File name: Pandora243s1_Downsview_20230610_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T222730.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v1d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230610_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230610T105640.6Z 8561.456026 212 1 29.64 2 77.84 69.68 54.32 174.96 0.00 1 0.00 1 0 17 4.264e-01 1.243e-02 2.037e-01 5.794e-03 6.780464e-01 3.073926e-03 7.758608e-03 -6.000000e+00 2.448408e-01 232.56 -2.00 3.57 -2.00 321.18 0.00e+00 3.123834e-03 1.444292e-03 2.433352e-03 -6.000000e+00 1.070916e-02 283.53 -2.00 20.00 -2.00 320.59 0.00e+00 4.606 0.002 302.00 328.00 3 3.7122e+00 1.0331e-02 5.9204e-02 -6.0000e+00 6.1537e-01 1.9799e-01 1.3853e-02 3.9036e-02 -6.0000e+00 6.6693e-01 -3.1934e-01 1.3297e-02 2.0480e-02 -6.0000e+00 3.9581e-01 1.2826e-01 6.3570e-03 6.3690e-03 -6.0000e+00 1.6622e-01 6.7628e-05 -2.2270e-04 1.5814e-04 8.6955e-05 -6.0000e+00 1.1339e-02 2.2563e-03 0.0000e+00 12 8 8 10 0 0 99.72 28.27 1.05 0.00226 0.00058 25 25 1 5 0 1185.370 36.75 20.00 28.27 22.29 3.8 936.66 -144985 -144835 -89047 -123351 -144607 -129959 -59611 -175109 100865 7526 -168254 -168900 -69210 -92385 -61926 -56274 -78036 -29949 -37217 -10012 -35596 -7366 4652 -26850 -24642 1857 -34270 -14616 -63415 30931 -31316 -8240 5969 4550 41159 1455 -23832 -2188 21819 1157 9689 4674 8003 8608 -1295 11534 2623 5465 6397 11819 8654 4236 9788 3170 6972 8561 3726 3936 8187 5461 965 670 6325 5051 7664 3076 2579 2667 2235 4138 2773 2744 3120 967 -4152 -4550 -1600 -3245 321 -1903 605 623 -1453 -2351 -2103 1320 329 -769 -1980 1138 -1142 302 398 -268 -158 -1225 -877 -133 -438 -1498 -1191 322 -2409 72 -1456 -806 -1442 -372 -620 445 213 354 115 89 561 -157 549 -434 258 294 -93 312 752 774 908 783 974 358 673 524 197 49 357 -403 -157 -305 116 124 -264 236 -72 -675 -495 -1936 -2158 -778 -1394 -1857 -1469 -367 -3868 570 43 -4235 -5119 -995 -2136 -1435 -1431 -2734 -711 -1009 -215 -986 -154 92 -789 -752 45 -1181 -396 -2831 612 -1398 -345 246 193 1140 62 -1481 -132 1270 97 816 438 755 817 -138 1101 280 590 719 1369 1164 661 1576 589 1308 1640 762 787 1517 1034 202 157 1605 1441 2170 883 746 811 774 1613 1185 1200 1317 388 -1579 -1563 -511 -1104 122 -882 318 371 -954 -1500 -1436 925 243 -586 -1510 878 -837 205 264 -190 -128 -1060 -877 -151 -529 -1785 -1308 311 -2230 67 -1495 -864 -1650 -454 -839 670 325 562 181 135 871 -238 843 -710 408 478 -148 476 1206 1192 1343 1117 1352 535 1046 916 378 99 761 -922 -354 -719 277 301 -637 538 -168 -1486 -1062 SS 20230610T110151.1Z 8561.459619 215 1 30.00 2 76.96 70.50 54.23 176.49 0.00 1 0.00 1 0 17 3.920e-01 9.674e-03 1.336e-01 4.253e-03 6.522499e-01 2.245797e-03 7.474203e-03 -6.000000e+00 