File name: Pandora243s1_Downsview_20231019_L2Fit_fout2c2d20230307p1-8.txt File generation date: 20240224T025553.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 243 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora243_OF_v2d20230125.txt Instrument calibration file used: Pandora243s1_CF_v2d20230307.txt Level 1 file used: Pandora243s1_Downsview_20231019_L1_smca1c2d20230307p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20231019 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.1256 305.2662 305.4067 305.5472 305.6877 305.8282 305.9687 306.1092 306.2497 306.3901 306.5305 306.6710 306.8114 306.9518 307.0922 307.2326 307.3729 307.5133 307.6536 307.7940 307.9343 308.0746 308.2149 308.3552 308.4955 308.6358 308.7760 308.9163 309.0565 309.1967 309.3370 309.4772 309.6173 309.7575 309.8977 310.0379 310.1780 310.3181 310.4583 310.5984 310.7385 310.8786 311.0186 311.1587 311.2988 311.4388 311.5788 311.7189 311.8589 311.9989 312.1389 312.2788 312.4188 312.5588 312.6987 312.8386 312.9785 313.1185 313.2584 313.3982 313.5381 313.6780 313.8178 313.9577 314.0975 314.2373 314.3771 314.5169 314.6567 314.7965 314.9362 315.0760 315.2157 315.3555 315.4952 315.6349 315.7746 315.9143 316.0539 316.1936 316.3332 316.4729 316.6125 316.7521 316.8917 317.0313 317.1709 317.3104 317.4500 317.5895 317.7291 317.8686 318.0081 318.1476 318.2871 318.4266 318.5660 318.7055 318.8449 318.9844 319.1238 319.2632 319.4026 319.5420 319.6813 319.8207 319.9601 320.0994 320.2387 320.3780 320.5173 320.6566 320.7959 320.9352 321.0745 321.2137 321.3529 321.4922 321.6314 321.7706 321.9098 322.0489 322.1881 322.3273 322.4664 322.6055 322.7447 322.8838 323.0229 323.1620 323.3010 323.4401 323.5791 323.7182 323.8572 323.9962 324.1352 324.2742 324.4132 324.5522 324.6911 324.8301 324.9690 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231019T121015.6Z 8692.507124 63 1 30.10 2 85.07 108.89 138.12 84.65 0.00 1 0.00 1 0 46 9.543e-01 2.183e-01 3.225e-01 5.845e-02 8.405581e-01 3.392470e-02 8.822125e-03 -6.000000e+00 5.709691e-01 225.06 -2.00 3.57 -2.00 318.76 0.00e+00 -3.377110e-02 4.990824e-03 4.961014e-03 -6.000000e+00 2.751913e-02 280.60 -2.00 20.00 -2.00 317.54 0.00e+00 9.928 0.019 302.00 328.00 3 5.2333e-01 9.1280e-02 1.1676e-01 -6.0000e+00 1.4262e+00 2.8201e+00 1.0583e-01 9.6340e-02 -6.0000e+00 1.5750e+00 -1.7967e+00 5.8862e-02 1.8725e-02 -6.0000e+00 9.1528e-01 3.0439e-01 2.7761e-02 3.0264e-02 -6.0000e+00 3.8288e-01 4.3444e-06 1.0113e-02 1.6175e-03 2.6060e-04 -6.0000e+00 2.8952e-02 8.7770e-03 1.3761e-04 12 9 8 11 32 0 56.23 27.90 5.08 0.00878 0.08477 10 10 1 5 0 3009.260 36.00 20.00 27.90 17.22 3.6 896.40 26414 51455 186387 900000 249495 900000 227806 900000 