File name: Pandora243s1_Downsview_20230624_L2Fit_fout2c6d20230307p1-8.txt
File generation date: 20241101T224140.3Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v1d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt
Level 1 file used: Pandora243s1_Downsview_20230624_L1_smca1c6d20230307p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20230624
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: AnaFld for Downsview
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230624T144525.7Z 8575.614880 254 1 16.95 2 37.65 109.97 99.67 67.26 0.00 1 0.00 1 0 17 1.115e-02 7.120e-03 7.505e-03 4.326e-03 1.976226e-01 2.214013e-03 2.378899e-03 -6.000000e+00 6.416225e-03 232.94 -2.00 3.57 -2.00 315.69 0.00e+00 2.067669e-04 2.166017e-04 4.090382e-05 -6.000000e+00 2.816816e-04 284.89 -2.00 20.00 -2.00 314.98 0.00e+00 1.262 0.000 302.00 328.00 3 6.0705e+00 5.7831e-03 1.6326e-02 -6.0000e+00 1.6134e-02 3.9703e-02 6.4358e-03 1.0412e-02 -6.0000e+00 1.7471e-02 -6.0284e-03 3.6766e-03 5.0334e-03 -6.0000e+00 1.0374e-02 -9.1350e-04 1.6533e-03 1.3667e-03 -6.0000e+00 4.3631e-03 2.8245e-04 2.9600e-04 1.2033e-04 1.6252e-05 -6.0000e+00 2.9640e-04 -4.4950e-03 0.0000e+00 12 9 1 12 5 1 999.00 22.36 0.37 -0.00450 -0.00227 2 9 1 5 0 3380.470 30.00 19.10 22.36 29.85 3.6 989.36 -773 -945 -885 32 -3957 -5634 178 -734 1722 -3683 -1184 -464 1874 360 2056 -1418 40 2660 -1357 2566 2122 1600 643 -585 -9 854 -523 -189 -1038 734 -409 630 1616 -1209 -1360 -1938 -1538 -1272 -103 204 -1007 325 770 -457 -984 243 -920 -199 -1187 -290 533 -163 1035 452 273 1087 347 352 337 503 659 1116 1909 856 264 131 -300 40 108 645 748 -422 548 639 -618 574 -1616 -1591 -1026 -1558 -870 -1712 -1730 -1286 -581 -720 464 584 1236 382 -19 -1035 266 -400 -383 -270 1099 428 770 -687 -304 -124 -673 -290 -631 -156 -56 -444 -346 905 632 206 628 -424 -495 -83 281 -275 531 -189 293 -109 373 791 134 -115 247 35 1048 298 183 -665 14 -279 -17 -65 410 110 89 587 -227 -1102 -605 -189 -243 -223 8 -900 -1293 42 -196 444 -1011 -338 -125 551 121 755 -571 16 1076 -589 1102 916 686 287 -278 -4 426 -256 -85 -437 303 -180 292 791 -595 -618 -899 -796 -710 -68 140 -745 244 588 -352 -757 183 -677 -140 -820 -201 387 -126 829 380 234 938 305 306 287 428 585 986 1798 848 252 113 -259 34 100 623 776 -426 580 647 -583 513 -1337 -1261 -862 -1479 -846 -1831 -1816 -1409 -680 -846 565 728 1522 481 -22 -1173 271 -402 -410 -296 1315 531 987 -862 -377 -141 -746 -339 -806 -195 -73 -604 -492 1266 921 299 914 -574 -652 -103 350 -362 702 -268 422 -156 515 1034 179 -145 295 42 1338 406 243 -909 19 -400 -24 -98 626 173 139 892 -337 -1594 -908
SS 20230624T153923.5Z 8575.652356 291 1 29.87 2 29.05 126.32 90.82 76.72 0.00 1 0.00 1 0 17 8.188e-03 5.649e-03 4.199e-03 2.394e-03 1.759735e-01 1.225460e-03 2.115408e-03 -6.000000e+00 4.712956e-03 232.94 -2.00 3.57 -2.00 315.74 0.00e+00 3.427479e-04 1.219629e-04 2.828712e-05 -6.000000e+00 2.069238e-04 284.89 -2.00 20.00 -2.00 315.03 0.00e+00 1.143 0.000 302.00 328.00 3 6.3031e+00 3.2021e-03 1.4681e-02 -6.0000e+00 1.1851e-02 2.8316e-02 3.5666e-03 9.2781e-03 -6.0000e+00 1.2833e-02 2.9362e-03 2.0357e-03 4.4831e-03 -6.0000e+00 7.6202e-03 -4.8184e-03 9.1023e-04 1.2368e-03 -6.0000e+00 3.2046e-03 2.6251e-04 2.3032e-04 6.7222e-05 1.4439e-05 -6.0000e+00 2.1775e-04 -3.7683e-03 0.0000e+00 11 1 0 11 4 0 99.97 22.38 0.49 -0.00377 -0.00204 22 22 1 5 0 1357.330 29.75 19.82 22.38 32.26 3.6 1007.60 -1922 -1340 655 -1266 -2618 -1604 395 857 -430 163 -2357 -1956 -1182 -130 1538 409 -192 1344 841 280 509 1459 1282 1687 11 596 30 -491 350 295 1383 842 296 -1046 -1879 -1834 -1302 -1151 -717 127 -710 -544 -637 -737 -99 -344 -806 -728 -162 8 705 739 355 1472 513 1009 210 844 580 203 589 833 1706 1124 -268 -61 -1123 -625 125 722 511 380 338 420 284 -370 -738 -775 -828 -1138 -932 -1204 -1790 -1401 -850 -219 147 367 598 314 157 90 -215 -11 -128 144 466 438 612 -83 -692 -757 -741 -443 -252 -313 -581 -15 -188 731 729 48 187 460 -103 -235 27 -68 234 46 200 410 -153 -130 132 310 29 478 463 263 -106 -184 -30 -85 25 79 263 116 -109 -239 -175 -358 -306 -505 -366 171 -301 -562 -337 88 214 -118 45 -641 -551 -368 -45 578 164 -78 555 359 112 224 628 570 711 5 270 13 -219 144 121 587 380 143 -499 -832 -824 -651 -616 -455 90 -541 -426 -509 -588 -78 -268 -609 -529 -113 6 519 574 289 1235 441 804 170 732 496 175 484 734 1598 1099 -254 -52 -973 -529 105 679 518 398 350 416 259 -331 -598 -600 -682 -1054 -875 -1234 -1939 -1584 -950 -261 183 466 753 377 187 97 -212 -11 -131 161 571 543 784 -104 -876 -885 -838 -529 -301 -394 -764 -20 -268 1086 1124 74 271 611 -135 -293 34 -90 307 64 286 578 -211 -171 177 393 35 581 597 331 -139 -245 -41 -119 38 123 419 175 -167 -382 -271 -538 -451
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