File name: Pandora243s1_Downsview_20230923_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T053512.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230923_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230923T120258.1Z 8666.502061 76 1 30.52 2 80.61 99.25 164.44 10.17 0.00 1 0.00 1 0 17 4.374e-01 3.012e-02 2.186e-01 6.784e-03 6.668049e-01 3.644327e-03 8.161392e-03 -6.000000e+00 2.502951e-01 228.10 -2.00 3.57 -2.00 321.14 0.00e+00 2.796499e-03 1.679947e-03 4.845652e-03 -6.000000e+00 1.228832e-02 283.87 -2.00 20.00 -2.00 320.54 0.00e+00 5.828 0.004 302.00 328.00 3 2.7868e+00 1.2107e-02 7.0577e-02 -6.0000e+00 6.2153e-01 4.6124e-01 1.5909e-02 4.6733e-02 -6.0000e+00 6.7788e-01 -7.1027e-01 1.3955e-02 2.3774e-02 -6.0000e+00 4.0213e-01 3.0754e-01 6.6747e-03 6.3598e-03 -6.0000e+00 1.7128e-01 5.5753e-05 -1.3053e-04 1.8949e-04 1.1254e-04 -6.0000e+00 1.1808e-02 9.8918e-03 5.6534e-05 12 9 9 12 33 1 98.00 28.46 0.88 0.00989 0.00891 18 19 1 5 0 1605.920 36.50 19.99 28.46 21.31 3.6 925.74 -36229 900000 900000 133945 900000 4595 -85393 -115662 83409 64414 -88391 -171514 -55164 -9202 -64329 110413 -68294 198894 46065 900000 -54937 900000 56984 18337 29817 900000 -53540 443 30542 70296 45659 56019 59135 38539 900000 -42714 -24742 165292 40072 67646 23864 50939 -4713 15630 40916 71474 48159 110271 14988 21268 1863 17603 5919 579 23547 13149 18947 18080 26576 -4914 1168 13564 7870 14885 3542 7644 -9354 19767 8643 11445 391 21066 -3868 16593 -6328 1855 -6977 2604 -4407 -1328 -8273 -5966 -640 -2740 -408 -445 -899 -3969 3262 -3612 401 -2699 7287 -2921 -466 -1287 -6412 405 -2506 -1483 -3089 -2403 3123 318 -1845 -2549 -427 234 -506 70 -2117 1616 -2992 1740 2185 -2377 358 1292 2902 732 1360 285 1697 -305 3448 142 -1165 1951 260 1423 803 1269 -95 1102 917 -1472 392 -1584 -1271 864 -172 184 -1829 -653 900000 900000 885 900000 44 -2154 -4307 551 426 -2761 -14319 -1789 -232 -3361 1127 -4471 1314 1157 900000 -3366 900000 1280 642 965 900000 -3891 18 888 1533 1508 1925 2188 1731 900000 -4064 -2207 2621 2674 3933 2318 3938 -651 1755 3568 4628 3977 5027 1842 2642 313 2768 1130 125 4185 2667 3655 3416 4425 -1107 260 2975 2075 4032 1086 2167 -3140 5198 2872 4219 173 7724 -1756 5690 -2450 594 -2337 831 -1747 -607 -4278 -3411 -374 -1731 -270 -313 -663 -3073 2322 -2614 259 -1694 4458 -1916 -341 -1107 -6732 453 -2815 -1611 -3440 -2383 2735 298 -1912 -2800 -488 287 -636 98 -3361 2581 -4972 2647 3130 -3459 519 1959 4603 1223 2214 451 2563 -453 4748 195 -1582 2755 426 2386 1480 2470 -198 2403 1993 -3417 908 -3801 -3005 1900 -386 386 -3832 SS 20230923T121201.4Z 8666.508349 82 1 30.11 2 79.00 100.87 164.07 16.99 0.00 1 0.00 1 0 25 3.899e-01 2.055e-02 1.349e-01 4.291e-03 6.003104e-01 2.219728e-03 7.239442e-03 -6.000000e+00 2.201632e-01 228.09 -2.00 3.57 -2.00 320.61 0.00e+00 5.180116e-04 8.811054e-04 3.231231e-03 -6.000000e+00 9.951116e-03 283.87 -2.00 20.00 -2.00 319.95 0.00e+00 5.051 0.002 302.00 328.00 3 2.9349e+00 6.9263e-03 6.0650e-02 -6.0000e+00 5.4732e-01 2.1485e-01 8.7774e-03 3.8537e-02 -6.0000e+00 5.9521e-01 -3.3774e-01 7.5974e-03 1.7617e-02 -6.0000e+00 3.5488e-01 1.4249e-01 3.7581e-03 4.5522e-03 -6.0000e+00 1.5108e-01 1.0934e-04 -7.5648e-04 