197436 900000 101954 -20298 900000 40249 900000 900000 150614 900000 91766 202770 -30882 900000 99853 900000 106827 414941 -32236 50200 80639 -60555 -580 900000 53381 900000 900000 46544 900000 900000 194610 253483 900000 418335 56958 115917 27989 171441 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13018 17242 8826 16637 -6069 16320 860 20261 15559 900000 -13332 15778 1329 9961 -20414 -18959 -735 900000 -15964 -24826 22055 23077 27301 900000 7151 -6634 25275 19234 11771 16121 14488 -21398 26512 19779 -6923 14207 13443 22537 12 -26376 8212 11083 8988 10696 28642 -10259 22170 10631 -24450 16909 -12266 32958 2019 -6304 33233 -25442 22843 22452 -4317 -24718 21019 -372 22459 -27737 -69308 19930 -12959 -10828 20673 30772 28852 13943 9384 -44050 22452 -60651 -18916 40611 2110 37548 39264 SS 20231019T122013.8Z 8692.514048 66 1 29.90 2 83.38 110.68 136.42 86.46 0.00 1 0.00 1 0 25 5.852e-01 3.778e-02 2.224e-01 9.758e-03 8.426374e-01 5.394153e-03 9.596907e-03 -6.000000e+00 3.327021e-01 225.06 -2.00 3.57 -2.00 321.83 0.00e+00 -1.909327e-04 2.681528e-03 5.309206e-03 -6.000000e+00 1.710095e-02 280.60 -2.00 20.00 -2.00 321.31 0.00e+00 7.888 0.009 302.00 328.00 3 1.0886e+00 1.9344e-02 9.3289e-02 -6.0000e+00 8.2219e-01 1.2629e+00 2.4264e-02 5.8091e-02 -6.0000e+00 8.9963e-01 -1.6355e+00 1.8274e-02 2.7037e-02 -6.0000e+00 5.3565e-01 6.4456e-01 8.9107e-03 7.0331e-03 -6.0000e+00 2.2870e-01 3.3720e-05 -8.0915e-04 2.6167e-04 1.2510e-04 -6.0000e+00 1.6671e-02 8.7302e-03 1.0678e-04 12 9 8 11 32 0 -15.88 27.93 1.42 0.00873 0.00265 35 35 1 5 0 854.120 36.25 20.00 27.93 17.61 3.6 900.24 -20608 8658 900000 900000 900000 85197 -7415 127846 2789 900000 24979 -100435 51562 -37735 45863 900000 57481 900000 31814 169280 -13453 49022 105867 900000 11196 900000 -34364 23734 -75302 -73544 -42164 67381 28986 211221 80672 2832 99058 900000 108866 149911 98122 165052 11643 27988 25611 38949 77826 340288 18244 140036 93786 91001 31712 3788 121989 5950 29439 77489 13545 12981 40854 9581 -2849 45407 14259 8602 -729 28707 -4503 17894 10181 41288 -3043 18382 -244 5874 -15437 -14128 -3856 16005 -15165 -4220 4187 -2653 14679 14200 -718 -5100 4815 -1538 -875 4188 16623 -10034 2905 -833 -6400 -3239 -1700 -1375 -3938 -7847 -4322 1407 -6211 -2518 3519 -7833 888 -64 -3852 1148 -1457 3156 -710 -5216 3759 -581 212 3045 1574 532 2717 3697 7192 1747 -3891 1746 -693 -1389 1778 1862 1842 843 -298 -255 678 -240 -1333 -27 -3106 1002 -642 -1406 441 900000 900000 900000 1177 -263 1215 94 900000 647 -10235 1380 -2933 1782 900000 2234 900000 1594 2047 -929 1693 2103 900000 599 900000 -2612 992 -7349 -7749 -4206 2560 1762 2007 2529 188 2729 900000 3723 3845 4474 3920 1272 2499 2263 2960 