File name: Pandora243s1_Downsview_20230806_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T073137.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230806_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230806 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230806T104533.1Z 8618.448300 219 1 30.83 2 85.20 71.41 41.48 209.81 0.00 1 0.00 1 0 49 9.192e-01 2.396e-01 3.288e-01 6.100e-02 7.785923e-01 3.406326e-02 1.013103e-02 -6.000000e+00 5.340061e-01 232.24 -2.00 3.57 -2.00 317.37 0.00e+00 -3.288583e-02 3.475933e-03 4.955643e-03 -6.000000e+00 2.463236e-02 287.26 -2.00 20.00 -2.00 316.08 0.00e+00 10.086 0.020 302.00 328.00 3 3.8389e-01 8.8678e-02 1.1851e-01 -6.0000e+00 1.3438e+00 2.5443e+00 1.0012e-01 9.4107e-02 -6.0000e+00 1.4584e+00 -1.6530e+00 5.5927e-02 2.1124e-02 -6.0000e+00 8.6370e-01 3.7253e-01 2.6191e-02 3.3301e-02 -6.0000e+00 3.6507e-01 4.9734e-06 5.9006e-03 1.6245e-03 1.4157e-04 -6.0000e+00 2.5650e-02 4.1369e-03 3.4184e-04 12 9 8 11 32 0 -1.56 28.90 4.33 0.00414 0.04848 12 12 1 5 0 2569.120 37.00 20.00 28.90 24.39 3.6 948.34 119750 -25588 68457 131346 80259 -19690 -318 26053 30190 900000 -35955 -15402 163212 104524 93821 900000 -5664 8849 -26593 89927 38480 55096 49197 132474 182892 144317 33700 11049 28248 -27405 86270 171346 53119 152544 -3566 63782 44666 900000 228607 143068 285065 49776 106147 127335 24720 207453 220720 119929 -18834 900000 -51995 900000 27360 -6227 900000 25424 75687 51638 142046 78260 -57810 -34 51942 1220 27511 900000 97880 129781 -6563 251086 12701 -24182 15276 900000 -15829 -71077 -66624 203969 128378 265449 -15553 -8166 58323 124432 1435 363024 9354 -1996 12438 62683 58281 1154 10937 -37733 -16685 200006 45624 58355 22720 13725 61584 -24933 152811 53392 -6429 30250 96744 -6050 9027 12116 25500 56157 7603 7390 4397 7596 -4789 7400 12551 27938 815 -35051 -1361 21807 7574 9930 -29956 -4871 32336 -4223 4021 -18595 17702 10724 -4579 -18210 -6415 -2994 -3053 21427 -4103 55719 45206 18968 -15959 14232 11703 10726 -7895 -129 9801 12254 900000 -28120 -9682 16966 19661 21785 900000 -3084 4396 -16454 17967 12052 14876 16471 22891 20740 23379 14012 4534 8237 -13615 14441 12954 13481 13180 -1329 12399 12060 900000 14814 24722 16933 21772 24074 20628 10011 12323 13111 15543 -9865 900000 -43800 900000 11819 -4001 900000 13043 23296 18682 18409 17327 -48699 -17 16548 672 11142 900000 18499 18922 -4217 14914 7750 -21023 8331 900000 -9060 -61793 -52166 12116 18301 15767 -11086 -5997 23306 29565 1116 21563 7723 -1814 9309 26063 23194 768 6562 -39671 -16056 24948 30081 37435 21323 13370 33654 -28731 28138 27909 -6492 21921 37927 -7115 10134 14825 29839 50035 10884 10141 5877 9565 -6969 9978 16849 32361 1190 -69956 -1875 22927 8862 10912 -48755 -6800 35726 -7551 7238 -44734 31545 22103 -11832 -56031 -17871 -8162 -8141 42128 -9749 68841 62029 SS 20230806T105531.0Z 8618.455220 222 1 29.97 2 83.48 73.08 42.36 213.19 0.00 1 0.00 1 0 25 6.442e-01 5.071e-02 2.097e-01 1.207e-02 8.787877e-01 6.593696e-03 1.000124e-02 -6.000000e+00 3.727904e-01 232.24 -2.00 3.57 -2.00 321.69 0.00e+00 -3.560397e-03 2.762428e-03 2.744769e-03 -6.000000e+00 1.805041e-02 287.26 -2.00 20.00 -2.00 321.06 0.00e+00 7.978 0.010 302.00 328.00 3 9.1924e-01 