File name: Pandora243s1_Downsview_20230812_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T071818.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230812_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230812 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230812T151701.8Z 8624.636826 380 1 30.37 2 39.38 127.29 18.52 213.38 0.00 1 0.00 1 0 17 1.220e-02 6.639e-03 2.933e-03 1.702e-03 1.997812e-01 8.690701e-04 2.434086e-03 -6.000000e+00 6.993651e-03 232.01 -2.00 3.57 -2.00 315.66 0.00e+00 -3.656893e-04 8.549107e-05 5.702305e-05 -6.000000e+00 3.113334e-04 287.38 -2.00 20.00 -2.00 314.91 0.00e+00 1.292 0.000 302.00 328.00 3 5.4324e+00 2.2635e-03 1.6623e-02 -6.0000e+00 1.7530e-02 1.5631e-02 2.5207e-03 1.0555e-02 -6.0000e+00 1.8991e-02 2.1541e-03 1.4414e-03 5.1217e-03 -6.0000e+00 1.1302e-02 -2.6177e-03 6.5002e-04 1.4267e-03 -6.0000e+00 4.7741e-03 5.2206e-04 2.9079e-04 4.7349e-05 1.6988e-05 -6.0000e+00 3.2437e-04 6.8166e-03 8.6381e-05 12 9 1 12 33 1 100.00 29.04 0.50 0.00682 0.00900 30 31 1 5 0 979.390 37.00 20.00 29.04 27.92 3.6 974.03 3205 -251 543 -3630 -3864 -1631 -1551 -656 -1076 3326 -3555 -4772 -1115 2543 2371 3181 -1358 -714 -400 -297 -502 604 -1405 2291 -398 1410 -125 -787 -434 -246 286 2699 427 -319 413 -4564 -1928 1026 1177 47 58 -850 -518 9 -843 -638 336 -667 -1319 1246 1194 992 387 1236 1227 147 221 872 863 103 -238 1019 1416 998 -56 101 -1146 -34 118 399 10 35 77 -68 -682 -768 -933 -412 231 -78 -992 -1624 -1583 -1146 -1190 245 91 92 326 294 486 131 656 -186 -471 182 410 793 313 62 -499 -1078 213 -308 -860 -351 68 -463 147 264 71 529 162 333 -113 -115 -3 -184 185 243 100 61 -185 568 1006 289 -226 659 667 318 -381 56 103 -86 -179 -330 269 -399 81 249 -436 -199 -399 798 -68 141 -875 -839 -348 -362 -171 -307 914 -1016 -1451 -365 904 859 1205 -548 -295 -170 -130 -219 259 -638 1058 -197 701 -61 -354 -181 -103 126 1230 212 -155 184 -2191 -1014 573 784 34 44 -664 -411 7 -664 -495 250 -483 -935 872 887 783 323 992 1004 124 188 727 706 85 -206 941 1312 965 -52 91 -968 -28 106 380 10 37 80 -68 -673 -676 -799 -338 201 -71 -956 -1717 -1758 -1252 -1401 287 112 116 407 369 556 144 659 -185 -503 200 497 991 406 78 -622 -1246 249 -363 -1106 -445 90 -639 200 379 106 782 227 453 -141 -144 -4 -232 249 331 139 84 -261 755 1263 367 -274 804 867 415 -521 78 144 -119 -264 -510 402 -615 125 372 -666 -293 -580 SS 20230812T152136.2Z 8624.640002 383 1 29.98 2 38.73 128.71 18.98 216.10 0.00 1 0.00 1 0 17 6.923e-03 5.277e-03 3.868e-04 2.790e-04 1.941380e-01 1.436778e-04 2.381470e-03 -6.000000e+00 3.970118e-03 232.01 -2.00 3.57 -2.00 314.78 0.00e+00 3.292807e-04 1.189774e-05 2.388818e-05 -6.000000e+00 1.767328e-04 287.38 -2.00 20.00 -2.00 314.12 0.00e+00 1.281 0.000 302.00 328.00 3 2.0984e+00 3.7051e-04 1.6336e-02 -6.0000e+00 9.9516e-03 -4.4943e-04 4.1107e-04 1.0259e-02 -6.0000e+00 1.0781e-02 3.3084e-03 2.3479e-04 4.9773e-03 -6.0000e+00 6.4161e-03 -3.5537e-03 1.0210e-04 1.3778e-03 -6.0000e+00 2.7102e-03 1.5034e-02 2.4256e-04 7.6863e-06 1.7694e-05 -6.0000e+00 1.8413e-04 6.5385e-03 8.4559e-05 10 0 0 10 0 0 99.70 29.04 0.46 0.00654 0.00836 368 368 1 5 0 81.450 37.00 20.00 29.04 28.30 3.6 977.46 -334 -719 -1221 -2330 -2182 -1608 178 976 643 -299 -1071 -714 -96 559 712 215 225 660 879 1158 665 809 554 672 435 326 -95 -279 82 574 1079 1510 854 -926 -1791 -1934 -1277 -359 -170 -453 -656 -720 -665 -489 -384 -438 -524 -509 -544 235 543 745 849 712 579 714 506 430 327 492 634 1060 1449 934 131 -399 -693 -179 386 384 348 137 231 18 -214 -327 -451 -455 -329 -494 -702 -1274 -1556 -1525 -921 -419 -87 118 302 352 362 148 133 285 269 237 491 562 243 -176 -474 -583 -357 -286 -493 -540 -522 -441 -1 247 351 360 319 132 114 -40 20 49 51 -139 -55 -13 122 404 603 414 558 656 573 441 126 -34 -35 -59 -22 -81 25 -49 -109 -124 -310 -376 -533 -124 -280 -466 -846 -711 -521 62 357 256 -121 -423 -280 -42 260 350 107 114 343 470 608 351 422 299 382 247 189 -54 -151 43 302 596 846 491 -528 -993 -1097 -775 -236 -124 -348 -519 -588 -553 -405 -316 -357 -413 -400 -416 181 441 618 715 626 502 630 451 379 284 428 576 1004 1388 934 126 -369 -616 -156 355 378 358 142 241 18 -210 -304 -392 -392 -293 -466 -697 -1349 -1691 -1694 -1043 -493 -104 145 368 417 412 161 139 292 287 264 574 686 308 -217 -570 -665 -403 -334 -598 -671 -662 -582 -1 336 495 503 431 172 142 -49 24 61 66 -188 -74 -17 161 528 764 511 670 798 707 564 165 -45 -47 -81 -31 -116 37 -72 -161 -182 -450 -529 -755 SS 20230812T153539.1Z 8624.649758 389 1 1.54 2 36.81 133.29 20.58 223.75 0.00 1 0.00 1 0 17 8.419e-03 6.901e-03 7.048e-03 5.098e-03 1.879294e-01 2.629081e-03 2.278456e-03 -6.000000e+00 4.826231e-03 232.01 -2.00 3.57 -2.00 314.75 0.00e+00 2.312610e-04 2.159518e-04 2.535168e-05 -6.000000e+00 2.148813e-04 287.38 -2.00 20.00 -2.00 314.09 0.00e+00 1.248 0.000 302.00 328.00 3 3.1874e+00 6.7799e-03 1.5833e-02 -6.0000e+00 1.2098e-02 3.7092e-03 7.5185e-03 9.8560e-03 -6.0000e+00 1.3107e-02 7.5413e-03 4.2942e-03 4.7767e-03 -6.0000e+00 7.8004e-03 -4.6745e-03 1.8682e-03 1.3119e-03 -6.0000e+00 3.2942e-03 5.2706e-03 1.9219e-04 1.4055e-04 1.6814e-05 -6.0000e+00 2.2396e-04 6.4635e-03 3.2578e-06 12 9 1 12 33 1 999.00 29.05 0.54 0.00646 0.00791 1 115 1 5 0 259.760 37.00 20.00 29.05 29.53 3.5 983.15 -652 -803 -128 -1802 -460 -31 -184 1557 905 -1916 -1082 -1020 -2257 -89 434 -549 -25 -46 1399 2147 1252 -523 -158 949 1344 769 -383 -133 80 -482 2037 2236 275 132 -1460 -1816 -571 -802 0 -1135 544 -550 -1618 -103 -568 -621 -632 -859 -592 -984 242 1090 868 -4 1825 2004 611 147 756 -196 135 575 1368 503 265 -331 -197 86 59 582 648 774 313 -192 -346 -615 -255 -274 -49 -250 -150 -2022 -1973 -2264 -943 -513 -18 -302 246 599 20 1052 144 668 46 -417 1006 108 680 -502 -414 -873 72 553 -513 -27 -396 -185 210 52 308 -6 -256 -26 -237 361 -244 27 29 304 401 -670 347 863 241 -16 1165 -30 700 -36 185 -170 290 -355 553 -328 248 63 247 -634 -630 339 -869 -239 -307 -47 -638 -154 -10 -63 591 353 -770 -418 -414 -981 -40 217 -277 -13 -24 747 1172 688 -276 -86 537 789 442 -225 -71 42 -255 1111 1232 164 77 -796 -1018 -340 -541 0 -881 439 -446 -1352 -84 -466 -504 -513 -674 -468 -789 195 892 746 -3 1586 1768 552 132 661 -174 121 535 1355 505 263 -307 -175 76 54 569 660 809 324 -197 -338 -555 -222 -230 -44 -235 -151 -2128 -2115 -2483 -1069 -602 -22 -371 306 723 23 1142 148 695 48 -469 1165 135 847 -627 -495 -995 81 640 -616 -34 -506 -240 277 70 433 -8 -348 -34 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