File name: Pandora243s1_Downsview_20231007_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T044716.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20231007_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231007T121016.2Z 8680.507133 293 1 30.10 2 82.36 105.24 17.67 185.04 0.00 1 0.00 1 0 25 5.851e-01 1.915e-02 1.535e-01 3.407e-03 7.902533e-01 1.823932e-03 9.068914e-03 -6.000000e+00 3.284725e-01 226.41 -2.00 3.57 -2.00 321.41 0.00e+00 5.411005e-03 9.396157e-04 2.456381e-03 -6.000000e+00 1.516565e-02 282.12 -2.00 20.00 -2.00 320.88 0.00e+00 6.986 0.007 302.00 328.00 3 5.6563e-01 6.3833e-03 8.0622e-02 -6.0000e+00 8.1360e-01 4.8294e-01 8.6701e-03 4.3805e-02 -6.0000e+00 8.8614e-01 -6.7211e-01 8.3855e-03 2.3954e-02 -6.0000e+00 5.2863e-01 2.7403e-01 3.9520e-03 8.9383e-03 -6.0000e+00 2.2628e-01 1.5630e-04 -9.0507e-04 8.8052e-05 1.2842e-04 -6.0000e+00 1.5969e-02 1.0052e-02 5.6601e-05 12 9 8 11 32 0 95.02 28.17 0.91 0.01005 0.00325 95 95 1 5 0 316.790 36.25 20.00 28.17 18.14 3.6 902.32 -227951 -166744 900000 900000 -108233 -140980 -129161 -122823 -136570 -159101 -165546 -185108 -104241 -69622 -79282 -75992 -34795 -32218 94884 91873 -77024 -62092 -64254 242754 -23819 153724 -63636 51367 -72378 -57627 -48405 114835 -5100 57840 25326 -40576 30741 116792 10201 42004 47334 63302 476 -1776 -2920 10350 15232 30372 18014 20849 5854 4197 22294 7338 23886 15613 18922 23951 15908 11882 -1937 15052 910 10493 10138 12942 38 11796 8425 11863 5982 11123 1580 5438 3040 -10803 -7523 2869 -4012 3419 -4244 -2212 389 -4039 -102 153 -331 -2152 542 -150 583 -712 -78 -4588 -1005 -2330 -1859 804 -1656 -468 -1113 -1742 -1670 -1213 -2382 -339 -136 -2166 -573 161 -391 218 -232 676 29 -627 -259 -313 392 495 918 783 1280 1466 2115 490 445 1041 688 891 325 230 923 155 127 -535 191 -488 -315 217 -977 -598 -624 -7365 -3222 900000 900000 -948 -1703 -1482 -1446 -1979 -2979 -3499 -5813 -2112 -1295 -2028 -2196 -740 -728 630 641 -2840 -1939 -2156 806 -593 664 -2367 580 -2885 -2316 -2203 1221 -205 1249 707 -2224 929 1785 549 1911 2233 2691 39 -152 -255 811 1174 2119 1514 1870 690 560 2718 1124 3245 2380 2822 3302 2277 1748 -345 2560 207 2440 2445 2983 10 2978 2505 3554 2050 3691 555 1862 953 -3502 -2289 843 -1356 1297 -2044 -1195 223 -2561 -67 106 -239 -1479 391 -103 372 -438 -47 -3162 -778 -1980 -1847 828 -1880 -517 -1142 -1732 -1524 -1134 -2431 -357 -153 -2492 -729 217 -592 349 -374 1051 44 -918 -387 -494 650 839 1506 1226 1929 2132 2952 673 648 1516 1168 1607 653 467 1969 336 296 -1311 472 -1232 -783 509 -2157 -1305 -1327 SS 20231007T121951.1Z 8680.513786 296 1 30.08 2 80.70 106.98 17.94 191.87 0.00 1 0.00 1 0 17 4.598e-01 1.215e-02 5.241e-02 1.714e-03 7.081453e-01 8.861932e-04 8.187749e-03 -6.000000e+00 2.580942e-01 226.40 -2.00 3.57 -2.00 320.73 0.00e+00 3.321301e-03 3.754573e-04 1.668464e-03 -6.000000e+00 1.147611e-02 282.12 -2.00 20.00 -2.00 320.14 0.00e+00 5.880 0.004 302.00 328.00 3 5.5077e-01 2.7783e-03 6.8576e-02 -6.0000e+00 6.3946e-01 1.7590e-01 3.6284e-03 3.8103e-02 -6.0000e+00 6.9643e-01 -2.5582e-01 3.5344e-03 2.0195e-02 -6.0000e+00 4.1508e-01 1.0329e-01 1.7407e-03 6.8819e-03 -6.0000e+00 1.7648e-01 4.9513e-04 -4.0027e-04 4.4117e-05 