File name: Pandora243s1_Downsview_20230802_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T073858.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230802_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230802T115911.1Z 8614.499434 261 1 30.35 2 71.61 82.74 101.91 253.90 0.00 1 0.00 1 0 17 1.540e-01 1.263e-02 3.403e-02 2.849e-03 4.424009e-01 1.451040e-03 5.244010e-03 -6.000000e+00 8.839295e-02 232.39 -2.00 3.57 -2.00 319.10 0.00e+00 1.737400e-04 3.550036e-04 2.454351e-04 -6.000000e+00 3.927383e-03 287.18 -2.00 20.00 -2.00 318.30 0.00e+00 3.129 0.001 302.00 328.00 3 4.2220e+00 4.0703e-03 3.8965e-02 -6.0000e+00 2.2180e-01 6.6365e-02 4.7316e-03 2.3769e-02 -6.0000e+00 2.4025e-01 -7.3447e-02 3.3735e-03 1.1496e-02 -6.0000e+00 1.4292e-01 3.2124e-02 1.7551e-03 3.1152e-03 -6.0000e+00 6.0280e-02 2.0902e-04 -2.1734e-04 7.9735e-05 3.3037e-05 -6.0000e+00 4.0973e-03 8.8608e-03 4.2758e-05 12 9 8 11 32 0 97.67 27.93 0.24 0.00886 0.00723 25 25 1 5 0 1214.030 36.25 20.00 27.93 28.74 3.6 979.78 -31939 -47576 97021 36425 -15006 -70026 -51375 -34207 -27810 16274 -54525 -39383 -7531 13261 -28457 17470 -16646 -15772 -2600 -3949 7212 -8306 -781 736 -8046 4888 3237 -17219 -1035 -10464 2508 6250 6225 9264 20654 -10174 -9219 8643 4602 2822 4904 7531 -2027 3642 4742 -1536 4564 2533 -242 5076 -825 4249 2345 1228 2583 -434 -196 1699 1443 2225 -745 -159 1433 1816 1504 1329 -3750 1598 -358 1966 -433 -30 -663 996 -2290 -3377 -2246 544 -835 -61 -2249 -3207 -1952 -1089 -1425 1156 -257 -839 698 554 338 343 1061 -1277 -1139 957 -860 504 97 152 -630 -1000 -379 52 -1474 -415 45 -481 802 369 -334 1532 465 323 237 -913 523 441 -171 -314 241 -1032 175 941 648 615 436 1273 641 684 357 -448 631 124 -464 -524 50 -352 -16 659 -1271 -813 279 -1154 -2181 1051 658 -417 -3463 -2355 -1511 -1275 497 -3454 -2418 -404 693 -2649 1141 -1633 -1639 -249 -399 655 -886 -82 83 -1048 580 382 -2339 -116 -1378 329 889 979 1408 2628 -1821 -1862 1758 1185 778 1433 2247 -686 1169 1513 -525 1459 830 -83 1734 -328 1745 1054 594 1280 -229 -105 878 729 1114 -404 -86 849 1152 945 784 -2253 930 -238 1453 -327 -23 -503 761 -1646 -2199 -1347 319 -553 -46 -1837 -2943 -1885 -1022 -1444 1216 -287 -962 781 589 358 335 973 -1225 -1206 1043 -1079 652 133 200 -776 -1206 -430 61 -1796 -524 59 -678 1125 567 -553 2536 755 493 336 -1336 766 637 -265 -511 389 -1641 267 1361 956 868 592 1785 933 1085 607 -751 1079 223 -850 -1005 98 -700 -31 1241 -2324 -1495 498 SS 20230802T130145.0Z 8614.542882 300 1 9.01 2 60.35 93.44 112.33 263.91 0.00 1 0.00 1 0 17 2.804e-02 9.079e-03 1.354e-02 5.008e-03 2.932392e-01 2.540100e-03 3.551055e-03 -6.000000e+00 1.608972e-02 232.39 -2.00 3.57 -2.00 316.96 0.00e+00 -2.972754e-04 3.357565e-04 1.216062e-04 -6.000000e+00 7.149386e-04 287.19 -2.00 20.00 -2.00 316.14 0.00e+00 2.012 0.000 302.00 328.00 3 4.6527e+00 6.7291e-03 2.5316e-02 -6.0000e+00 4.0372e-02 4.7112e-02 7.5513e-03 1.5616e-02 -6.0000e+00 4.3734e-02 -2.2449e-02 4.4382e-03 7.5406e-03 -6.0000e+00 2.6016e-02 7.5820e-03 2.1295e-03 2.0580e-03 -6.0000e+00 1.0972e-02 4.8172e-04 -5.6102e-05 1.3986e-04 2.2946e-05 -6.0000e+00 7.4596e-04 8.3833e-03 -7.9354e-06 12 9 1 12 33 1 999.00 27.98 0.17 0.00838 0.00796 2 