3992 3233 1802 4390 5167 5619 3796 637 6490 1029 3999 6183 1904 1751 4269 1511 -579 6341 2777 1724 -162 5018 -1236 4454 2921 8747 -954 4226 -60 1200 -3754 -3610 -1044 4272 -6483 -1848 1829 -1310 6484 6637 -404 -3033 2548 -821 -431 1870 6553 -5624 1669 -588 -5102 -2890 -1609 -1276 -3466 -7007 -3408 1075 -5522 -2275 3195 -7921 931 -78 -5526 1675 -2213 4475 -1003 -7527 5087 -866 333 4736 2408 783 3780 4939 8993 2240 -5199 2404 -1144 -2654 3360 3796 4001 1987 -765 -682 1824 -610 -3369 -69 -7553 2174 -1372 SS 20231019T123035.5Z 8692.521244 69 1 30.15 2 81.64 112.57 134.65 88.28 0.00 1 0.00 1 0 17 5.259e-01 1.765e-02 1.721e-01 3.154e-03 7.476388e-01 1.654043e-03 8.561743e-03 -6.000000e+00 2.939896e-01 225.06 -2.00 3.57 -2.00 321.18 0.00e+00 3.690842e-03 7.880107e-04 2.270627e-03 -6.000000e+00 1.336232e-02 280.60 -2.00 20.00 -2.00 320.65 0.00e+00 6.468 0.005 302.00 328.00 3 9.8286e-01 5.4964e-03 7.4716e-02 -6.0000e+00 7.2623e-01 3.6668e-01 7.4814e-03 4.1098e-02 -6.0000e+00 7.9213e-01 -5.0030e-01 7.4409e-03 2.2709e-02 -6.0000e+00 4.7250e-01 1.9866e-01 3.5591e-03 8.1332e-03 -6.0000e+00 2.0183e-01 1.7601e-04 -4.5653e-04 8.2090e-05 1.0760e-04 -6.0000e+00 1.4046e-02 8.3792e-03 4.9093e-05 12 9 8 11 32 0 93.93 27.97 0.87 0.00838 0.00495 90 90 1 5 0 334.930 36.25 20.00 27.97 18.38 3.6 905.05 -224514 -186063 900000 243666 39870 -128112 -152662 -44300 -125244 -53730 -135035 -194174 -95074 -108082 -63615 33866 -23352 139118 -29865 34930 -47840 -17171 -36796 900000 -19101 154521 -62559 -28404 -82708 14931 -67441 13551 -8461 24894 34313 -9350 -747 66760 30296 45187 31623 33235 176 8978 13299 10183 19649 28123 6090 25197 -1391 16917 15960 4286 22841 6892 7855 11610 5956 6335 -3899 8131 2030 11621 2930 3897 -168 7613 3440 5012 3921 5550 -1091 3147 -1535 -11519 -7817 -2553 -2028 2115 -2952 -1792 -1614 -3155 1082 1851 -151 -1204 1265 -57 -981 77 2016 -3595 -231 -922 -1152 -557 252 -882 -1587 -2389 363 -176 -1988 -527 -910 -1732 -174 -376 -590 449 466 134 -110 -1127 1042 -222 212 755 742 464 1141 1179 1532 847 -413 890 464 538 257 602 197 115 122 -380 92 -731 -170 484 -928 -99 -708 -6651 -4160 900000 749 123 -1361 -2261 -272 -1715 -413 -2491 -7164 -1871 -3124 -1467 344 -467 599 -735 462 -1427 -375 -1041 900000 -517 760 -2654 -821 -4196 331 -4188 446 -395 842 992 -428 -36 1950 1555 2334 2051 2248 17 811 1165 942 1704 2352 674 2525 -206 2320 2419 791 3673 1348 1543 2142 1117 1171 -843 1757 538 3140 807 1041 -48 2109 1131 1860 1588 2257 -457 1168 -535 -3995 -2526 -833 -773 930 -1600 -1095 -979 -2060 725 1305 -114 -930 942 -41 -660 53 1348 -2512 -181 -852 -1152 -636 306 -1059 -1773 -2396 355 -178 -2041 -561 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