File name: Pandora243s1_Downsview_20230603_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T222736.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v1d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230603_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230603 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230603T112105.0Z 8554.472974 243 1 31.55 2 73.90 74.30 114.84 259.74 0.00 1 0.00 1 0 17 2.503e-01 1.621e-02 2.275e-01 1.249e-02 5.250264e-01 6.483077e-03 6.027466e-03 -6.000000e+00 1.436019e-01 232.11 -2.00 3.57 -2.00 320.50 0.00e+00 -2.274125e-03 2.355629e-03 1.164827e-03 -6.000000e+00 6.270212e-03 282.80 -2.00 20.00 -2.00 319.84 0.00e+00 3.544 0.001 302.00 328.00 3 5.8046e+00 1.9838e-02 4.5448e-02 -6.0000e+00 3.6060e-01 1.4405e-01 2.4450e-02 2.9937e-02 -6.0000e+00 3.9092e-01 -2.1708e-01 2.0668e-02 1.3971e-02 -6.0000e+00 2.3200e-01 8.9543e-02 1.0390e-02 4.4587e-03 -6.0000e+00 9.7518e-02 2.6645e-05 9.3276e-05 3.5960e-04 4.5044e-05 -6.0000e+00 6.6556e-03 -1.8559e-03 0.0000e+00 12 8 8 10 0 0 98.01 29.41 1.34 -0.00186 -0.00116 10 10 1 5 0 3154.400 37.50 20.00 29.41 30.04 3.6 990.75 -59142 -91434 -50436 21023 -79576 -76965 165011 -84605 3202 -40111 -54970 -61301 -55534 10878 42723 -26039 16532 -34722 24640 1193 -24020 -5691 20126 -732 28085 1796 -25210 -24238 -7215 -33795 10996 -18835 3150 6503 -20730 -7496 -2516 17730 -2930 -13932 15914 -2702 3174 15106 -5566 10773 9797 3906 2961 -3190 -12502 5499 -3062 3928 7895 1986 8462 7161 3389 2717 4949 8939 9268 2596 4769 4607 5767 850 4051 -4015 2871 -1064 202 1765 217 -6819 -6331 -5745 3646 -3860 3080 -65 -5940 -1176 -1556 400 -46 -533 1686 3256 77 -1465 85 79 304 -3740 394 -517 151 -763 -1430 -477 1488 -2406 -137 -3285 1105 1394 -401 67 542 -326 -557 158 -508 199 986 -1722 52 2687 1326 -112 -1447 1362 -86 -81 1440 -118 866 -19 533 179 -20 -384 84 787 4 258 333 -716 -388 -427 -864 -1179 -2735 -1006 256 -1763 -1705 2011 -2624 46 -933 -1522 -2037 -2092 253 852 -1154 513 -1923 792 50 -1304 -258 758 -37 1266 109 -1966 -1742 -422 -2759 657 -1721 257 515 -2021 -658 -239 1663 -414 -2563 2366 -507 576 2430 -1099 1811 1659 709 556 -676 -3214 1293 -847 1086 2193 608 2475 2085 991 791 1471 2810 3241 1053 1889 1729 2094 335 1733 -2128 1536 -608 111 899 102 -3074 -2662 -2436 1582 -2107 1798 -44 -4559 -910 -1299 348 -42 -500 1530 2762 62 -1119 61 58 252 -3673 423 -630 193 -957 -1672 -500 1440 -2530 -152 -3959 1344 1798 -572 104 912 -570 -954 255 -768 287 1432 -2703 85 4476 2219 -184 -2337 2049 -125 -113 1914 -167 1353 -33 990 350 -40 -750 176 1701 8 582 743 -1547 -790 -910 -1809 SS 20230603T112742.5Z 8554.477575 247 1 30.43 2 72.74 75.35 115.97 260.74 0.00 1 0.00 1 0 25 1.338e-01 8.880e-03 1.400e-01 7.067e-03 4.901470e-01 3.703703e-03 5.727510e-03 -6.000000e+00 7.740983e-02 232.11 -2.00 3.57 -2.00 320.27 0.00e+00 1.323999e-03 1.269362e-03 3.284624e-04 -6.000000e+00 3.423505e-03 282.80 -2.00 20.00 -2.00 319.58 0.00e+00 3.321 0.001 302.00 328.00 3 5.3563e+00 1.1156e-02 4.2218e-02 -6.0000e+00 1.9460e-01 3.5291e-02 1.3595e-02 2.6807e-02 -6.0000e+00 2.1117e-01 -7.7914e-02 1.1637e-02 1.3078e-02 -6.0000e+00 1.2456e-01 2.7187e-02 5.9162e-03 4.0457e-03 -6.0000e+00 5.2132e-02 5.4119e-05 -2.1715e-04 