File name: Pandora243s1_Downsview_20230815_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T231850.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230815_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230815T120609.5Z 8627.504276 133 1 29.76 2 72.51 87.13 62.42 86.37 0.00 1 0.00 1 0 17 8.137e-02 7.359e-03 1.885e-02 1.972e-03 4.433457e-01 9.999464e-04 5.233344e-03 -6.000000e+00 4.661152e-02 231.90 -2.00 3.57 -2.00 318.91 0.00e+00 5.867839e-04 2.330597e-04 1.961559e-04 -6.000000e+00 2.077501e-03 287.44 -2.00 20.00 -2.00 318.10 0.00e+00 3.279 0.001 302.00 328.00 3 3.7991e+00 2.7871e-03 4.0051e-02 -6.0000e+00 1.1680e-01 3.7979e-02 3.2175e-03 2.3730e-02 -6.0000e+00 1.2658e-01 -3.7478e-02 2.2976e-03 1.1475e-02 -6.0000e+00 7.5341e-02 1.1350e-02 1.2080e-03 3.1803e-03 -6.0000e+00 3.1794e-02 2.8060e-04 -1.1465e-04 5.4945e-05 3.2608e-05 -6.0000e+00 2.1641e-03 3.9112e-03 0.0000e+00 11 9 0 11 32 0 98.93 28.08 0.53 0.00391 0.00305 43 43 1 5 0 691.930 36.25 19.99 28.08 26.70 3.6 964.23 4079 1836 6654 -20901 -19551 -39695 -38265 -34272 -23768 -14763 -35828 -30266 -13389 3741 6849 2486 -2341 -8024 -4256 -285 -1915 1015 -2923 3260 -3264 12616 -5259 385 -6243 -4283 -8115 1573 971 3267 3283 -9027 -5087 4695 1618 3970 880 1005 709 201 -25 202 1714 1465 -739 3127 -1715 1798 235 115 2904 799 -245 445 305 -729 -471 974 1883 1742 1030 867 -2265 91 317 750 -159 363 5 765 -1080 -118 -642 -226 313 190 -953 -1729 -1660 -1470 -1362 253 -473 15 211 761 664 208 13 -630 -97 653 -148 453 182 -356 -617 -612 119 -458 -905 -153 -450 -817 444 272 139 758 51 560 -141 -404 269 286 87 36 124 -300 -193 554 620 140 -238 826 892 532 -368 -57 16 160 -202 -182 92 -117 -95 392 -506 -359 -230 99 50 174 -659 -560 -1427 -1516 -1496 -1038 -613 -1881 -1699 -767 218 457 194 -205 -799 -431 -29 -200 103 -330 375 -427 1463 -717 47 -789 -568 -1273 253 174 574 542 -1741 -1076 987 427 1186 294 352 258 74 -9 76 630 543 -285 1222 -708 781 111 58 1485 431 -136 242 162 -392 -265 550 1171 1168 687 543 -1420 57 222 554 -128 298 4 579 -758 -79 -404 -143 219 144 -830 -1575 -1612 -1504 -1405 273 -540 18 242 823 707 206 12 -609 -104 732 -178 572 241 -461 -787 -709 138 -563 -1137 -200 -587 -1133 655 416 216 1192 79 844 -211 -578 389 412 135 58 199 -471 -294 802 903 195 -322 1155 1301 849 -600 -96 28 280 -379 -341 175 -227 -185 726 -944 -639 -401 SS 20230815T121120.6Z 8627.507878 136 1 30.04 2 71.58 88.01 61.52 87.23 0.00 1 0.00 1 0 25 3.665e-02 5.732e-03 2.947e-03 5.501e-04 4.231711e-01 2.787658e-04 5.022356e-03 -6.000000e+00 2.099777e-02 231.90 -2.00 3.57 -2.00 318.17 0.00e+00 7.404159e-04 5.150555e-05 1.793895e-04 -6.000000e+00 9.358476e-04 287.44 -2.00 20.00 -2.00 317.33 0.00e+00 3.123 0.001 302.00 328.00 3 1.6271e+00 7.5572e-04 3.8099e-02 -6.0000e+00 5.2618e-02 2.0071e-02 8.5730e-04 2.2474e-02 -6.0000e+00 5.7020e-02 -3.3552e-02 5.5083e-04 1.0846e-02 -6.0000e+00 3.3939e-02 1.2337e-02 2.8377e-04 2.9997e-03 -6.0000e+00 1.4324e-02 2.9476e-03 -1.6634e-04 1.5113e-05 3.1022e-05 -6.0000e+00 9.7476e-04 3.3060e-03 0.0000e+00 10 0 0 10 0 0 96.96 28.07 0.43 0.00331 0.00206 362 362 1 5 0 82.960 36.25 20.00 28.07 26.96 3.6 966.66 -9568 -14808 -4974 -13197 -15780 -15850 -12068 -11367 -10282 -8394 -12659 -9357 -5639 -2056 -382 -633 -424 -53 627 -211 325 -132 -135 358 -234 392 -686 -2210 -2281 -1550 -655 1001 1142 -376 -2219 -3557 -2199 -75 408 650 252 285 145 677 608 520 346 297 83 1158 819 1156 1187 996 1223 1052 618 617 585 438 830 1456 1836 1277 886 -66 -524 -151 282 363 294 81 150 -57 -464 -874 -780 -774 -649 -686 -981 -1448 -1756 -1804 -1168 -461 -191 71 433 451 464 288 138 74 23 90 384 445 162 -361 -768 -782 -521 -441 -685 -671 -469 -372 54 351 337 383 370 220 186 77 156 194 78 -77 73 105 239 452 495 341 457 703 599 452 135 37 -14 -36 -65 -114 102 -81 -90 -213 -410 -347 -472 -519 -925 -284 -749 -844 -867 -708 -758 -752 -625 -1003 -806 -563 -216 -47 -86 -61 -8 101 -36 55 -23 -25 70 -45 78 -136 -417 -457 -301 -143 241 304 -102 -573 -961 -616 -25 151 260 109 130 68 320 289 249 165 143 41 551 428 617 679 607 729 648 389 383 355 267 530 962 1339 956 657 -48 -374 -110 217 302 253 72 130 -49 -365 -651 -569 -566 -501 -584 -909 -1433 -1780 -1854 -1234 -516 -215 82 491 505 497 297 140 74 24 103 460 575 213 -478 -981 -943 -619 -531 -863 -856 -629 -510 77 523 520 600 563 323 262 108 221 279 116 -117 111 160 354 659 711 469 625 964 876 697 216 59 -23 -61 -115 -205 182 -148 -163 -383 -725 -585 -806 SS 20230815T122046.5Z 8627.514427 139 1 8.62 2 69.87 89.63 59.87 88.80 0.00 1 0.00 1 0 25 2.991e-02 5.821e-03 4.553e-03 1.126e-03 3.904254e-01 5.703864e-04 4.652745e-03 -6.000000e+00 1.713791e-02 231.90 -2.00 3.57 -2.00 317.75 0.00e+00 6.731417e-04 9.399705e-05 1.355178e-04 -6.000000e+00 7.637896e-04 287.44 -2.00 20.00 -2.00 316.91 0.00e+00 2.875 0.000 302.00 328.00 3 1.9573e+00 1.5311e-03 3.5089e-02 -6.0000e+00 4.2945e-02 9.6129e-03 1.7281e-03 2.0693e-02 -6.0000e+00 4.6537e-02 -2.3777e-02 1.0661e-03 9.9850e-03 -6.0000e+00 2.7699e-02 9.0068e-03 5.3758e-04 2.7601e-03 -6.0000e+00 1.1691e-02 2.7987e-03 -5.8928e-05 3.1076e-05 2.9089e-05 -6.0000e+00 7.9547e-04 2.7002e-03 0.0000e+00 12 1 1 12 1 1 52.49 28.08 0.47 0.00270 0.00226 59 237 1 5 0 126.720 36.25 20.00 28.08 27.74 3.5 971.39 -6492 -10525 -6981 -9466 -12890 -14842 -12775 -6950 -7236 -6320 -10151 -7027 -3428 -1129 593 680 -112 720 308 974 1260 -68 -57 1331 14 1333 -464 -732 -1563 -484 60 1827 1128 -472 -2073 -2622 -2123 92 411 683 -189 306 555 231 141 597 288 362 158 1128 809 1373 1028 765 974 1039 603 407 301 329 592 1022 1488 1235 599 -130 -779 -63 354 685 253 139 -24 139 -641 -755 -810 -828 -781 -738 -783 -1371 -1786 -1973 -1101 -420 -156 43 276 436 376 188 144 4 91 134 248 532 70 -296 -850 -645 -437 -371 -525 -588 -505 -399 48 399 422 553 350 84 258 154 48 141 133 18 77 76 167 529 488 320 558 747 726 410 143 -14 -14 -151 -101 -258 -51 0 -54 -51 -360 -445 -474 -503 -839 -594 -753 -971 -1162 -1089 -638 -670 -599 -1013 -756 -424 -162 98 114 -20 136 62 201 262 -14 -13 316 3 321 -112 -179 -373 -120 15 514 352 -149 -623 -816 -694 35 178 319 -91 153 285 120 73 312 150 188 83 611 453 828 630 500 656 684 405 271 196 215 405 728 1111 988 473 -101 -585 -48 284 597 229 129 -22 120 -533 -589 -614 -626 -624 -650 -719 -1349 -1806 -2110 -1212 -473 -184 50 328 491 404 194 144 4 98 152 305 682 94 -388 -1072 -766 -511 -441 -656 -771 -675 -544 67 592 647 857 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