17 1 5 0 1791.550 36.25 20.00 27.98 30.60 3.5 991.12 -3420 -5891 -7537 11777 7747 -9011 -11275 -1637 -981 -2361 -15879 -5890 2555 6618 -2840 2479 -30 -1839 1024 4093 1649 -3317 -959 308 970 1674 560 -3225 -687 -397 -1517 3634 1192 800 -1413 -5360 -2572 599 -299 -225 2134 671 -421 -1589 1082 -7 169 283 -1705 3862 521 2007 1623 1306 1402 885 220 601 633 1226 -279 1021 1053 565 -599 140 -752 -391 90 955 -743 720 132 849 -1489 -171 -1568 -1040 -1157 -1000 -2108 -2778 -1823 -713 -1038 908 15 -229 1285 569 117 -308 -318 -1035 -80 180 49 993 -41 -256 -689 -1766 -579 -805 -436 -223 -126 -635 374 808 877 827 1315 77 -359 -142 -36 129 -290 -151 451 -94 -204 444 848 310 208 1030 940 596 119 241 -114 -37 585 -395 -572 -477 -173 17 -204 -345 -539 -471 -880 -1127 1300 810 -1131 -1603 -240 -156 -387 -2686 -976 447 1281 -685 609 -8 -511 287 1152 476 -1005 -298 101 331 583 191 -1055 -208 -123 -515 1276 425 281 -514 -1913 -1011 272 -152 -131 1291 397 -257 -981 649 -4 107 175 -1065 2348 327 1328 1140 967 1064 645 164 438 484 934 -211 827 927 493 -511 115 -593 -308 78 870 -697 684 132 800 -1314 -142 -1208 -781 -946 -871 -2080 -2851 -1957 -752 -1183 1083 18 -280 1534 684 130 -331 -316 -1037 -86 203 61 1294 -53 -338 -850 -2133 -664 -980 -543 -290 -172 -865 533 1171 1333 1259 1904 110 -497 -187 -48 179 -415 -217 651 -140 -296 611 1161 406 274 1310 1292 835 176 365 -168 -57 912 -651 -965 -820 -296 27 -325 -555 -853 SS 20230802T130639.6Z 8614.546291 303 1 29.95 2 59.47 94.33 113.16 264.71 0.00 1 0.00 1 0 17 9.181e-03 5.165e-03 1.013e-03 5.036e-04 2.802280e-01 2.571596e-04 3.388535e-03 -6.000000e+00 5.269075e-03 232.39 -2.00 3.57 -2.00 316.25 0.00e+00 3.086841e-04 2.866880e-05 4.337866e-05 -6.000000e+00 2.341065e-04 287.19 -2.00 20.00 -2.00 315.46 0.00e+00 1.960 0.000 302.00 328.00 3 2.4463e+00 6.7383e-04 2.4420e-02 -6.0000e+00 1.3221e-02 1.1194e-02 7.5245e-04 1.4822e-02 -6.0000e+00 1.4321e-02 -3.4008e-03 4.3290e-04 7.1665e-03 -6.0000e+00 8.5192e-03 -8.5609e-04 1.9973e-04 1.9600e-03 -6.0000e+00 3.5934e-03 4.7463e-03 1.2364e-04 1.3928e-05 2.2511e-05 -6.0000e+00 2.4423e-04 8.9082e-03 5.4337e-05 10 0 0 10 0 0 99.34 27.98 0.48 0.00891 0.00984 189 189 1 5 0 158.360 36.25 20.00 27.98 30.69 3.5 992.05 -1487 -1592 -910 -2946 -4012 -3895 -1989 353 79 -1124 -2564 -1882 -747 632 71 354 296 643 1325 1262 931 434 697 650 468 1128 -31 -639 -370 358 940 1804 792 -740 -1626 -2510 -1481 -79 -27 -171 -366 -356 -551 -205 -96 -302 -389 -325 -570 472 470 979 889 751 609 472 465 424 351 421 617 1102 1512 1004 171 -421 -765 -146 464 534 299 135 96 -107 -339 -522 -588 -461 -470 -593 -701 -1312 -1664 -1557 -1006 -303 -10 145 382 496 477 270 159 234 279 213 400 447 161 -236 -637 -728 -342 -348 -525 -560 -413 -430 39 268 301 394 294 161 146 0 110 73 108 -207 -34 -52 131 454 582 303 507 693 536 370 102 -10 90 -43 -10 -112 47 6 -148 -131 -404 -359 -451 -301 -316 -191 -567 -710 -697 -386 76 17 -251 -574 -453 -205 183 22 117 101 229 489 452 335 157 263 261 197 485 -13 -251 -138 136 385 796 359 -334 -688 -1103 -729 -41 -16 -110 -240 -242 -384 -143 -66 -209 -264 -216 -374 315 338 715 658 585 487 371 370 333 282 339 499 928 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