File name: Pandora243s1_Downsview_20230724_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T225328.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230724_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230724T114005.3Z 8605.486172 110 1 29.78 2 73.66 77.92 136.55 34.39 0.00 1 0.00 1 0 17 2.110e-01 1.487e-02 7.763e-02 3.286e-03 5.109486e-01 1.704854e-03 5.976121e-03 -6.000000e+00 1.212017e-01 232.73 -2.00 3.57 -2.00 319.85 0.00e+00 1.455527e-03 5.279598e-04 4.538543e-04 -6.000000e+00 5.582959e-03 287.01 -2.00 20.00 -2.00 319.09 0.00e+00 3.496 0.001 302.00 328.00 3 4.3309e+00 4.9722e-03 4.4152e-02 -6.0000e+00 3.0432e-01 6.5702e-02 5.9732e-03 2.7540e-02 -6.0000e+00 3.2966e-01 -1.0437e-01 4.7871e-03 1.3548e-02 -6.0000e+00 1.9620e-01 3.9104e-02 2.4607e-03 3.9650e-03 -6.0000e+00 8.3099e-02 1.2314e-04 -6.0596e-04 9.2424e-05 4.3317e-05 -6.0000e+00 5.7668e-03 7.0833e-03 0.0000e+00 12 9 8 11 32 0 99.99 27.90 0.67 0.00708 0.00253 38 38 1 5 0 783.680 36.25 20.00 27.90 27.78 3.6 973.22 -89664 -65341 900000 900000 97561 -74282 -26043 -42408 39979 -19320 -76860 -86241 11826 20710 -62586 12218 -19955 -7070 -15876 18721 20015 -19473 -18475 21000 -26636 9311 -15499 -31675 -4572 -11743 -22053 621 -7052 26332 39872 -19772 -13935 18236 8325 14081 10622 14754 -3253 -2313 2221 -4021 1944 10493 3925 15447 -2426 8471 6576 623 7443 1280 988 1584 1282 3027 -420 -387 153 1154 1862 1502 -2658 3132 -1116 3910 -525 -754 -1853 1646 -2150 -5212 -3320 -96 -578 1461 -2348 -2104 -1198 -1705 -54 686 -121 -653 513 789 1081 78 1058 -434 -227 -87 -542 600 -572 -1006 -895 -1126 215 -839 -1539 -497 230 -1323 636 -279 -874 1719 -512 911 1132 -729 1076 933 29 -1111 -242 357 120 1096 724 710 455 1829 603 505 174 -211 558 14 -181 -571 -69 -876 -132 324 -357 93 -563 -2507 -1579 900000 900000 438 -1903 -459 -1005 461 -421 -3077 -4365 277 544 -4531 474 -1157 -390 -1012 882 936 -1360 -1361 1130 -2457 623 -1311 -2983 -324 -974 -2352 61 -829 2227 2771 -2578 -1955 2237 1376 2553 2171 3048 -758 -539 549 -974 491 2470 1013 3785 -715 2452 2095 225 2620 496 391 613 485 1124 -170 -174 77 620 990 758 -1370 1572 -657 2292 -347 -513 -1245 1003 -1236 -3026 -1778 -51 -346 919 -1757 -1757 -979 -1481 -50 666 -124 -686 528 767 969 71 911 -392 -211 -93 -612 752 -764 -1312 -1079 -1325 236 -974 -1807 -607 294 -1827 872 -426 -1444 2838 -844 1397 1616 -1019 1504 1376 46 -1857 -398 565 184 1597 1085 1020 634 2638 914 843 293 -373 1017 27 -354 -1169 -144 -1870 -277 649 -683 179 -1072 SS 20230724T114514.2Z 8605.489748 113 1 29.85 2 72.75 78.75 136.05 36.03 0.00 1 0.00 1 0 25 1.710e-01 9.732e-03 4.190e-02 2.063e-03 4.933363e-01 1.054415e-03 5.789994e-03 -6.000000e+00 9.822706e-02 232.73 -2.00 3.57 -2.00 