File name: Pandora243s1_Downsview_20230924_L2Fit_fout2c6d20230307p1-8.txt File generation date: 20241101T234840.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c6p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt Level 1 file used: Pandora243s1_Downsview_20230924_L1_smca1c6d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20230924 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: AnaFld for Downsview First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230924T113935.8Z 8667.485830 57 1 30.11 2 84.99 95.47 158.29 315.22 0.00 1 0.00 1 0 25 7.687e-01 1.425e-01 2.721e-01 3.858e-02 9.501408e-01 2.176848e-02 1.205770e-02 -6.000000e+00 4.433635e-01 227.98 -2.00 3.57 -2.00 320.22 0.00e+00 -2.608089e-02 3.985224e-03 2.298117e-03 -6.000000e+00 2.119134e-02 283.75 -2.00 20.00 -2.00 319.10 0.00e+00 9.805 0.018 302.00 328.00 3 4.1509e-01 5.9676e-02 1.1451e-01 -6.0000e+00 1.1028e+00 2.7120e+00 6.9784e-02 7.7406e-02 -6.0000e+00 1.2026e+00 -2.0315e+00 4.0470e-02 2.4145e-02 -6.0000e+00 7.1167e-01 5.1046e-01 1.9909e-02 2.0567e-02 -6.0000e+00 3.0173e-01 5.3616e-06 -3.3820e-03 9.8779e-04 1.9022e-04 -6.0000e+00 2.0804e-02 7.9317e-03 0.0000e+00 12 9 8 11 32 0 29.48 28.56 3.05 0.00793 -0.01748 15 15 1 5 0 2006.730 36.75 20.00 28.56 20.48 3.6 919.15 13927 42606 900000 231733 900000 76125 18088 -37781 83762 63382 -5274 160089 82103 77310 168986 161134 100011 190374 49844 900000 -38772 145477 56017 132416 52792 900000 15233 -62243 51941 900000 17955 900000 93334 85908 900000 -28843 175022 88114 91964 139023 55651 197239 -25526 27668 107311 211780 83172 900000 -15560 31607 -45335 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-36003 1201 10277 2721 7332 -10222 -17212 15438 11619 20575 23594 13765 4409 22262 1799 8001 -1092 3430 5975 16710 9794 -33136 23104 14402 1990 8237 4438 16591 17766 6866 9007 12490 11942 8100 18902 -16493 26206 -17770 23711 22312 -9502 1523 6211 13334 -1622 -6972 -26672 9818 -14452 14641 -28458 -29448 5460 -13428 4468 -1108 -6754 -12704 -1406 715 -11669 7191 -10493 -16564 36435 -4776 20035 18653 SS 20230924T114929.6Z 8667.492704 60 1 29.85 2 83.22 97.21 159.41 320.10 0.00 1 0.00 1 0 25 4.343e-01 3.150e-02 1.650e-01 7.221e-03 8.273551e-01 3.946996e-03 9.314007e-03 -6.000000e+00 2.476962e-01 227.98 -2.00 3.57 -2.00 321.82 0.00e+00 -5.540121e-03 2.113829e-03 1.391447e-03 -6.000000e+00 1.157758e-02 283.75 -2.00 20.00 -2.00 321.28 0.00e+00 7.729 0.009 302.00 328.00 3 1.1335e+00 1.4705e-02 8.7952e-02 -6.0000e+00 6.1697e-01 9.9543e-01 1.9415e-02 4.5847e-02 -6.0000e+00 6.7418e-01 -1.3630e+00 1.5694e-02 2.3963e-02 -6.0000e+00 3.9928e-01 5.4917e-01 7.2936e-03 8.1175e-03 -6.0000e+00 1.6822e-01 4.0854e-05 -1.9450e-03 1.9384e-04 1.1467e-04 -6.0000e+00 1.1691e-02 5.5362e-03 0.0000e+00 12 9 8 11 32 0 -1.12 28.57 0.99 0.00554 -0.00908 94 94 1 5 0 317.530 36.50 20.00 28.57 20.75 3.6 922.05 -37752 21236 900000 5003 12946 -93987 -65952 -68401 3640 -14133 -97722 -132764 29367 64059 -8963 28948 -24146 238053 73646 900000 -11699 48876 53729 46041 32713 900000 -33493 -35516 42250 -65336 -40039 900000 73565 65078 900000 -3149 -10922 87960 75799 95830 84425 93526 9109 74032 -21077 77791 40996 162259 21790 43817 -2654 27569 24077 2954 44220 48336 51252 44002 48049 22469 9706 20759 6805 39569 7075 12690 -12243 38979 30283 18247 8248 42054 650 17029 8645 -20888 2588 4841 3352 3530 -7654 -8845 3663 -6736 1744 2510 -8267 -1670 10363 -507 4898 -2216 10265 -252 2415 -1711 -9552 -659 -2664 -3444 -1523 -3440 -4205 -344 -4156 -2085 923 -1879 -561 -978 -2544 1933 -1555 839 -354 -1313 -718 141 1464 962 1474 1514 883 341 5702 304 34 -440 481 1589 723 659 2439 453 -374 -733 367 -676 -407 1591 -2608 -425 -1224 -1280 407 900000 90 182 -3727 -2109 -2450 68 -316 -5062 -10869 563 1024 -344 833 -1235 1675 1460 900000 -501 1094 1323 1328 1128 900000 -2097 -2024 1040 -5102 -2845 900000 2122 2014 900000 -173 -715 2537 2986 3573 3801 3948 891 3646 -2595 3503 2653 3196 1824 3175 -342 2890 2829 461 4791 5203 5409 4798 4699 2703 1352 2848 1221 5707 1448 2393 -2998 6060 5816 4519 2431 8994 202 4109 2013 -5819 546 1056 865 1093 -3112 -4176 1665 -3601 915 1383 -5275 -1013 5490 -284 2423 -1121 4571 -135 1465 -1275 -8199 -598 -2657 -3416 -1374 -2820 -3505 -283 -3495 -1812 830 -1895 -629 -1267 -3780 2937 -2482 1277 -523 -1907 -1061 218 2365 1467 2374 2323 1320 496 7622 416 46 -646 815 2797 1429 1405 5439 1022 -916 -1884 949 -1789 -1061 3840 -6091 -979 -2757 SS 20230924T115946.9Z 8667.499848 63 1 29.90 2 81.38 99.03 160.45 325.65 0.00 1 0.00 1 0 25 4.780e-01 1.648e-02 6.949e-02 2.459e-03 7.219331e-01 1.286874e-03 8.430443e-03 -6.000000e+00 2.697998e-01 227.97 -2.00 3.57 -2.00 320.98 0.00e+00 5.159077e-03 5.837932e-04 2.195310e-03 -6.000000e+00 1.201272e-02 283.75 -2.00 20.00 -2.00 320.38 0.00e+00 6.294 0.005 302.00 328.00 3 1.0561e+00 4.1973e-03 7.2751e-02 -6.0000e+00 6.7054e-01 3.2042e-01 5.5443e-03 3.9562e-02 -6.0000e+00 7.2933e-01 -4.5474e-01 5.1878e-03 2.1603e-02 -6.0000e+00 4.3456e-01 1.8783e-01 2.5062e-03 7.9870e-03 -6.0000e+00 1.8425e-01 1.9617e-04 -8.6949e-04 6.3709e-05 1.0261e-04 -6.0000e+00 1.2699e-02 4.8935e-03 0.0000e+00 12 9 8 11 32 0 -7.94 28.57 0.76 0.00489 -0.00164 113 113 1 5 0 264.560 36.75 20.00 28.57 21.48 3.6 926.77 -199693 -158200 -15172 -114034 -164095 -119412 -153302 -159237 -150857 -137886 -156333 -174040 -84050 -48167 -97936 -41027 -64781 12384 -8223 49559 -51121 -27769 -5558 2532 -10140 20396 -23184 -42631 -27226 -40868 -39009 63308 2610 1531 18289 -14557 -5615 16946 8564 24973 7115 21285 -3233 8949 -6072 12653 7588 20197 5718 8718 2221 10983 9204 5849 10955 10617 10646 10161 7606 5698 4728 7550 5841 8566 5449 6622 -594 4659 4737 4124 3101 6855 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