1.1856e-04 6.4384e-05 -6.0000e+00 1.0426e-02 1.0979e-02 3.1448e-05 12 9 8 11 32 0 95.94 28.46 0.83 0.01098 0.00529 31 31 1 5 0 970.980 36.50 20.00 28.46 21.85 3.6 929.91 -83878 -69052 900000 -94558 118031 -26474 -79491 -144074 -34473 -27950 -128516 -145578 -45610 -8780 -63163 363 -54325 54474 12907 25448 -38688 26312 6703 38513 19069 219171 -40133 -52931 -20506 -49011 -8601 143137 12055 14213 61083 -29684 -19331 33652 11713 12400 18038 15269 4285 9473 -10405 19715 10715 26254 4430 13640 18088 8386 -138 486 7688 4902 9552 11320 11010 -1393 1055 3846 502 7508 2577 3278 4445 9123 5264 4816 -493 9051 -1389 4553 -4705 -580 -3629 -1391 -4022 -20 -4676 -3918 -1386 -4171 1095 -309 -3621 -1015 1729 -2210 174 -2005 3782 -2252 -1127 -471 -2584 -112 -1152 -1329 -809 -1762 48 -7 -1483 -1647 -31 -465 194 543 -228 1182 -468 1362 954 -1 220 -178 1014 551 809 -368 756 738 2599 312 -371 382 846 884 548 89 116 610 491 -1112 90 -809 -191 -641 -1553 643 -26 -1595 -1234 900000 -1978 494 -288 -1482 -5809 -563 -444 -5807 -8250 -1298 -213 -3171 11 -3068 1117 421 756 -2169 771 255 1160 742 1192 -2855 -4031 -1115 -3917 -540 2276 797 922 2326 -2881 -1925 2379 1259 1541 2309 2115 683 1439 -1937 2747 1650 3548 773 2334 3300 1856 -36 136 2091 1421 2690 3069 2893 -411 319 1258 175 2673 972 1176 1564 3196 2165 2277 -266 4541 -752 2170 -2222 -236 -1447 -561 -1905 -11 -3043 -2855 -1061 -3186 853 -259 -3287 -916 1503 -1898 135 -1629 2811 -1868 -959 -459 -2963 -131 -1446 -1632 -915 -1962 49 -8 -1740 -1879 -36 -596 271 784 -363 1927 -764 2085 1380 -1 339 -270 1618 915 1320 -586 1155 1169 3876 458 -533 577 1334 1553 979 168 229 1275 1032 -2483 203 -1869 -435 -1399 -3223 1316 -53 SS 20230923T121717.1Z 8666.512003 85 1 29.74 2 78.07 101.82 163.78 20.80 0.00 1 0.00 1 0 17 2.619e-01 1.276e-02 4.250e-02 2.595e-03 5.653688e-01 1.328887e-03 6.664942e-03 -6.000000e+00 1.478862e-01 228.09 -2.00 3.57 -2.00 320.13 0.00e+00 1.218085e-03 4.583090e-04 1.572328e-03 -6.000000e+00 6.683951e-03 283.87 -2.00 20.00 -2.00 319.45 0.00e+00 4.687 0.002 302.00 328.00 3 2.5529e+00 3.9383e-03 5.4972e-02 -6.0000e+00 3.6764e-01 9.2181e-02 4.8467e-03 3.1113e-02 -6.0000e+00 3.9980e-01 -1.5692e-01 4.1675e-03 1.5442e-02 -6.0000e+00 2.3837e-01 6.4173e-02 2.1243e-03 4.3234e-03 -6.0000e+00 1.0149e-01 2.3570e-04 -3.1181e-04 7.1339e-05 5.4088e-05 -6.0000e+00 7.0024e-03 1.0631e-02 3.4917e-05 12 9 8 11 32 0 99.09 28.46 0.51 0.01063 0.00829 42 42 1 5 0 708.040 36.50 20.00 28.46 22.14 3.6 931.71 -72534 -100251 900000 -85003 -65060 -89257 -70021 -101960 -29729 -66713 -82165 -115826 -45547 -15849 -43951 -3084 -39461 3237 -5529 21845 -28747 15253 -10742 6218 -7054 53476 -29321 -35068 -17142 -25376 -6942 35096 -88 2456 26368 -20330 -13423 17517 4732 9365 4996 8165 135 3480 4998 7709 3756 11162 -830 4236 -1794 2221 -1098 -1052 3584 3059 2824 2134 2977 14 439 3763 3575 3434 777 1155 1141 5152 2592 2897 107 3817 -1571 1395 -2041 -1419 -1561 -311 -1361 -1101 -3007 -2857 -2210 -2321 -858 -33 -1651 -445 985 -315 825 -303 -1008 -559 -191 266 -1678 619 -182 -486 -752 -1393 213 -390 -861 -934 -485 41 437 364 -7 1007 -163 716 226 76 -57 95 695 303 235 -112 464 391 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