File name: Pandora243s1_Downsview_20230630_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T084040.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230630_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230630T111832.7Z 8581.471212 164 1 30.07 2 74.72 72.36 136.53 284.26 0.00 1 0.00 1 0 17 3.959e-01 4.688e-02 1.660e-01 1.173e-02 4.827611e-01 6.126480e-03 6.755753e-03 -6.000000e+00 2.275947e-01 232.97 -2.00 3.57 -2.00 319.87 0.00e+00 1.175443e-02 1.772860e-03 3.598784e-03 -6.000000e+00 1.040756e-02 285.42 -2.00 20.00 -2.00 319.11 0.00e+00 3.723 0.001 302.00 328.00 3 5.3862e+00 1.7745e-02 4.5947e-02 -6.0000e+00 5.7210e-01 4.7085e-01 2.0580e-02 2.7319e-02 -6.0000e+00 6.1972e-01 -4.6782e-01 1.4102e-02 1.6091e-02 -6.0000e+00 3.6838e-01 1.7960e-01 7.2842e-03 7.7991e-03 -6.0000e+00 1.5587e-01 3.1147e-05 -2.7727e-03 3.3908e-04 1.2694e-04 -6.0000e+00 1.0827e-02 6.2384e-03 -1.7652e-04 12 9 8 11 32 0 -1.41 27.96 -0.78 0.00624 -0.01460 8 8 1 5 0 3758.070 36.25 20.00 27.96 27.73 3.6 973.56 -16469 -54087 900000 900000 27839 91457 -34726 -105545 184406 -12059 10944 33225 2443 36567 17728 307965 9987 -48029 -39439 -620 34949 25062 -15868 31272 -25239 28434 51041 -34782 15194 -27967 2741 76658 18748 75807 58178 12981 1910 -25266 52393 80978 56374 14264 -22176 24417 13050 -2286 46048 44760 7872 13976 -8175 9967 6594 4763 37936 -3057 9565 6337 28313 -2769 -4400 8514 -1632 1863 2713 12816 4557 22627 5356 13313 -9536 -710 5900 12261 -6183 -9212 -24975 -7334 1520 982 -6333 -8588 -970 -4313 -7335 8103 -7366 -6770 5247 4431 1739 -2033 -4882 -5504 10170 3861 -5608 -3825 -2357 1847 -923 -2142 45 -438 -2130 -2068 1713 22 1115 571 1185 -446 -1255 2587 5845 -4447 6033 816 3240 3279 1008 -2862 -487 2145 1749 4318 -5251 4828 3647 2025 -1984 -2022 674 -1397 66 -2019 -653 -139 1544 835 -4376 1825 681 -890 -4611 900000 900000 810 1331 -1805 -11631 2109 -527 375 1036 130 1882 1318 3522 959 -7939 -6191 -74 2838 2150 -2032 2503 -3550 2341 3269 -5012 1321 -4094 342 5172 2487 5635 4724 1648 297 -5952 6651 8705 8252 3311 -7684 5389 3268 -677 8426 8343 2143 3724 -2945 3226 2338 1803 10455 -1276 3511 2341 8159 -1093 -1862 3495 -827 989 1424 5701 2116 8850 2738 7125 -6892 -480 3630 6632 -3648 -5004 -14766 -3657 775 587 -4650 -7179 -801 -3857 -6566 7265 -7328 -6849 5142 4171 1549 -1732 -4031 -4651 8141 3757 -6227 -4709 -3036 2230 -1063 -2482 48 -481 -2572 -2623 2202 28 1503 849 1890 -744 -2058 3851 7839 -6315 7809 1170 4844 5134 1610 -4612 -742 3051 2380 6034 -7752 6676 5134 3184 -3488 -3717 1245 -2770 137 -4493 -1462 -315 3436 1798 -9417 3505 1285 SS 20230630T112505.8Z 8581.475762 168 1 30.60 2 73.59 73.39 137.63 285.64 0.00 1 0.00 1 0 17 3.954e-01 2.009e-02 9.820e-02 4.914e-03 4.618751e-01 2.539213e-03 5.579143e-03 -6.000000e+00 2.274940e-01 232.97 -2.00 3.57 -2.00 319.63 0.00e+00 3.540642e-03 7.144441e-04 1.333151e-03 -6.000000e+00 1.018276e-02 285.42 -2.00 20.00 -2.00 318.88 0.00e+00 3.482 0.001 302.00 328.00 3 4.6603e+00 7.2631e-03 4.2516e-02 -6.0000e+00 5.7187e-01 1.4646e-01 8.5640e-03 2.5253e-02 -6.0000e+00 6.1936e-01 -1.5624e-01 6.4410e-03 1.3056e-02 -6.0000e+00 3.6790e-01 6.3371e-02 3.3174e-03 4.4307e-03 -6.0000e+00 1.5506e-01 9.2419e-05 -7.7471e-04 1.3918e-04 5.1259e-05 -6.0000e+00 1.0706e-02 5.7393e-03 -2.9680e-05 12 9 8 11 32 0 99.44 27.96 0.37 0.00574 -0.00008 11 11 1 5 0 2781.060 36.25 20.00 27.96 27.86 3.6 974.22 -16650 -58726 -23799 900000 -47381 -34476 -53005 -87179 404866 -28333 -58251 -94637 7465 -17243 -3455 87264 -19693 17614 26554 -7651 14397 -935 -16852 1007 -24306 734 -5083 -25519 -7065 -20171 -5325 13654 15294 20633 26841 -27397 -6038 -3658 15653 20051 15497 3682 6928 8267 3161 -1466 10359 11988 -3334 5135 -2565 -906 3252 2851 9147 -2711 1784 2499 5480 1545 -435 1896 686 3518 2445 3867 -6353 4348 1413 6421 -3020 153 1905 3760 -1690 -5085 -6599 -693 986 -698 -2652 -4129 -2732 -3241 -2762 2011 -1411 -1783 2283 1866 388 -1375 -1104 -2620 2001 706 -1767 -1037 -1037 641 -1866 -1226 200 -538 -1358 -741 919 38 753 -109 9 576 180 1252 1892 -1139 1884 337 969 803 458 -402 94 58 338 908 -1854 2182 1127 1056 -402 538 485 -805 569 -875 -657 -1334 475 459 -1616 805 -75 -406 -2379 -753 900000 -1566 -1008 -2032 -5263 1940 -1059 -2986 -7935 275 -991 -205 2341 -1651 1089 1578 -663 1000 -75 -1663 88 -2876 70 -502 -2922 -660 -2319 -605 1452 1773 2264 2585 -4647 -934 -659 2805 3958 3460 970 1829 2175 883 -434 2720 3119 -1027 1530 -905 -342 1260 1072 3668 -1142 728 996 2274 668 -184 862 351 1892 1320 1932 -3403 2136 797 3924 -2189 111 1319 2409 -1041 -2904 -3567 -356 555 -465 -2055 -3618 -2310 -2904 -2646 1957 -1487 -1930 2354 1836 358 -1299 -984 -2422 1956 728 -2123 -1281 -1350 798 -2397 -1419 216 -610 -1681 -957 1229 50 1064 -169 16 980 298 1936 2704 -1607 2615 500 1527 1326 757 -651 148 87 482 1230 -2689 3163 1683 1726 -713 916 853 -1509 1123 -1834 -1310 -2728 950 945 -3232 1497 -138 SS 20230630T113024.6Z 8581.479451 171 1 29.99 2 72.67 74.23 138.52 286.79 0.00 1 0.00 1 0 17 2.504e-01 1.776e-02 1.019e-01 4.470e-03 4.337588e-01 2.291093e-03 5.115441e-03 -6.000000e+00 1.439525e-01 232.97 -2.00 3.57 -2.00 319.38 0.00e+00 3.104683e-03 6.019343e-04 3.527827e-04 -6.000000e+00 6.432622e-03 285.43 -2.00 20.00 -2.00 318.62 0.00e+00 3.308 0.001 302.00 328.00 3 4.7132e+00 6.4972e-03 4.0049e-02 -6.0000e+00 3.6196e-01 1.0533e-01 7.6008e-03 2.3414e-02 -6.0000e+00 3.9203e-01 -1.2069e-01 5.5254e-03 1.1649e-02 -6.0000e+00 2.3300e-01 5.4176e-02 2.8536e-03 4.2336e-03 -6.0000e+00 9.8330e-02 1.0821e-04 -7.6163e-04 1.2672e-04 4.1508e-05 -6.0000e+00 6.7037e-03 6.9417e-03 -6.9910e-05 12 9 8 11 32 0 99.68 27.96 0.18 0.00694 0.00122 13 13 1 5 0 2306.220 36.25 20.00 27.96 27.96 3.6 974.90 -10278 -57396 900000 203833 15382 -14011 -48157 -57356 123238 -22821 -65614 -80365 -14334 -2411 1986 47323 -6043 16171 -22472 -1274 11084 -3155 -15463 10817 -17387 8970 -149 -20901 -4025 -9545 -10499 12290 5923 12997 12694 -24227 -2136 -4930 8227 18762 14097 1268 4589 3483 863 499 6466 11843 -2184 3768 3897 -496 1610 2387 10252 -2807 1167 1091 4178 -140 -1120 1315 -723 2712 1607 2221 386 4049 1330 2847 -2981 -804 1397 2002 -1466 -5444 -6159 -2190 -1410 -891 -2064 -3478 -1465 -2705 -2815 2012 -1598 -1079 2613 1003 1217 -506 3592 -1903 2238 345 -420 -1201 -1187 307 -1151 -1847 -55 113 -1307 -124 429 -361 -34 -330 -880 1136 -222 295 1338 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