2.0560e-04 4.2572e-05 -6.0000e+00 3.6101e-03 -9.8946e-04 0.0000e+00 11 8 0 10 0 0 98.70 29.41 1.88 -0.00099 -0.00262 15 15 1 5 0 2028.590 37.50 20.00 29.41 30.32 3.6 992.45 -66293 -8675 -47193 -72503 900000 -54185 -4990 900000 -30880 -15064 10152 -40853 -20499 5076 -24699 -7096 -6210 -18448 5603 -18746 10883 25674 17498 -14981 -5253 1126 -2412 39802 -1496 -7587 -5591 -14627 -2667 -5623 -14727 -9711 -13803 -1884 -1066 2730 -1171 -2191 5420 -8724 6227 1382 1030 -3677 4635 4498 7455 9224 4153 1958 3100 -166 -289 -662 -2031 -487 -334 114 2206 4655 909 -1429 2616 -1493 -756 1258 514 176 2684 -635 962 987 -1401 -2239 -216 -2681 -1006 -1836 -860 -1732 -1056 -342 1891 -258 1536 115 1210 233 -507 13 -622 542 176 764 -519 606 -1791 -523 -716 -822 -511 -970 -693 -482 -506 -60 581 111 488 970 -236 -179 813 -1134 157 -622 -456 -86 441 775 540 -141 563 1042 1184 464 -387 -90 -48 510 338 142 -114 -514 -155 65 -349 -496 165 -1204 -98 -798 -1453 900000 -848 -53 900000 -542 -259 140 -1070 -537 126 -987 -269 -252 -915 232 -1033 450 920 723 -929 -315 66 -145 1481 -82 -481 -401 -1310 -237 -519 -1400 -903 -1522 -222 -152 436 -212 -423 1004 -1881 1167 275 206 -783 929 958 1700 2262 1156 596 972 -56 -99 -224 -679 -160 -115 43 917 2049 414 -630 1080 -659 -371 692 308 109 1585 -366 496 456 -621 -1012 -107 -1592 -672 -1384 -688 -1475 -873 -299 1695 -241 1541 111 1070 193 -402 11 -564 553 186 904 -657 738 -2073 -595 -770 -925 -565 -1131 -849 -626 -711 -92 956 188 804 1500 -345 -250 1143 -1711 249 -1041 -757 -138 683 1147 765 -193 737 1418 1786 774 -699 -168 -94 1043 679 300 -246 -1133 -340 136 -760 -1031 334 SS 20230603T113306.0Z 8554.481320 250 1 29.84 2 71.80 76.21 116.90 261.56 0.00 1 0.00 1 0 25 1.239e-01 7.048e-03 9.239e-02 4.484e-03 4.698931e-01 2.322384e-03 5.509144e-03 -6.000000e+00 7.107443e-02 232.11 -2.00 3.57 -2.00 319.92 0.00e+00 1.333167e-03 7.180498e-04 2.995870e-04 -6.000000e+00 3.103342e-03 282.80 -2.00 20.00 -2.00 319.24 0.00e+00 3.159 0.001 302.00 328.00 3 4.9330e+00 6.7717e-03 4.0206e-02 -6.0000e+00 1.7848e-01 1.7116e-02 8.1281e-03 2.5438e-02 -6.0000e+00 1.9348e-01 -4.0795e-02 6.8101e-03 1.2616e-02 -6.0000e+00 1.1483e-01 8.0203e-03 3.5165e-03 3.8482e-03 -6.0000e+00 4.8267e-02 9.8430e-05 -3.0477e-04 1.2822e-04 4.0727e-05 -6.0000e+00 3.2941e-03 -2.0046e-03 0.0000e+00 11 8 0 10 0 0 83.60 29.41 1.11 -0.00200 -0.00429 19 19 1 5 0 1570.120 37.50 20.00 29.41 30.46 3.6 993.52 -34796 -24757 32819 8689 7969 -72406 -63473 30327 8557 -39601 -56226 -19131 -16475 -30615 -818 9079 -2690 9721 4487 21174 6695 -3993 5136 -5963 -2130 -4064 967 -5124 -8602 -3029 -10920 637 4783 -6479 3232 -5040 -1357 -1530 -10 594 -1290 3753 -1734 3905 270 -195 177 -1482 -4492 2603 1773 409 2030 -453 1494 380 765 -2170 1422 -131 187 222 1775 3732 644 8 77 106 -230 2355 486 -155 755 527 -149 -672 -1194 -1096 88 -770 -1833 -357 -1151 -1318 -1233 -736 560 1458 822 1593 884 -828 288 -42 -272 -14 -78 443 565 -546 -1674 -749 -1042 -724 -82 -459 -1028 -763 -141 567 65 426 291 180 302 469 323 102 -218 -684 677 -594 -22 670 97 400 136 583 771 390 166 77 -66 -136 -132 -208 -48 77 258 -44 -369 -289 -165 -553 -394 330 103 87 -1805 -1610 345 135 -1056 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