File name: Pandora243s1_Downsview_20230917_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T060021.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230917_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230917T142624.7Z 8660.601674 170 1 19.52 2 55.47 126.50 81.14 111.98 0.00 1 0.00 1 0 17 3.523e-02 1.426e-02 1.365e-02 5.357e-03 2.297672e-01 2.677761e-03 2.855445e-03 -6.000000e+00 1.994066e-02 228.81 -2.00 3.57 -2.00 316.86 0.00e+00 3.575165e-04 3.478681e-04 4.762294e-05 -6.000000e+00 8.884021e-04 284.61 -2.00 20.00 -2.00 316.08 0.00e+00 1.759 0.000 302.00 328.00 3 6.2496e+00 7.0369e-03 2.1120e-02 -6.0000e+00 4.9643e-02 3.0934e-02 7.9026e-03 1.2207e-02 -6.0000e+00 5.3958e-02 1.5001e-03 4.6434e-03 5.9613e-03 -6.0000e+00 3.2144e-02 -2.0517e-03 2.2317e-03 1.6583e-03 -6.0000e+00 1.3622e-02 1.3960e-04 -6.9076e-04 1.5221e-04 1.9285e-05 -6.0000e+00 9.3644e-04 9.1911e-03 -1.0690e-04 12 9 9 12 33 33 99.98 28.74 0.19 0.00919 0.00400 4 8 1 5 0 3903.320 36.75 20.00 28.74 28.75 3.5 977.95 -1029 -3087 8534 -6229 15429 457 -7705 -10904 6754 -92 -10717 36 -2010 7754 -993 7244 3076 2402 -3875 412 -7200 815 -2330 -3180 -3908 15935 7422 -4997 -476 -4318 -3053 7604 1959 -610 7923 1365 -6252 2354 -1528 -237 -1182 -1772 2480 -867 -3653 2357 721 3654 -2436 -2576 5 2669 687 889 1460 -1082 -132 2941 2290 -856 -1549 2096 1426 2019 -1167 1058 -1780 3125 151 97 -1966 2324 -261 938 -3030 -3337 -1520 -1012 -2553 -1057 -2933 -2703 -1305 -430 -1621 3644 -582 -77 1289 1093 513 -1063 169 -1197 2061 -188 -389 1382 456 487 -1247 28 516 1409 -353 -433 -302 891 277 153 -62 1230 -405 844 458 -1027 941 -1312 510 -53 -293 -955 17 -259 421 429 -1775 412 920 963 -259 -270 -748 -101 460 -922 -178 -683 452 789 -735 425 593 -158 -508 1222 -921 1660 58 -1155 -1903 1073 -16 -1999 6 -416 1657 -259 1851 841 685 -1217 128 -2407 250 -767 -1115 -1441 4928 2416 -1697 -146 -1390 -1037 2495 728 -226 2504 473 -2636 981 -792 -137 -735 -1146 1570 -567 -2448 1475 445 2128 -1475 -1592 3 1773 490 661 1100 -852 -104 2218 1705 -662 -1263 1633 1208 1774 -1015 817 -1443 2397 120 87 -1941 2258 -257 869 -2681 -2883 -1174 -754 -2080 -879 -2768 -2781 -1393 -478 -1814 4130 -722 -97 1592 1283 601 -1149 166 -1176 2105 -217 -460 1769 610 629 -1522 33 595 1710 -437 -563 -409 1246 410 224 -95 1846 -633 1199 597 -1290 1171 -1757 723 -80 -452 -1456 25 -363 556 538 -2349 543 1192 1326 -377 -402 -1135 -159 710 -1508 -295 -1166 764 1290 -1179 650 959 SS 20230917T143547.7Z 8660.608191 176 1 29.62 2 54.13 128.86 79.64 113.70 0.00 1 0.00 1 0 17 2.984e-02 1.216e-02 6.718e-03 2.951e-03 2.269877e-01 1.477601e-03 2.773496e-03 -6.000000e+00 1.688928e-02 228.81 -2.00 3.57 -2.00 316.60 0.00e+00 -2.245937e-04 1.806928e-04 7.106805e-05 -6.000000e+00 7.523233e-04 284.61 -2.00 20.00 -2.00 315.84 0.00e+00 1.702 0.000 302.00 328.00 3 5.9122e+00 3.8632e-03 2.0509e-02 -6.0000e+00 4.2047e-02 2.9409e-02 4.3398e-03 1.1907e-02 -6.0000e+00 4.5698e-02 -5.8610e-03 2.5303e-03 5.8190e-03 -6.0000e+00 2.7223e-02 1.2990e-03 1.1913e-03 1.6265e-03 -6.0000e+00 1.1539e-02 2.0875e-04 -3.3356e-04 8.2927e-05 1.8424e-05 -6.0000e+00 7.9296e-04 8.8649e-03 -6.4820e-05 12 9 8 11 32 0 99.97 28.75 0.01 0.00886 0.00636 9 9 1 