File name: Pandora284s1_Downsview_20250326_L2Fit_fout2c2d20241105p1-8.txt File generation date: 20250905T151619.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v1d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250326_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250326 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0011 305.1417 305.2823 305.4229 305.5635 305.7040 305.8446 305.9851 306.1256 306.2662 306.4067 306.5471 306.6876 306.8281 306.9686 307.1090 307.2494 307.3899 307.5303 307.6707 307.8111 307.9515 308.0918 308.2322 308.3725 308.5129 308.6532 308.7935 308.9338 309.0741 309.2144 309.3547 309.4949 309.6352 309.7754 309.9156 310.0559 310.1961 310.3363 310.4764 310.6166 310.7568 310.8969 311.0371 311.1772 311.3173 311.4574 311.5975 311.7376 311.8777 312.0177 312.1578 312.2978 312.4378 312.5779 312.7179 312.8579 312.9978 313.1378 313.2778 313.4177 313.5577 313.6976 313.8375 313.9774 314.1173 314.2572 314.3970 314.5369 314.6768 314.8166 314.9564 315.0962 315.2360 315.3758 315.5156 315.6554 315.7951 315.9349 316.0746 316.2143 316.3541 316.4938 316.6335 316.7731 316.9128 317.0525 317.1921 317.3317 317.4714 317.6110 317.7506 317.8902 318.0297 318.1693 318.3089 318.4484 318.5879 318.7275 318.8670 319.0065 319.1460 319.2854 319.4249 319.5644 319.7038 319.8432 319.9827 320.1221 320.2615 320.4009 320.5402 320.6796 320.8189 320.9583 321.0976 321.2369 321.3762 321.5155 321.6548 321.7941 321.9333 322.0726 322.2118 322.3511 322.4903 322.6295 322.7687 322.9079 323.0470 323.1862 323.3253 323.4645 323.6036 323.7427 323.8818 324.0209 324.1600 324.2990 324.4381 324.5771 324.7162 324.8552 324.9942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250326T131733.9Z 9216.553864 133 1 22.93 2 68.05 108.83 64.33 152.52 0.00 1 0.00 1 0 25 1.127e-01 5.884e-03 4.231e-02 2.376e-03 5.274802e-01 1.192848e-03 6.219700e-03 -6.000000e+00 6.313197e-02 226.60 -2.00 3.57 -2.00 319.56 0.00e+00 1.956279e-03 3.357703e-04 4.528036e-04 -6.000000e+00 2.716221e-03 275.11 -2.00 20.00 -2.00 319.01 0.00e+00 2.652 0.000 302.00 328.00 3 3.2383e+00 3.3429e-03 3.8095e-02 -6.0000e+00 1.5686e-01 3.4476e-02 3.9754e-03 2.7547e-02 -6.0000e+00 1.7094e-01 -1.7765e-02 3.4242e-03 1.4152e-02 -6.0000e+00 1.0143e-01 1.5145e-03 1.8086e-03 4.6307e-03 -6.0000e+00 4.2971e-02 7.6868e-04 -6.1783e-04 6.3707e-05 4.4581e-05 -6.0000e+00 2.9429e-03 -3.3223e-02 5.0253e-05 12 1 1 12 1 1 99.14 22.04 0.30 -0.03322 -0.03787 20 27 1 5 0 1091.670 29.50 14.99 22.04 5.01 2.3 891.18 900000 -44006 -34812 -30732 -30347 -16432 -48662 -53222 -41323 -12573 -35692 -37497 -30814 -15619 -8670 -13216 -6859 -8427 -7489 745 1845 -348 -5972 -4912 857 -1738 -5383 -8237 -10515 -9442 -5618 -6752 -2480 -2972 -3099 -3252 -5901 -4939 532 1761 -1827 132 220 734 -156 3618 -95 498 74 -520 1547 1578 1144 1874 1265 2889 325 950 673 265 129 849 1273 1665 2345 1287 91 463 -394 1044 982 788 445 442 599 -637 29 -1246 -1573 -827 -924 -1292 -1218 -1651 -1727 -1493 -516 -126 327 471 331 605 -71 179 -43 1 43 531 262 29 7 -417 -958 -275 -399 -887 -529 -879 -180 338 598 703 709 449 85 -237 -27 120 358 -145 -299 -135 564 202 190 4 -296 258 541 99 240 -71 27 -97 -197 -118 -235 45 202 -31 166 -70 -243 -295 900000 -724 -589 -520 -478 -206 -846 -1073 -852 -219 -827 -912 -800 -434 -281 -548 -308 -422 -404 40 102 -20 -361 -311 56 -125 -420 -660 -824 -718 -443 -629 -257 -352 -378 -374 -701 -654 80 322 -407 32 56 176 -38 953 -24 126 19 -140 430 484 390 686 500 1175 140 417 293 112 54 369 608 891 1258 710 53 259 -227 603 651 570 333 325 414 -406 18 -724 -922 -491 -644 -1041 -1017 -1491 -1642 -1514 -552 -131 346 493 357 601 -66 156 -39 1 48 633 329 40 9 -550 -1142 -302 -451 -1088 -680 -1191 -240 485 944 1128 1176 732 132 -367 -39 177 552 -223 -482 -216 865 320 290 7 -414 368 744 152 382 -123 49 -170 -365 -232 -460 89 408 -63 339 -135 -445 -526 SS 20250326T132343.5Z 9216.558143 137 1 29.88 2 67.00 110.05 63.82 154.02 0.00 1 0.00 1 0 25 9.502e-02 5.639e-03 3.787e-02 2.093e-03 5.069685e-01 1.053970e-03 5.969976e-03 -6.000000e+00 5.323657e-02 226.60 -2.00 3.57 -2.00 319.60 0.00e+00 1.582890e-03 2.981585e-04 3.540411e-04 -6.000000e+00 2.290558e-03 275.11 -2.00 20.00 -2.00 319.06 0.00e+00 2.539 0.000 302.00 328.00 3 3.2878e+00 2.9571e-03 3.6537e-02 -6.0000e+00 1.3227e-01 4.2739e-02 3.5069e-03 2.6459e-02 -6.0000e+00 1.4415e-01 -1.8072e-02 2.9924e-03 1.3498e-02 -6.0000e+00 8.5533e-02 5.5084e-04 1.5810e-03 4.2414e-03 -6.0000e+00 3.6235e-02 8.3075e-04 -7.4540e-04 5.7356e-05 4.2389e-05 -6.0000e+00 2.4817e-03 -3.3243e-02 4.3341e-05 11 1 0 11 8 0 99.98 22.05 0.52 -0.03324 -0.03884 116 116 1 5 0 257.590 29.50 14.99 22.05 5.09 2.3 892.12 900000 12118 -49505 -16352 -37433 -37607 -39558 -22026 -10346 -39700 -25661 -27411 -8917 -28252 -5444 -9954 -7927 -4279 -2497 -10828 -3318 -4197 -2728 -2911 -2332 -2002 165 -4426 -3798 -373 -3889 -1552 -167 -1273 -2132 -2530 -5512 -3293 -140 -1971 388 -1680 1094 -220 -635 2747 562 -1026 1347 -202 1908 1208 1570 1258 1067 1336 1449 -235 723 882 797 1008 1961 2797 1778 1125 889 -926 -794 448 614 862 329 -132 -94 -384 -783 -2168 -1394 -1134 -649 -1044 -1401 -1825 -1203 -1216 -419 338 564 325 992 296 67 39 -97 -201 -185 480 953 -56 -211 -341 -779 -255 -611 -1128 -643 -645 -237 313 614 528 570 643 398 -271 70 -193 148 -135 -238 -178 -101 499 158 223 -283 305 540 -48 226 6 -147 -284 -34 -132 -13 238 244 -111 -63 -256 -98 -101 900000 126 -1071 -264 -695 -637 -686 -355 -171 -989 -587 -655 -200 -951 -181 -421 -377 -214 -133 -667 -199 -258 -165 -186 -161 -148 13 -350 -284 -26 -304 -137 -17 -147 -255 -286 -645 -423 -21 -368 83 -405 271 -57 -169 712 151 -281 366 -57 557 391 558 440 401 523 586 -99 297 351 314 413 877 1391 980 633 475 -486 -424 262 411 626 249 -98 -66 -246 -451 -1172 -748 -674 -448 -831 -1152 -1621 -1118 -1208 -440 369 630 360 1044 290 60 33 -84 -194 -203 549 1222 -78 -288 -431 -888 -291 -720 -1334 -795 -838 -325 460 920 858 954 1054 619 -393 103 -289 214 -208 -385 -287 -157 744 245 329 -401 412 752 -74 359 11 -263 -526 -62 -256 -26 490 512 -232 -127 -488 -177 -189 SS 20250326T132814.3Z 9216.561277 140 1 29.25 2 66.23 110.95 63.46 155.14 0.00 1 0.00 1 0 17 1.760e-01 7.866e-03 2.247e-01 7.543e-03 4.922396e-01 3.851198e-03 5.780741e-03 -6.000000e+00 9.926887e-02 226.60 -2.00 3.57 -2.00 319.90 0.00e+00 1.110308e-03 1.176481e-03 2.743786e-04 -6.000000e+00 4.288432e-03 275.11 -2.00 20.00 -2.00 319.35 0.00e+00 2.463 0.000 302.00 328.00 3 5.0749e+00 1.1039e-02 3.5511e-02 -6.0000e+00 2.4648e-01 6.0757e-02 1.3238e-02 2.5784e-02 -6.0000e+00 2.6866e-01 -2.5627e-02 1.1714e-02 1.3160e-02 -6.0000e+00 1.5894e-01 4.4099e-03 6.1295e-03 4.1103e-03 -6.0000e+00 6.7162e-02 1.5081e-04 -2.8100e-04 2.1380e-04 4.3068e-05 -6.0000e+00 4.6055e-03 -3.3590e-02 1.3325e-04 12 9 1 12 1 1 99.97 22.05 0.65 -0.03359 -0.03570 8 9 1 5 0 3249.210 29.50 15.00 22.05 5.25 2.3 893.22 900000 34938 -50900 -79648 -31503 42141 900000 88213 -28797 60117 43164 67695 63849 -7407 -9445 41181 -4938 1549 -26064 20483 10236 2794 45885 -7838 12168 863 -3219 3697 8942 12313 -12137 -4553 -50 1707 -3582 -5875 -6875 1757 173 -1307 5599 -4133 -1323 -3775 -789 -190 -2436 2517 -786 -1819 1103 -154 1 -1850 -983 3201 2069 -1957 622 4322 -827 -626 4337 3485 1461 1527 2610 1095 341 2809 1071 -375 -509 657 -1334 1220 -1220 -1767 -3059 -2694 -914 411 -2720 -1842 -875 -1528 -310 18 441 159 -123 1199 1711 823 -331 -747 35 929 329 247 50 -189 -599 -655 -290 -268 -965 -93 -260 1153 18 586 369 608 314 -104 580 -913 -111 -830 33 75 -139 152 -33 -392 337 -41 -306 249 410 -320 -69 -148 -170 979 -46 -62 298 -462 -148 -352 -118 426 900000 257 -987 -2130 -484 310 900000 649 -501 482 433 597 657 -191 -306 969 -211 67 -1610 844 489 146 1552 -478 662 56 -230 245 533 688 -919 -368 -4 168 -382 -601 -713 187 23 -211 993 -888 -292 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