8.2938e-05 -6.0000e+00 1.2213e-02 9.4931e-03 6.5532e-05 12 8 8 10 0 0 38.20 28.17 0.61 0.00949 0.00649 172 172 1 5 0 174.860 36.25 20.00 28.17 18.49 3.6 905.60 -209295 -176877 -93023 -55110 -119714 -166919 -122536 -143280 -155345 -109094 -146632 -155309 -98341 -71503 -41825 -67103 -36287 -23252 -18831 18466 -48102 -64194 -53519 4403 -22951 20091 -41998 -13010 -39462 -37522 -30162 6970 -10874 -2924 -4697 -18498 -1257 15896 3509 8539 10024 10138 430 3583 2852 5792 2570 8259 189 4746 947 3376 8391 6779 7836 4635 4253 5987 3886 1398 -1233 4504 2289 5933 3098 2894 -181 3216 2834 3989 2186 2864 195 1092 -18 -4201 -3055 -686 -1838 483 -1910 -1430 -1673 -2571 -1495 -691 246 -377 766 837 447 26 -280 -1527 -662 -734 -500 335 -449 -135 -884 -1060 -1465 -1054 -1262 -924 -683 -778 -31 269 227 484 219 352 310 -357 75 0 -14 199 726 315 513 751 1105 326 306 828 730 544 337 177 194 -217 -7 -304 67 -177 -210 -41 -559 -252 -373 -4293 -3252 -762 -286 -1100 -2539 -1331 -2179 -2960 -1386 -2916 -4127 -1940 -1398 -762 -1851 -825 -513 -425 299 -1520 -2403 -1941 98 -717 426 -1650 -370 -1497 -1618 -1487 283 -605 -153 -237 -1110 -73 941 289 786 1004 1081 53 434 354 718 340 1084 29 752 177 686 1619 1444 1740 1106 1039 1410 904 332 -318 1240 742 2077 1145 1047 -68 1242 1148 1835 1108 1476 100 515 -8 -1697 -1283 -298 -865 266 -1163 -986 -1254 -1915 -1182 -575 212 -333 662 687 369 20 -217 -1282 -588 -713 -564 402 -580 -171 -1036 -1185 -1524 -1130 -1463 -1053 -826 -1018 -42 391 365 771 349 568 474 -533 114 0 -22 329 1165 512 805 1134 1602 487 446 1222 1171 937 639 341 395 -450 -15 -676 152 -407 -477 -89 -1186 -524 -761 SS 20231007T122848.6Z 8680.520007 302 1 29.99 2 79.16 108.61 18.36 198.04 0.00 1 0.00 1 0 25 2.977e-01 8.507e-03 2.262e-02 1.034e-03 6.312814e-01 5.259650e-04 7.329641e-03 -6.000000e+00 1.671160e-01 226.40 -2.00 3.57 -2.00 320.11 0.00e+00 2.004578e-03 1.831066e-04 7.146340e-04 -6.000000e+00 7.430955e-03 282.12 -2.00 20.00 -2.00 319.47 0.00e+00 5.120 0.003 302.00 328.00 3 4.2187e-01 1.5490e-03 5.9886e-02 -6.0000e+00 4.1405e-01 8.2037e-02 1.9103e-03 3.3242e-02 -6.0000e+00 4.5094e-01 -1.1921e-01 1.7313e-03 1.6886e-02 -6.0000e+00 2.6876e-01 4.5012e-02 8.8832e-04 5.4146e-03 -6.0000e+00 1.1427e-01 1.2365e-03 -2.6187e-04 2.7129e-05 5.8936e-05 -6.0000e+00 7.9082e-03 9.5643e-03 5.8765e-05 11 8 0 10 0 0 75.66 28.17 0.56 0.00956 0.00760 291 291 1 5 0 103.040 36.25 20.00 28.17 18.90 3.6 908.18 -132703 -124287 -64317 -62179 -99396 -99801 -87936 -84142 -94414 -88522 -88023 -91049 -57220 -40061 -32346 -28548 -27185 -16965 -10194 -3428 -28884 -26279 -21758 -5221 -7906 -2139 -22917 -11690 -24269 -14009 -12586 1993 -3673 -3946 -7831 -11952 -4477 4311 1115 3766 4120 3028 1438 851 2002 1300 835 3714 1041 3313 1220 2246 3351 2828 3843 2261 1857 1842 974 671 470 2394 2409 3365 1901 1259 -516 1223 1467 1304 1054 1363 182 302 -599 -1925 -2332 -1718 -1615 -833 -1327 -1457 -1490 -1962 -1097 -246 215 -81 440 576 468 120 -51 -716 -308 -263 -9 422 8 -289 -619 -862 -755 -942 -732 -619 -698 -547 -4 351 451 457 309 377 233 -292 53 -59 -102 -108 363 44 357 515 678 399 536 610 584 490 214 152 42 -95 -203 -174 12 -54 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