File name: Pandora243s1_Downsview_20231015_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T042018.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20231015_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231015T120459.5Z 8688.503467 58 1 30.09 2 85.07 106.79 94.12 103.78 0.00 1 0.00 1 0 17 8.252e-01 7.147e-02 2.875e-01 2.040e-02 9.908056e-01 1.157966e-02 1.177368e-02 -6.000000e+00 4.758322e-01 225.44 -2.00 3.57 -2.00 321.76 0.00e+00 -2.357756e-02 3.963644e-03 1.556582e-03 -6.000000e+00 2.312368e-02 281.12 -2.00 20.00 -2.00 321.13 0.00e+00 9.919 0.019 302.00 328.00 3 -3.3672e-01 3.7623e-02 1.1026e-01 -6.0000e+00 1.1797e+00 2.2907e+00 4.4248e-02 5.5450e-02 -6.0000e+00 1.2935e+00 -2.2429e+00 2.6164e-02 2.5648e-02 -6.0000e+00 7.6007e-01 7.0933e-01 1.4029e-02 1.7383e-02 -6.0000e+00 3.2388e-01 1.3844e-05 -1.1509e-03 5.2500e-04 2.9446e-04 -6.0000e+00 2.3804e-02 6.8892e-03 1.5509e-04 12 9 8 11 32 0 38.41 27.76 2.41 0.00689 -0.00176 30 30 1 5 0 1002.740 36.00 20.01 27.76 14.80 3.7 879.20 3216 37337 900000 900000 900000 104380 58608 900000 55298 48525 13321 248065 338243 40873 88104 212951 62424 387090 311536 900000 -8869 70482 78722 900000 8332 196455 544 109839 -65159 -85344 -39131 900000 3049 91097 900000 -40250 -23641 900000 181943 133911 900000 207723 13773 -8628 -29403 34901 200457 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-9612 -8800 7292 -2635 13649 14078 -1882 -4172 9628 3246 2136 5689 12708 -12918 7274 6048 -2288 7305 558 7591 2734 -11134 1651 4468 -2118 4817 8638 -8433 -2598 -1252 -5670 6956 -4762 9826 -1721 -19256 4093 -2031 934 10096 1182 -9735 3950 3312 11147 -494 -16050 2938 -3874 -3288 -3332 4699 12220 1897 1292 -13196 7794 -8198 6423 2754 -9922 644 9504 SS 20231015T121504.2Z 8688.510465 61 1 29.92 2 83.34 108.59 92.44 105.48 0.00 1 0.00 1 0 25 5.181e-01 2.442e-02 1.968e-01 4.851e-03 8.942772e-01 2.650743e-03 1.003140e-02 -6.000000e+00 2.924539e-01 225.44 -2.00 3.57 -2.00 321.81 0.00e+00 3.353638e-03 1.419070e-03 1.883869e-03 -6.000000e+00 1.429312e-02 281.11 -2.00 20.00 -2.00 321.32 0.00e+00 7.844 0.009 302.00 328.00 3 4.9479e-02 9.6147e-03 9.0598e-02 -6.0000e+00 7.2161e-01 1.0503e+00 1.2736e-02 4.9086e-02 -6.0000e+00 7.8816e-01 -1.4059e+00 1.1128e-02 2.5999e-02 -6.0000e+00 4.6821e-01 5.7155e-01 5.2468e-03 9.0683e-03 -6.0000e+00 2.0017e-01 9.7646e-05 -9.1022e-04 1.2165e-04 1.3266e-04 -6.0000e+00 1.4232e-02 7.4991e-03 9.3601e-05 12 8 8 10 0 0 10.19 27.77 0.89 0.00750 0.00066 132 132 1 5 0 226.620 36.00 20.00 27.77 15.20 3.7 882.66 -127970 -72955 900000 900000 900000 -68583 -53228 145631 -53249 -70606 -112529 -132014 1452 -49472 50070 48950 -7365 211882 85324 221138 12748 -32375 -18279 166272 -17807 900000 -35101 119826 -75085 -72927 -48399 900000 27493 92812 47311 -24523 1502 142818 31521 107678 120206 72756 27332 31241 37492 20399 33683 72771 15835 91343 939 39952 28760 20030 57478 29186 22357 26058 15079 23018 -513 15510 4412 30118 13753 14367 11414 15475 11186 20445 12422 21319 3641 11875 2547 -17802 -4400 2957 -6780 9119 -4659 -4261 2755 -4125 3594 2878 -1726 -1455 1949 -84 -302 770 2754 -6358 -2060 -3194 -3015 -611 -1963 -1114 -3234 -4148 242 -1914 -4569 -694 202 -2359 -2205 -778 -1327 137 -539 1127 -407 -2924 468 91 341 1847 776 1049 1962 2014 3424 1379 356 1089 193 909 388 1235 1076 360 239 -751 756 -906 23 59 -1441 -394 -1553 -7148 -2445 900000 900000 900000 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1.306215e-02 281.11 -2.00 20.00 -2.00 320.51 0.00e+00 6.427 0.005 302.00 328.00 3 3.8817e-01 6.2305e-03 7.5535e-02 -6.0000e+00 7.1619e-01 3.4975e-01 8.4387e-03 4.3195e-02 -6.0000e+00 7.8058e-01 -4.6390e-01 8.3740e-03 2.3936e-02 -6.0000e+00 4.6564e-01 1.8982e-01 4.0195e-03 8.5358e-03 -6.0000e+00 1.9901e-01 3.1428e-04 -5.8800e-04 9.1154e-05 1.1471e-04 -6.0000e+00 1.3827e-02 7.1154e-03 3.8164e-05 12 9 9 12 1 1 99.27 27.78 0.74 0.00712 0.00270 45 122 1 5 0 246.130 36.00 20.00 27.78 15.97 3.6 887.33 -260307 -183486 900000 -25347 1564 -189564 -184838 -119328 -137358 -129844 -187858 -197972 -73217 -112809 -28269 -62753 -62759 29485 38566 29530 -51715 -33811 -30339 -6189 -35664 77692 -48107 -34215 -69698 -70297 -51022 27962 -5014 6000 18581 -28747 -3574 19700 22849 23028 25145 16897 12111 6344 8311 14273 10595 23401 3803 18850 11397 13357 8568 8340 15127 8936 6367 11752 2961 4140 1062 7593 5390 6213 5577 4004 1690 3765 3173 5563 4083 5155 1501 353 -910 -649 -3462 -276 -3444 1757 -2997 -1794 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