File name: Pandora243s1_Downsview_20230622_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T224252.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v1d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230622_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230622 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230622T101950.3Z 8573.430443 84 1 30.12 2 84.05 63.00 113.39 24.19 0.00 1 0.00 1 0 25 6.767e-01 7.549e-02 5.835e-01 7.724e-02 9.769065e-01 4.606736e-02 1.120792e-02 -6.000000e+00 4.075053e-01 232.92 -2.00 3.57 -2.00 321.90 0.00e+00 -1.165603e-02 1.902257e-02 1.252643e-02 -6.000000e+00 2.042447e-02 284.69 -2.00 20.00 -2.00 321.31 0.00e+00 8.590 0.012 302.00 328.00 3 2.2673e+00 1.5738e-01 1.3114e-01 -6.0000e+00 1.0252e+00 1.9125e+00 1.8747e-01 1.2843e-01 -6.0000e+00 1.1147e+00 -1.7899e+00 1.1518e-01 3.3149e-02 -6.0000e+00 6.5635e-01 5.9739e-01 6.1115e-02 1.9307e-02 -6.0000e+00 2.7613e-01 3.2576e-06 -6.5925e-04 2.0316e-03 1.1399e-04 -6.0000e+00 1.9563e-02 -2.5242e-03 0.0000e+00 12 9 8 11 4 0 -39.40 22.56 3.92 -0.00252 -0.00748 9 9 1 5 0 3346.510 30.50 20.22 22.56 25.75 3.7 960.51 900000 -47822 191366 -84780 154080 900000 900000 58654 -81539 900000 -31619 900000 -83069 -80462 156982 -6239 126440 900000 235185 900000 900000 900000 -71322 900000 58426 6042 900000 211963 900000 900000 -51677 900000 38929 13508 -15889 91369 -119259 900000 10999 32446 116192 12766 -6743 37475 59795 26934 -56083 114306 49195 92595 -15485 43350 -31900 101931 147024 99145 89609 900000 -3846 167276 900000 243990 130964 52805 1562 225947 38103 -5591 23110 46871 -1134 35139 -9197 -26 838 -5472 -39490 -19666 -3977 3046 49523 9216 13449 -10731 2459 28221 30760 3051 -14009 6552 19676 -12792 9403 -2913 -3612 12975 -6634 -4257 -2034 5349 -10090 -14350 4756 -18609 -1844 4821 -9614 1757 -2243 -187 158 1306 6218 2258 -5528 5133 7811 -190 4075 1453 -1886 183 -5567 -116 11822 5937 -5484 1879 -1627 8764 -3572 1199 -2434 -1129 -1887 1935 -1163 -536 2316 168 -3747 2489 1234 900000 -3590 14365 -6894 11566 900000 900000 4403 -6631 900000 -2373 900000 -8834 -9563 11784 -468 9491 900000 17654 900000 900000 900000 -9247 900000 4386 454 900000 15911 900000 900000 -5642 900000 2922 1014 -1301 6859 -29298 900000 1051 2878 8722 1481 -920 3069 4488 2206 -10333 8580 3693 6951 -2430 4141 -6966 7651 11036 7442 6726 900000 -630 12556 900000 18315 9831 6126 309 16960 5200 -1259 4416 7996 -333 7194 -2761 -6 177 -1083 -10510 -4563 -923 869 10409 3321 5048 -4906 1144 10592 11545 1511 -7992 2853 6942 -5953 3529 -1356 -1979 7110 -5179 -3738 -1878 4497 -9089 -11849 2928 -14667 -1315 3366 -8227 1464 -2205 -209 200 1765 8168 3034 -7718 6280 9498 -262 5659 2095 -2690 241 -7439 -143 12423 6417 -6545 2285 -2418 13617 -7052 2456 -5554 -2746 -4986 5143 -3231 -1493 6156 428 -9114 5249 2547 SS 20230622T103020.5Z 8573.437737 87 1 29.56 2 82.35 64.72 112.63 26.64 0.00 1 0.00 1 0 17 4.856e-01 2.223e-02 4.029e-01 1.444e-02 9.025801e-01 8.038639e-03 1.038230e-02 -6.000000e+00 2.794493e-01 232.92 -2.00 3.57 -2.00 322.07 0.00e+00 8.244164e-03 4.685887e-03 3.771762e-03 -6.000000e+00 1.226040e-02 284.69 -2.00 20.00 -2.00 321.59 0.00e+00 6.978 0.006 302.00 328.00 3 2.2527e+00 3.1764e-02 8.5867e-02 -6.0000e+00 7.0271e-01 1.0418e+00 4.1978e-02 5.1484e-02 -6.0000e+00 7.6102e-01 -1.2606e+00 3.6331e-02 2.7073e-02 -6.0000e+00 4.5183e-01 4.8030e-01 1.6883e-02 1.0392e-02 -6.0000e+00 1.8996e-01 2.1478e-05 -1.0750e-03 3.7243e-04 1.8943e-04 -6.0000e+00 1.2913e-02 -3.0371e-03 0.0000e+00 12 9 8 11 4 0 -324.02 22.53 1.85 -0.00304 -0.01112 24 24 1 5 0 1231.330 30.50 19.69 22.53 26.15 3.6 962.70 -86758 -108117 -18530 -167935 -134653 -183424 44109 47340 -111350 -2338 -165167 -61438 -71823 -90871 22173 10449 19347 -21933 174773 -16125 -16628 -61194 111977 -46419 36120 -38511 6880 -6067 -5067 211767 -22492 -12268 -30622 -43179 75108 65285 -16028 125968 36906 14961 57590 26295 63921 59717 6158 26612 -4243 19123 37081 35911 49934 40634 39310 22488 46129 22257 20715 32137 18890 6496 13131 18094 9405 16194 16503 15922 20542 15848 20827 8709 15827 18278 9259 11664 6172 -14122 -7969 705 10958 -1522 -1523 -1224 5915 -2973 4380 1503 736 -1068 2960 -4455 -6957 985 -7041 -3460 -3450 -2141 -4786 -118 -1034 -1378 -2611 -763 -2864 -986 -4149 -3414 -900 -2731 -2125 -619 412 400 -107 -597 1376 -583 -2158 -1401 321 2629 2247 2124 1247 -63 2605 655 -1235 2475 1559 1038 798 861 305 -394 154 -461 369 -739 -210 -112 588 -1204 -1084 -1666 -2768 -261 -6663 -3275 -6809 621 667 -2138 -33 -5497 -865 -1471 -2908 312 174 322 -590 2461 -413 -404 -2193 1577 -1485 509 -1134 123 -116 -97 2982 -749 -440 -1489 -2377 1154 1086 -657 1774 1351 779 2108 1370 2340 2270 399 1424 -317 1185 2036 2174 2953 2918 3099 2248 3767 2350 2217 2941 1862 704 1387 2038 1337 2440 2579 2466 3095 2655 3754 2023 3677 4195 2216 2480 1225 -3062 -1571 137 2283 -437 -517 -476 2332 -1352 1967 732 375 -562 1475 -2271 -3379 420 -3252 -1681 -1968 -1438 -3908 -107 -1027 -1357 -2404 -609 -2113 -725 -3383 -2908 -797 -2695 -2361 -785 586 611 -167 -918 1993 -841 -3245 -2205 525 4282 3547 3176 1810 -90 3488 868 -1639 3450 2574 1812 1561 1825 695 -972 408 -1279 1032 -2112 -588 -295 1424 -2751 -2389 SS 20230622T104009.9Z 8573.444559 90 1 30.04 2 80.74 66.31 111.86 28.89 0.00 1 0.00 1 0 17 6.330e-01 1.225e-02 1.794e-01 4.558e-03 7.968764e-01 2.490536e-03 9.044101e-03 -6.000000e+00 3.642180e-01 232.92 -2.00 3.57 -2.00 321.58 0.00e+00 5.214059e-03 1.331615e-03 2.385293e-03 -6.000000e+00 1.598130e-02 284.69 -2.00 20.00 -2.00 321.03 0.00e+00 5.901 0.004 302.00 328.00 3 2.0327e+00 8.9922e-03 7.3110e-02 -6.0000e+00 9.1587e-01 3.2361e-01 1.2885e-02 4.5319e-02 -6.0000e+00 9.9192e-01 -4.3678e-01 1.3137e-02 2.4820e-02 -6.0000e+00 5.8892e-01 1.7065e-01 6.0646e-03 9.2040e-03 -6.0000e+00 2.4756e-01 9.4568e-05 -5.9129e-04 1.1880e-04 1.2551e-04 -6.0000e+00 1.6834e-02 -1.9504e-03 0.0000e+00 12 9 8 11 4 0 -5.64 22.42 0.85 -0.00195 -0.00639 59 59 1 5 0 509.120 30.50 19.96 22.42 26.43 3.7 965.43 -146449 -245764 -244251 -210253 -228728 -206778 -136101 -207549 -155959 -140614 -179351 -168111 -142119 -125501 -77740 -81120 -74013 -63387 -45792 -23058 -83657 -80081 -69782 -22243 -65726 -9560 -62318 -24866 -13240 -28080 -42114 -28958 1260 -10340 -8490 -16732 -35627 -12536 23145 10024 5960 20982 17044 2951 6953 15204 21182 1815 18043 3447 14910 12258 10627 12680 11507 13343 5812 11722 2776 2453 6683 1582 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