File name: Pandora243s1_Downsview_20231022_L2Fit_fout2c6d20230307p1-8.txt
File generation date: 20241112T031144.2Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c6p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 243
Spectrometer number: 1
Processing software version used: BlickP v1.8.60
Instrument operation file used: Pandora243_OF_v2d20230125.txt
Instrument calibration file used: Pandora243s1_CF_v6d20230307.txt
Level 1 file used: Pandora243s1_Downsview_20231022_L1_smca1c6d20230307p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20231022
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: AnaFld for Downsview
First and last pixel inside fitting window: 197 339
Nominal wavelengths inside fitting window [nm]: 305.1230 305.2636 305.4043 305.5449 305.6855 305.8261 305.9667 306.1073 306.2479 306.3884 306.5290 306.6695 306.8101 306.9506 307.0911 307.2316 307.3720 307.5125 307.6529 307.7934 307.9338 308.0742 308.2146 308.3550 308.4954 308.6358 308.7761 308.9164 309.0568 309.1971 309.3374 309.4777 309.6180 309.7582 309.8985 310.0387 310.1790 310.3192 310.4594 310.5996 310.7398 310.8800 311.0201 311.1603 311.3004 311.4405 311.5806 311.7207 311.8608 312.0009 312.1410 312.2810 312.4210 312.5611 312.7011 312.8411 312.9811 313.1211 313.2610 313.4010 313.5409 313.6809 313.8208 313.9607 314.1006 314.2405 314.3803 314.5202 314.6600 314.7999 314.9397 315.0795 315.2193 315.3591 315.4989 315.6386 315.7784 315.9181 316.0578 316.1976 316.3373 316.4769 316.6166 316.7563 316.8959 317.0356 317.1752 317.3148 317.4544 317.5940 317.7336 317.8732 318.0127 318.1523 318.2918 318.4313 318.5709 318.7104 318.8498 318.9893 319.1288 319.2682 319.4077 319.5471 319.6865 319.8259 319.9653 320.1047 320.2440 320.3834 320.5227 320.6621 320.8014 320.9407 321.0800 321.2193 321.3585 321.4978 321.6370 321.7763 321.9155 322.0547 322.1939 322.3331 322.4723 322.6114 322.7506 322.8897 323.0288 323.1679 323.3070 323.4461 323.5852 323.7243 323.8633 324.0024 324.1414 324.2804 324.4194 324.5584 324.6974 324.8364 324.9753
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20231022T130653.5Z 8695.546452 93 1 29.96 2 76.51 120.24 154.87 46.78 0.00 1 0.00 1 0 25 1.878e-01 6.642e-03 3.489e-02 1.447e-03 5.764036e-01 7.288496e-04 6.733575e-03 -6.000000e+00 1.047148e-01 224.78 -2.00 3.57 -2.00 319.96 0.00e+00 1.457947e-03 2.398275e-04 3.213782e-04 -6.000000e+00 4.649290e-03 280.22 -2.00 20.00 -2.00 319.34 0.00e+00 4.183 0.001 302.00 328.00 3 2.1778e+00 2.1107e-03 5.0650e-02 -6.0000e+00 2.5865e-01 6.6209e-02 2.5906e-03 3.0215e-02 -6.0000e+00 2.8215e-01 -6.4640e-02 2.3347e-03 1.5188e-02 -6.0000e+00 1.6819e-01 1.8854e-02 1.2086e-03 4.8464e-03 -6.0000e+00 7.1575e-02 5.2713e-04 -4.3927e-04 3.8816e-05 4.9448e-05 -6.0000e+00 4.9837e-03 4.3824e-03 0.0000e+00 11 8 0 10 0 0 99.99 27.58 0.50 0.00438 0.00108 346 346 1 5 0 86.580 36.00 19.99 27.58 12.37 3.7 860.53 -99748 -95896 -7214 -19724 -46064 -60956 -54737 -46703 -50842 -50040 -66408 -63234 -19014 -29159 -13347 -6902 -6051 5432 -12048 -4059 -9709 -11982 -14211 12309 -9855 1693 -11187 -1896 -20101 -20925 -15849 -2397 -1991 -560 -5941 -7636 -3681 6185 599 2155 -275 455 131 1139 -171 -212 1202 3957 400 2072 -841 1183 2772 1509 3258 1648 156 1391 759 