File name: Pandora243s1_Downsview_20230822_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T065923.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230822_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230822 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230822T110317.3Z 8634.460617 63 1 29.46 2 85.01 78.46 144.93 41.46 0.00 1 0.00 1 0 33 8.816e-01 2.462e-01 3.093e-01 6.529e-02 6.872500e-01 3.536023e-02 7.304850e-03 -6.000000e+00 5.151167e-01 231.28 -2.00 3.57 -2.00 317.66 0.00e+00 -2.114906e-02 4.250700e-03 2.944099e-03 -6.000000e+00 2.402060e-02 286.90 -2.00 20.00 -2.00 316.20 0.00e+00 9.812 0.018 302.00 328.00 3 8.1429e-01 9.1311e-02 1.0686e-01 -6.0000e+00 1.2923e+00 2.3570e+00 1.0413e-01 6.1447e-02 -6.0000e+00 1.4061e+00 -1.4173e+00 6.1707e-02 1.6008e-02 -6.0000e+00 8.3036e-01 2.8240e-01 2.9225e-02 1.8194e-02 -6.0000e+00 3.5228e-01 4.6813e-06 1.0917e-02 1.8307e-03 1.3859e-04 -6.0000e+00 2.5151e-02 9.6820e-03 2.3117e-04 12 9 8 11 32 0 -1.01 28.01 4.54 0.00968 0.09172 9 9 1 5 0 3273.030 36.25 20.00 28.01 22.98 3.6 938.06 900000 50146 900000 25328 900000 32819 104787 -17900 9284 -8540 37637 13044 267252 221656 900000 55536 -17103 39547 78173 43038 147283 29172 67955 900000 -2079 59035 -26113 14997 -15653 -66068 -3792 202712 123880 900000 111249 -67289 84283 900000 163847 198017 89205 44197 20666 50161 -26837 37162 372721 157104 29518 900000 -8106 32644 6681 162389 900000 -15617 44006 131222 132706 -24474 -890 163823 32421 11199 113377 900000 -32021 283717 34185 111326 4496 51185 5140 166888 -25123 -68233 16113 62218 138164 194063 -17648 -21627 48239 204832 36164 15548 36807 4355 52242 121286 1255 -7662 215341 -18399 14991 64373 -25615 19683 11046 -9285 14851 18495 107042 63942 10952 47166 64110 -19760 28859 4571 -20974 39872 -16561 60194 7146 715 88389 20562 18195 33405 1109 -18247 -6177 -13853 -2808 -13986 -38711 26693 1089 20513 7770 -1949 44469 -3004 -7842 -414 -4110 -21469 -1605 28353 4897 65213 16601 900000 12746 900000 5767 900000 7299 13317 -8815 3687 -3979 10962 5042 16982 14085 900000 15881 -9962 13936 18063 13426 15315 10280 18450 900000 -1297 18757 -16442 5198 -6782 -49234 -1621 12881 15744 900000 13496 -51699 16554 900000 20823 19446 26281 19659 10745 17676 -18914 12881 23684 15428 10572 900000 -4870 13766 3860 20638 900000 -12359 18558 21225 19165 -16117 -473 17981 14234 6146 20959 900000 -24232 18029 16193 26367 3169 21880 3207 18317 -16255 -60701 5957 15455 18357 18497 -14273 -19740 22850 23429 21309 11587 24558 3930 27553 29287 925 -5842 17789 -17186 11336 33542 -36948 19511 11863 -11387 12834 13868 32649 32099 9813 30571 37072 -28503 28424 6361 -40117 41806 -29570 47047 8990 950 50550 24433 23124 36298 1600 -30727 -8910 -20686 -3622 -19375 -70107 28157 1682 28807 13331 -3889 59340 -6948 -20281 -1023 -10760 -67392 -3999 49365 10176 71276 30276 SS 20230822T111323.0Z 8634.467627 66 1 30.15 2 83.22 80.17 143.76 44.94 0.00 1 0.00 1 0 25 6.297e-01 4.902e-02 2.510e-01 1.243e-02 7.873384e-01 6.701461e-03 8.900086e-03 -6.000000e+00 3.645351e-01 231.28 -2.00 3.57 -2.00 321.73 0.00e+00 -3.907006e-04 2.834498e-03 2.703461e-03 -6.000000e+00 1.654244e-02 286.90 -2.00 20.00 -2.00 321.09 0.00e+00 7.722 0.009 302.00 328.00 