5 0 3290.780 36.75 20.00 28.75 29.36 3.5 983.03 -3281 -3604 8469 -9423 11934 866 -1671 -9156 9823 -1169 -2300 -15707 -539 1857 1346 4283 519 544 1606 3473 -3912 2977 -459 252 -616 4962 -4482 -6918 1505 -877 -532 6420 1876 -1904 3206 -6672 -3801 3230 -1796 1993 -236 373 1228 -1084 1014 411 457 3810 -1534 -430 -3005 1241 68 558 1929 -165 1017 2538 2188 -263 -406 1644 1215 726 -1371 856 -3813 1458 -357 607 -787 2091 -311 2218 -1833 -2778 -2394 -1120 -2310 -1700 -2078 -2842 -1574 -749 -671 1868 691 194 1624 67 56 -695 74 -1229 1085 49 -204 1695 204 268 -906 -692 -247 307 -348 -921 -891 79 80 1044 -104 766 -254 575 522 -471 514 -452 295 210 91 -858 340 691 895 102 -733 505 1260 316 -32 438 -198 -166 245 -1036 -326 -1033 85 177 -130 159 110 -602 -694 1409 -1668 1542 126 -275 -1831 1767 -237 -460 -3819 -127 485 395 1174 151 164 495 1083 -1311 926 -154 89 -229 1783 -1708 -2483 513 -309 -181 2187 715 -733 1196 -2564 -1602 1506 -1053 1169 -150 244 812 -731 667 269 290 2474 -942 -266 -2033 855 50 425 1479 -132 812 1965 1667 -207 -334 1431 1058 662 -1222 733 -3202 1155 -316 556 -785 2082 -313 2074 -1638 -2422 -1892 -847 -1903 -1571 -1982 -2984 -1716 -791 -762 2210 867 250 2049 82 62 -762 74 -1229 1139 58 -247 2211 280 354 -1126 -790 -292 356 -442 -1229 -1243 106 113 1554 -163 1186 -377 780 694 -601 656 -613 400 303 134 -1247 475 981 1202 131 -905 627 1662 447 -44 614 -284 -249 388 -1630 -521 -1703 139 280 -212 251 170 SS 20230917T144042.8Z 8660.611606 179 1 1.96 2 53.45 130.12 78.87 114.61 0.00 1 0.00 1 0 17 1.085e-02 6.625e-03 7.145e-03 4.236e-03 2.206843e-01 2.143004e-03 2.715911e-03 -6.000000e+00 6.143864e-03 228.81 -2.00 3.57 -2.00 315.65 0.00e+00 4.617132e-04 2.100530e-04 2.989491e-05 -6.000000e+00 2.736058e-04 284.61 -2.00 20.00 -2.00 314.96 0.00e+00 1.675 0.000 302.00 328.00 3 3.9328e+00 5.5421e-03 2.0082e-02 -6.0000e+00 1.5295e-02 -5.5514e-04 6.1817e-03 1.1555e-02 -6.0000e+00 1.6621e-02 2.9262e-03 3.5419e-03 5.6439e-03 -6.0000e+00 9.9019e-03 -2.9477e-03 1.6002e-03 1.5953e-03 -6.0000e+00 4.1983e-03 1.5814e-03 7.3572e-05 1.1771e-04 1.9161e-05 -6.0000e+00 2.8833e-04 8.2926e-03 1.2098e-05 12 9 1 12 33 1 999.00 28.76 0.37 0.00829 0.00885 2 46 1 5 0 650.750 36.75 20.00 28.76 29.79 3.5 985.48 -2155 -205 780 -2671 -4927 -4918 1107 2131 2734 -1307 -2592 -1317 484 -437 112 529 828 233 594 2481 231 -239 1133 44 -275 66 1191 -1041 -144 321 340 963 1803 374 -358 -3503 -1668 304 -487 255 -378 -661 -807 -690 -119 127 -820 239 -428 597 -251 143 1152 89 1289 923 156 372 -578 215 698 1349 1479 1090 -961 -1216 -347 141 1683 495 150 848 724 386 -244 -183 -1363 -836 -572 -1097 -775 -753 -1911 -1089 -640 -727 116 274 1088 692 300 -469 -194 -255 423 -43 390 583 98 -287 -739 -1012 -507 -540 -377 -496 -401 -131 -453 395 195 248 376 401 618 -429 -54 -139 163 123 -363 -335 465 344 517 832 947 1003 92 516 -152 685 248 -206 -194 -236 301 -369 -220 -59 -648 -453 -183 -594 -54 214 -676 -1152 -1156 269 577 798 -369 -725 -387 158 -152 43 217 346 95 249 1053 100 -104 502 21 -136 33 574 -473 -61 137 155 468 928 190 -170 -1762 -871 173 -317 176 -280 -482 -602 -513 -88 98 -617 173 -304 427 -193 111 927 72 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