 1357 811 -473 1967 -72 -302 2098 2225 463 -720 332 227 -107 2612 1089 -1061 -1286 -404 -261 2213 -96 -123 819 1252 1402 87 476 -2095 -928 41 265 -2144 -686 -2742 -1110 -67 473 705 689 -537 1268 1482 -602 -273 -168 -333 -1180 251 1781 -459 230 -1614 -1143 105 -77 -2172 -881 -2648 -547 1210 180 1455 991 385 -601 -1428 54 -771 403 561 -144 -319 1756 943 890 1557 -630 1074 967 -43 1140 -671 -268 479 620 166 -762 802 -334 -592 -200 -834 -1119 SS 20220131T174611.2Z 8066.740407 263 1 10.36 2 61.11 184.05 68.75 189.34 0.00 1 0.00 1 0 17 3.716e-02 1.244e-02 1.263e-02 3.823e-03 3.015654e-01 1.923170e-03 3.657397e-03 -6.000000e+00 2.120336e-02 224.05 -2.00 3.57 -2.00 317.21 0.00e+00 1.133170e-03 2.673195e-04 7.505200e-05 -6.000000e+00 9.036881e-04 271.77 -2.00 20.00 -2.00 316.69 0.00e+00 2.061 0.000 302.00 328.00 3 3.7429e+00 5.0256e-03 2.5294e-02 -6.0000e+00 5.2436e-02 3.1807e-02 5.6450e-03 1.5420e-02 -6.0000e+00 5.7056e-02 4.3876e-04 3.4668e-03 7.6971e-03 -6.0000e+00 3.3856e-02 -1.0213e-02 1.7441e-03 2.5309e-03 -6.0000e+00 1.4505e-02 1.1436e-03 2.1223e-03 1.1009e-04 2.6477e-05 -6.0000e+00 1.0211e-03 -6.4573e-03 2.6635e-04 12 9 9 12 33 33 95.09 22.55 0.45 -0.00646 0.00949 4 5 1 5 0 2035.490 26.51 20.00 22.55 6.97 34.60 21.2 1001.83 -4393 5628 12949 -547 9700 -525 -22978 -3775 2551 -15627 9031 -3110 -266 9131 7114 3398 819 5668 1335 2234 -4038 -6432 -4915 -194 4902 -3144 -2385 552 5799 8123 1489 1855 1655 -3170 -676 2870 -5318 -5451 -2426 355 709 533 591 -3356 522 1350 -2911 -1270 -1323 1082 1010 -1900 4148 -557 396 3035 458 -990 -3 -704 770 -606 3926 1277 -728 72 -980 -223 2752 -378 -215 1270 1834 1658 391 32 -2915 -1784 459 -1909 -1959 -1399 -2500 -879 -472 1284 396 823 1884 1452 834 -490 -109 -327 -167 -1187 523 1226 271 -269 -2219 -1372 -316 384 -1926 -592 -2357 -91 618 208 595 307 299 -435 -689 -351 -113 1527 361 -174 -353 582 599 671 1250 -688 474 694 -315 1799 -464 -802 457 971 -11 -744 686 -51 -362 -332 -631 -547 -463 582 1257 -56 823 -49 -2838 -440 305 -2259 1050 -434 -41 1506 1348 717 185 1279 324 556 -1066 -1734 -1354 -54 1373 -961 -711 153 1485 2093 437 588 558 -1100 -220 926 -2022 -2384 -1187 187 393 305 344 -2018 307 786 -1729 -738 -768 634 624 -1258 2746 -393 283 2165 334 -724 -2 -512 576 -486 3227 1097 -618 58 -768 -177 2300 -347 -205 1218 1727 1508 338 26 -2289 -1398 379 -1741 -1920 -1441 -2682 -967 -541 1513 482 1007 2264 1688 924 -518 -111 -340 -183 -1406 654 1607 360 -350 -2780 -1635 -373 470 -2491 -782 -3233 -127 892 312 911 466 441 -615 -936 -469 -154 2127 526 -259 -527 852 860 937 1693 -915 620 936 -447 2622 -701 -1229 709 1550 -18 -1261 1168 -88 -620 -557 -1036 -883 SS 20220131T175001.9Z 8066.743077 266 1 2.95 2 61.17 185.09 68.85 190.25 0.00 1 0.00 1 0 17 2.127e-02 9.058e-03 9.281e-03 3.231e-03 3.022543e-01 1.628083e-03 3.705977e-03 -6.000000e+00 1.210848e-02 224.05 -2.00 3.57 -2.00 317.01 0.00e+00 8.977998e-04 2.131337e-04 7.014516e-05 -6.000000e+00 5.168837e-04 271.77 -2.00 20.00 -2.00 316.50 0.00e+00 2.064 0.000 302.00 328.00 3 2.2293e+00 4.2390e-03 2.5370e-02 -6.0000e+00 2.9942e-02 1.6431e-02 4.7540e-03 1.5471e-02 -6.0000e+00 3.2606e-02 -1.0513e-02 2.8683e-03 7.7224e-03 -6.0000e+00 1.9348e-02 -2.4364e-03 1.4222e-03 2.3346e-03 -6.0000e+00 8.2723e-03 5.2336e-03 -2.5655e-04 9.2711e-05 2.6336e-05 -6.0000e+00 5.8486e-04 -1.7774e-03 -1.4502e-04 12 9 1 12 1 1 80.38 22.55 0.29 -0.00178 -0.00371 5 22 1 5 0 460.070 26.51 20.01 22.55 7.07 34.60 21.2 1002.00 5560 4598 2006 -8840 -3260 -4873 -8816 -4372 803 -10309 3341 -3499 -4233 803 1895 954 -405 899 593 3934 -1414 2023 745 1181 1620 64 -718 -1677 1289 114 1832 1336 3010 -3955 -4442 -1964 -3665 -1987 -460 -371 -914 925 -396 -1769 694 391 232 -148 -366 -206 1615 441 1620 223 839 2015 1267 213 -304 -1 -14 260 2889 2205 -607 -784 -1006 -1193 1470 122 834 806 1242 1046 344 -286 -2308 -960 -593 -1068 -1960 -1757 -2658 -1430 -809 261 306 869 845 842 1037 -531 -498 -96 -76 -282 1380 630 -324 32 -720 -1294 280 -165 -1186 -358 -1652 -561 498 -6 604 185 254 -195 -478 -383 232 709 465 -167 21 786 422 412 619 -632 942 1135 216 618 -277 -425 69 68 140 -296 1007 173 -266 -583 -399 -1064 626 557 248 -1113 -360 -547 -1112 -592 113 -1628 471 -561 -777 161 422 229 -102 234 160 1066 -402 560 216 358 510 21 -230 -516 376 34 585 461 1084 -1484 -1604 -711 -1476 -901 -234 -206 -534 549 -241 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