1588 394 1893 2179 2102 858 588 193 874 292 968 503 951 185 252 -730 -2253 -1325 -1670 -1571 -507 -994 -1432 -1396 -2125 -509 -156 -114 -31 706 900 798 546 346 -35 -65 173 73 657 198 -199 -954 -675 -421 -440 -793 -566 -534 -571 12 328 158 355 240 455 -115 -289 244 -175 -230 -55 11 -48 87 492 406 290 284 655 337 361 309 217 93 -86 -69 -237 69 -179 -107 229 -305 -184 -372 -1816 -1881 -60 -173 -488 -774 -734 -666 -847 -876 -1443 -1571 -384 -819 -392 -219 -210 184 -519 -169 -432 -551 -720 525 -563 90 -674 -100 -1265 -1480 -1264 -195 -183 -51 -544 -736 -390 720 91 376 -54 94 26 247 -35 -44 248 901 89 490 -229 349 875 520 1155 617 60 524 279 577 153 808 962 1021 425 280 92 429 163 613 319 615 117 162 -429 -1208 -667 -871 -934 -325 -738 -1202 -1168 -1895 -479 -155 -118 -30 734 886 728 466 308 -31 -63 181 88 834 266 -262 -1168 -790 -461 -501 -978 -685 -683 -782 16 510 252 586 389 699 -177 -427 366 -276 -366 -89 17 -75 139 748 593 407 410 940 516 612 537 398 178 -165 -142 -487 143 -379 -225 458 -608 -346 -687
SS 20231022T131539.0Z 8695.552535 96 1 3.24 2 75.16 121.96 153.73 50.26 0.00 1 0.00 1 0 25 1.102e-01 7.001e-03 1.571e-02 1.611e-03 5.290944e-01 7.993075e-04 6.287370e-03 -6.000000e+00 6.148131e-02 224.77 -2.00 3.57 -2.00 318.96 0.00e+00 1.426857e-03 1.886735e-04 2.863809e-04 -6.000000e+00 2.729473e-03 280.21 -2.00 20.00 -2.00 318.29 0.00e+00 3.826 0.001 302.00 328.00 3 7.8792e-01 2.1913e-03 4.6249e-02 -6.0000e+00 1.5186e-01 4.9040e-02 2.5362e-03 2.7316e-02 -6.0000e+00 1.6564e-01 -6.8053e-02 1.8869e-03 1.3621e-02 -6.0000e+00 9.8739e-02 2.6579e-02 1.0048e-03 4.1527e-03 -6.0000e+00 4.2031e-02 3.1336e-03 -2.5685e-04 4.2759e-05 4.2960e-05 -6.0000e+00 2.9251e-03 2.7222e-03 0.0000e+00 12 9 1 12 1 1 95.92 27.59 0.41 0.00272 0.00079 47 445 1 5 0 67.360 36.00 20.00 27.59 12.29 3.7 859.56 -55700 -36704 -23398 -37468 -41124 -45317 -32730 -28445 -24855 -29079 -36314 -27589 -18559 -14827 -6794 -1268 -2457 -1047 -450 -262 -5369 -5199 -2066 -1410 -1932 -2199 -7040 -3361 -6165 -5339 -4114 1621 1671 -145 -3564 -3874 -2270 143 483 1847 1481 1102 869 623 2217 768 870 1223 806 1398 433 2176 1920 1477 1827 693 1482 951 585 806 740 1085 1802 1669 1126 825 -71 -199 629 352 656 50 153 -178 -394 -959 -1797 -1130 -855 -820 -1025 -1724 -1562 -1771 -1380 -636 -103 288 307 707 429 524 -189 -303 154 -237 228 364 52 -361 -651 -763 -524 -494 -825 -800 -559 -512 68 380 419 506 393 255 90 98 142 116 -79 -116 153 295 270 516 611 321 348 830 584 585 235 117 5 -125 12 -146 -162 -39 -192 -282 -316 -363 -336 -1916 -1159 -662 -1124 -1182 -1395 -992 -947 -890 -1142 -1597 -1291 -988 -943 -482 -97 -208 -95 -43 -24 -516 -503 -207 -153 -225 -268 -893 -391 -730 -688 -613 263 305 -27 -652 -734 -442 33 135 549 483 382 291 211 748 267 305 437 298 550 178 967 926 720 927 368 796 505 303 416 403 615 1078 1092 743 519 -45 -129 430 262 526 39 123 -135 -286 -663 -1181 -754 -611 -653 -894 -1551 -1504 -1730 -1441 -673 -113 322 339 740 433 513 -179 -299 162 -265 279 466 71 -477 -827 -907 -606 -597 -1041 -1021 -725 -684 95 568 656 791 619 393 134 140 207 171 -121 -185 240 460 408 771 873 456 478 1194 881 946 387 202 9 -225 23 -277 -313 -74 -376 -529 -575 -644 -601
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