2.251599e-01 232.56 -2.00 3.57 -2.00 320.91 0.00e+00 2.349615e-03 9.806440e-04 1.573244e-03 -6.000000e+00 9.847420e-03 283.53 -2.00 20.00 -2.00 320.30 0.00e+00 4.317 0.001 302.00 328.00 3 3.5974e+00 7.3430e-03 5.5723e-02 -6.0000e+00 5.6590e-01 1.3691e-01 9.5813e-03 3.6332e-02 -6.0000e+00 6.1328e-01 -2.0359e-01 9.1261e-03 1.8629e-02 -6.0000e+00 3.6397e-01 7.5333e-02 4.4433e-03 5.7541e-03 -6.0000e+00 1.5288e-01 1.0146e-04 -5.0308e-04 1.1580e-04 7.5606e-05 -6.0000e+00 1.0424e-02 9.3137e-04 0.0000e+00 12 8 8 10 0 0 82.75 28.27 0.77 0.00093 -0.00285 30 30 1 5 0 999.980 36.50 20.00 28.27 22.53 3.8 938.79 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127 597 1188 751 1327 679 530 -56 843 -223 599 261 409 98 783 1187 1438 1606 482 1487 942 503 1450 -58 154 373 422 -251 -484 -549 -921 -90 -1100 -566 -1161 -1356 -1074 125 -306 142 164 429 1022 848 449 -515 -1078 -828 -403 102 -266 -372 -1214 -287 -1016 -1221 -359 -799 -807 -1340 -454 -300 -291 446 -17 172 144 -218 253 394 84 793 285 1156 300 1067 1077 1033 58 -217 -530 1757 269 635 318 1 -239 -205 -43 216 176 -147 -197 -1294 -1163 102 SS 20230610T111209.3Z 8561.466774 218 1 29.77 2 75.20 72.14 54.12 179.55 0.00 1 0.00 1 0 25 2.198e-01 5.931e-03 7.200e-02 2.447e-03 5.926888e-01 1.270799e-03 6.797066e-03 -6.000000e+00 1.262271e-01 232.56 -2.00 3.57 -2.00 320.34 0.00e+00 1.482684e-03 4.659613e-04 3.511889e-04 -6.000000e+00 5.520932e-03 283.53 -2.00 20.00 -2.00 319.68 0.00e+00 3.836 0.001 302.00 328.00 3 3.2768e+00 3.8600e-03 4.9631e-02 -6.0000e+00 3.1725e-01 3.8190e-02 4.8488e-03 3.2183e-02 -6.0000e+00 3.4383e-01 -6.7920e-02 4.4650e-03 1.6029e-02 -6.0000e+00 2.0406e-01 1.8812e-02 2.2507e-03 5.0299e-03 -6.0000e+00 8.5701e-02 2.3637e-04 -2.7149e-04 6.6420e-05 4.9373e-05 -6.0000e+00 5.8450e-03 1.8305e-03 0.0000e+00 10 0 0 10 0 0 99.23 28.27 0.85 0.00183 -0.00021 62 62 1 5 0 480.030 36.75 20.00 28.27 23.23 3.7 943.43 -77676 -85300 -55003 -88961 -89893 -45718 -89776 -36595 -83131 -50292 -30347 -48899 -51234 -37314 -13473 -31532 -24649 -23613 -27088 -10885 -6601 -1345 -9096 -13591 -19497 -10487 3454 -10350 -6216 -24047 -6608 -7923 -2008 -4705 -8376 -6455 -2844 362 -1335 -1924 608 3303 686 -182 2279 387 1957 -733 -2718 1949 2784 2996 2558 2784 2900 1825 1517 -795 -253 844 1467 2073 2503 2312 2759 462 26 -187 323 553 1118 352 767 595 -1017 -1335 -776 -1586 -1479 -1399 -359 -910 -1794 -1145 -1015 -632 228 508 342 1162 636 520 -531 -491 -180 -79 368 283 -37 -37 -538 -867 -892 -1069 -237 -247 -422 -518 111 445 -3 553 201 260 -54 74 269 -214 -210 -14 -106 -93 -40 341 34 438 646 383 289 299 338 -79 -80 21 -221 69 154 -92 53 -19 -277 -299 -132 -708 -1038 -512 -1083 -1030 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