2.2545e-02 9.2998e-02 -6.0000e+00 9.3626e-01 1.6264e+00 2.6475e-02 5.2000e-02 -6.0000e+00 1.0169e+00 -1.9471e+00 1.5124e-02 2.2401e-02 -6.0000e+00 6.0248e-01 7.3897e-01 8.0740e-03 7.6535e-03 -6.0000e+00 2.5399e-01 3.1057e-05 -1.7980e-04 3.1498e-04 7.7028e-05 -6.0000e+00 1.7458e-02 8.4338e-03 1.1611e-04 12 9 8 11 32 0 -19.54 28.90 1.25 0.00843 0.00708 78 78 1 5 0 384.170 37.00 20.00 28.90 24.92 3.6 953.26 202221 7726 900000 85027 -18482 -67225 -44366 1506 -20139 900000 77234 -19410 143061 300398 30735 317164 42285 36984 40549 -10168 35184 -24415 14070 207389 -10435 900000 67831 25248 1835 -4702 -22502 73468 39038 172471 900000 -47970 40322 206140 112357 140408 116182 44789 45508 91279 27994 32482 89024 62947 18735 150024 -22409 86758 42254 5997 92498 42436 34773 22683 33877 25292 -20254 320 -39784 13865 29024 47577 2393 32734 -1439 45037 9874 1565 6713 21150 -12688 -44989 -30948 29123 16677 32143 -3144 -10781 9001 -2259 2068 15746 583 -11204 2647 7696 8650 -2929 12876 -9513 -11851 9365 -4745 1069 1166 -2511 3536 -9079 -4015 2474 -8159 -72 7389 -8859 -1630 -1589 -5457 7013 1311 6719 -525 -8367 -2672 -230 -240 6090 9024 -1389 -1516 1253 4949 1643 -3051 644 2838 1959 430 -1983 2324 2074 656 -1702 487 -2433 -1451 -1509 -1385 3378 387 3891 1008 900000 3635 -1817 -9988 -5311 118 -1959 900000 2642 -1909 3211 3532 2727 3729 3571 3281 3337 -1304 2595 -3027 1203 2660 -1182 900000 3045 1511 129 -382 -2526 3534 2837 3447 900000 -6768 2797 3151 5152 5448 6011 4740 4655 5581 3061 3284 5024 4663 2225 5115 -4716 6631 5366 1156 7722 5938 5192 3600 4421 3390 -4334 61 -12770 2869 5221 6881 549 5850 -408 9055 2995 517 1989 4899 -3610 -15658 -8988 4931 3745 7408 -1205 -5083 3768 -1116 1038 7239 322 -7021 1413 3683 3804 -1377 5178 -5224 -7775 5869 -4017 985 1152 -2524 3085 -7964 -3068 1821 -7195 -62 6264 -9656 -1870 -1914 -7723 9371 1881 8942 -721 -12163 -3770 -335 -369 8957 12462 -2022 -2135 1663 6750 2249 -4316 874 4413 3534 879 -4486 5380 5181 1641 -4550 1293 -6728 -3907 -3823 -3535 7634 874 SS 20230806T110549.5Z 8618.462379 225 1 29.83 2 81.70 74.80 43.36 216.58 0.00 1 0.00 1 0 17 4.311e-01 2.350e-02 8.735e-02 3.453e-03 7.636065e-01 1.834082e-03 8.969064e-03 -6.000000e+00 2.472929e-01 232.24 -2.00 3.57 -2.00 321.27 0.00e+00 5.275798e-04 8.810472e-04 4.588448e-03 -6.000000e+00 1.099660e-02 287.26 -2.00 20.00 -2.00 320.65 0.00e+00 6.498 0.005 302.00 328.00 3 1.0174e+00 6.3539e-03 7.9592e-02 -6.0000e+00 6.2026e-01 5.3132e-01 8.2260e-03 5.2026e-02 -6.0000e+00 6.7193e-01 -8.1434e-01 6.9161e-03 2.2007e-02 -6.0000e+00 3.9978e-01 3.4438e-01 3.3052e-03 5.8869e-03 -6.0000e+00 1.6869e-01 1.5944e-04 -5.0845e-04 8.9295e-05 8.6725e-05 -6.0000e+00 1.1468e-02 9.3497e-03 7.3534e-05 12 9 8 11 32 0 68.69 28.90 0.83 0.00935 0.00553 78 78 1 5 0 382.350 37.00 20.00 28.90 25.77 3.6 957.99 -61047 -156481 32380 -78931 -161625 -169139 -171340 -105587 -126268 -19044 -167337 -111983 -44348 23325 -39952 56961 -38854 -39813 -20476 -54730 -8987 -53018 -16335 36258 -52705 -5136 4408 -23066 -2288 -8200 -29237 53246 -3315 25956 120521 -34216 -10630 78477 34271 47402 46527 26867 31961 37772 22588 10197 29731 24606 15390 35404 2196 28172 20764 12477 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