319.33 0.00e+00 8.144669e-04 2.787897e-04 4.207341e-04 -6.000000e+00 4.357739e-03 287.01 -2.00 20.00 -2.00 318.54 0.00e+00 3.322 0.001 302.00 328.00 3 3.7749e+00 2.9853e-03 4.2213e-02 -6.0000e+00 2.4669e-01 3.5179e-02 3.4965e-03 2.6501e-02 -6.0000e+00 2.6721e-01 -6.5271e-02 2.6485e-03 1.2900e-02 -6.0000e+00 1.5889e-01 2.4783e-02 1.3875e-03 3.5587e-03 -6.0000e+00 6.6887e-02 2.5888e-04 -7.0746e-04 5.6623e-05 3.6134e-05 -6.0000e+00 4.5493e-03 5.7249e-03 0.0000e+00 12 9 8 11 32 0 99.97 27.90 0.39 0.00572 0.00041 38 38 1 5 0 785.450 36.25 20.00 27.90 28.21 3.6 976.33 -52121 -54954 107865 72296 1026 -71188 6341 -42566 27512 -12462 -58795 -57753 -14016 1705 -9968 -6181 -18040 -639 -6046 6837 9443 -8356 -4404 7304 -17618 -5093 -6621 -16671 -2853 -8566 -10702 -3245 -4557 7486 10387 -12748 -7284 4367 2930 7138 5026 5455 -1722 737 -1 -1482 652 4487 1156 6132 -1468 3892 3878 1159 2553 630 1581 654 1259 1121 627 125 1630 1083 1205 1367 -1782 1425 -797 2044 347 -55 -499 1292 -1058 -2886 -2497 -579 -925 -42 -2159 -1514 -1659 -1605 -822 479 -246 -45 464 959 392 558 989 -444 -280 93 -338 251 -21 -653 -891 -504 -631 -505 -1288 -515 -362 -479 -166 180 -88 434 161 713 -41 -192 748 766 346 -528 255 -4 289 824 370 561 412 1135 470 653 190 -213 78 -145 45 -208 8 -366 -220 -67 -651 -311 39 -1479 -1769 695 611 16 -2392 110 -1379 493 -349 -2697 -2998 -575 73 -574 -387 -1376 -44 -468 487 661 -705 -381 611 -2021 -537 -699 -1842 -269 -927 -1365 -439 -698 1023 1298 -2073 -1280 824 623 1695 1328 1513 -531 224 0 -470 203 1363 372 1993 -569 1565 1543 508 1149 299 758 312 582 518 307 68 899 651 721 772 -1013 808 -518 1476 256 -42 -373 962 -733 -1829 -1477 -341 -614 -30 -1796 -1306 -1533 -1567 -803 492 -266 -50 505 986 400 526 884 -415 -290 102 -401 333 -28 -845 -1133 -615 -727 -609 -1593 -664 -491 -652 -244 274 -138 690 251 1095 -60 -281 1102 1126 544 -831 416 -6 443 1204 548 794 563 1612 706 1075 320 -377 136 -267 84 -409 16 -748 -447 -131 -1208 -574 70 SS 20230724T115022.6Z 8605.493318 116 1 30.08 2 71.84 79.59 135.54 37.63 0.00 1 0.00 1 0 25 7.510e-02 6.498e-03 9.548e-03 1.046e-03 4.709796e-01 5.322120e-04 5.546763e-03 -6.000000e+00 4.315433e-02 232.73 -2.00 3.57 -2.00 318.83 0.00e+00 1.231061e-03 1.202876e-04 2.121480e-04 -6.000000e+00 1.914125e-03 287.01 -2.00 20.00 -2.00 318.01 0.00e+00 3.166 0.001 302.00 328.00 3 2.7476e+00 1.4789e-03 4.0228e-02 -6.0000e+00 1.0838e-01 3.0730e-03 1.7018e-03 2.5207e-02 -6.0000e+00 1.1738e-01 -3.6628e-02 1.1991e-03 1.2193e-02 -6.0000e+00 6.9798e-02 1.2601e-02 6.2867e-04 3.5087e-03 -6.0000e+00 2.9394e-02 8.6853e-04 -2.4726e-04 2.8624e-05 3.5425e-05 -6.0000e+00 1.9976e-03 3.2072e-03 0.0000e+00 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