3 1.4080e+00 2.2780e-02 8.7313e-02 -6.0000e+00 9.1398e-01 1.3064e+00 2.7567e-02 4.4362e-02 -6.0000e+00 9.9442e-01 -1.6444e+00 1.7458e-02 2.0862e-02 -6.0000e+00 5.8886e-01 6.2819e-01 8.9606e-03 5.8024e-03 -6.0000e+00 2.4703e-01 2.9378e-05 -7.0575e-05 3.3903e-04 7.5037e-05 -6.0000e+00 1.7154e-02 1.0615e-02 6.9114e-05 12 9 8 11 32 0 88.53 27.99 1.24 0.01061 0.01008 74 74 1 5 0 407.420 36.25 20.00 27.99 23.43 3.6 941.99 194523 -39388 900000 -7456 67378 -42332 29974 13349 -37862 -70939 17589 7671 76473 208837 94457 14406 52676 107212 89837 77155 88422 -23761 71337 900000 10808 209865 -36663 24045 -22299 -45179 -49343 198555 23619 900000 173026 -32828 -23188 220934 78096 900000 80895 45058 54165 87930 -6432 -11055 53231 136658 27307 343892 -4971 17775 19361 68434 55601 17295 46515 43166 14295 -20826 19083 58489 634 29530 54573 42717 -13063 35621 30024 24908 11787 11176 3321 19138 4787 -44274 5843 16179 15062 33733 -5817 -10115 9675 -4866 12562 13537 6605 -4961 5117 9710 -855 -6315 2474 -9792 -8858 5408 -10178 -4102 -4712 -4637 -5210 206 8829 85 -5397 2339 3864 -11074 1375 -1864 -7874 4153 -3660 3432 -1249 -6504 4313 2695 995 2020 8534 384 793 3694 160 1719 -1681 5939 123 3297 1324 218 -921 813 59 1330 242 -2291 -865 4337 -4610 -317 -1315 2571 -5336 900000 -542 1929 -3403 1188 647 -3086 -7735 775 414 2443 2530 3329 1206 3075 3661 3562 3314 3116 -2408 2828 900000 809 2543 -3917 1245 -1744 -4827 -6358 2646 1946 900000 2725 -3977 -2781 2677 4636 900000 5488 4422 4790 5326 -966 -1701 4256 4801 2944 4166 -867 2670 3049 6964 6601 3059 6086 5543 2286 -4542 2867 6519 142 5438 7868 6676 -3577 6301 6329 6246 3584 3439 1050 4707 1200 -16145 1239 3273 3595 7969 -2375 -4889 4138 -2541 5874 6609 3585 -3059 2802 4799 -436 -3229 1151 -5576 -5795 3603 -9260 -4031 -4978 -4792 -4999 167 6086 66 -4806 2032 3529 -12799 1577 -2299 -11543 5717 -5482 4654 -1696 -9104 5576 3749 1495 3079 11871 555 1105 5330 232 2376 -2369 8455 195 5791 2625 470 -2133 1986 157 3333 623 -6147 -2259 11083 -12003 -740 -3028 SS 20230822T112348.2Z 8634.474863 69 1 29.92 2 81.36 81.94 142.48 48.36 0.00 1 0.00 1 0 17 4.417e-01 1.922e-02 9.177e-02 3.363e-03 6.967917e-01 1.774944e-03 8.008235e-03 -6.000000e+00 2.524858e-01 231.28 -2.00 3.57 -2.00 321.11 0.00e+00 2.856611e-03 8.262053e-04 2.170834e-03 -6.000000e+00 1.142079e-02 286.90 -2.00 20.00 -2.00 320.47 0.00e+00 6.277 0.005 302.00 328.00 3 1.2902e+00 5.9872e-03 7.2436e-02 -6.0000e+00 6.3187e-01 3.4074e-01 7.8626e-03 3.9291e-02 -6.0000e+00 6.8506e-01 -5.4675e-01 6.9591e-03 2.0021e-02 -6.0000e+00 4.0811e-01 2.2858e-01 3.3341e-03 5.9951e-03 -6.0000e+00 1.7308e-01 1.6533e-04 -5.4190e-04 8.9779e-05 8.3771e-05 -6.0000e+00 1.1818e-02 1.0092e-02 7.8550e-05 12 9 8 11 32 0 32.33 27.98 0.89 0.01009 0.00602 75 75 1 5 0 398.890 36.25 20.00 27.98 24.06 3.6 945.09 -69772 -189962 900000 -140437 -52219 -148154 -68913 -139652 -154080 -170884 -123718 -114981 -30469 -38252 -8493 -68329 -33914 4966 -12243 -25774 97520 -57090 -28075 142095 -41794 55459 -58476 -1986 -47576 -42471 -43329 36194 19297 44734 5741 -18513 -8136 58545 6762 42872 27613 11236 17954 21001 -896 7463 23160 26915 11566 32675 8771 4963 9974 376 15883 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