File name: Pandora284s1_Downsview_20250419_L2Fit_fwvt1c2d20241105p1-8.txt File generation date: 20250905T152027.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v1d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250419_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0083 492.1292 492.2500 492.3709 492.4917 492.6125 492.7332 492.8540 492.9747 493.0955 493.2162 493.3369 493.4575 493.5782 493.6988 493.8194 493.9401 494.0606 494.1812 494.3018 494.4223 494.5428 494.6633 494.7838 494.9043 495.0248 495.1452 495.2656 495.3860 495.5064 495.6268 495.7472 495.8675 495.9878 496.1081 496.2284 496.3487 496.4689 496.5892 496.7094 496.8296 496.9498 497.0700 497.1901 497.3102 497.4304 497.5505 497.6706 497.7906 497.9107 498.0307 498.1507 498.2707 498.3907 498.5107 498.6306 498.7506 498.8705 498.9904 499.1103 499.2301 499.3500 499.4698 499.5896 499.7094 499.8292 499.9490 500.0687 500.1885 500.3082 500.4279 500.5475 500.6672 500.7869 500.9065 501.0261 501.1457 501.2653 501.3848 501.5044 501.6239 501.7434 501.8629 501.9824 502.1018 502.2213 502.3407 502.4601 502.5795 502.6989 502.8182 502.9376 503.0569 503.1762 503.2955 503.4148 503.5340 503.6533 503.7725 503.8917 504.0109 504.1300 504.2492 504.3683 504.4874 504.6065 504.7256 504.8447 504.9637 505.0828 505.2018 505.3208 505.4398 505.5587 505.6777 505.7966 505.9155 506.0344 506.1533 506.2721 506.3910 506.5098 506.6286 506.7474 506.8662 506.9849 507.1037 507.2224 507.3411 507.4598 507.5785 507.6971 507.8158 507.9344 508.0530 508.1716 508.2901 508.4087 508.5272 508.6458 508.7643 508.8827 509.0012 509.1196 509.2381 509.3565 509.4749 509.5933 509.7116 509.8300 509.9483 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250419T114549.0Z 9240.490151 215 1 30.01 2 76.99 86.64 75.54 200.26 0.00 1 0.00 1 0 22 2.917e-03 2.888e-03 1.292e-04 1.290e-04 7.441661e+03 7.931596e+00 5.366646e+02 -6.000000e+00 1.515615e+02 277.83 -2.00 20.00 -2.00 505.30 0.00e+00 9.086640e-04 3.445022e-06 5.952139e-05 -6.000000e+00 7.928010e-05 277.83 -2.00 20.00 -2.00 500.62 0.00e+00 3.995383e-01 2.490551e-03 5.021853e-02 -6.000000e+00 5.678983e-02 228.51 -2.00 3.57 -2.00 502.19 0.00e+00 4.329 0.001 489.00 513.00 1 2.6362e+00 1.8982e-04 7.5857e-03 -6.0000e+00 4.3331e-03 -2.5014e-02 4.9428e-05 1.3073e-03 -6.0000e+00 1.1463e-03 7.2616e-02 3.1436e-04 1.0450e-05 7.4659e-05 -6.0000e+00 2.4882e-04 -2.4484e-02 -1.9511e-05 10 0 0 10 0 0 87.94 21.60 0.89 -0.02448 -0.02230 413 413 1 4 0 72.660 29.00 15.00 21.60 22.37 1.5 969.50 900000 -616 -263 -87 247 383 450 516 443 407 223 53 -74 -163 -239 -279 -90 72 117 216 238 173 188 297 255 372 377 298 -10 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-248 -65 74 246 352 543 623 563 427 380 181 85 161 118 138 248 183 128 242 220 26 121 45 -232 -175 -147 -194 -26 181 145 127 153 146 240 298 264 100 -80 -279 -416 -405 SQ 20250419T120544.3Z 9240.503985 222 1 4.23 2 73.39 90.06 76.85 204.43 0.00 1 0.00 1 0 15 3.214e-03 3.185e-03 1.541e-03 1.539e-03 6.087048e+03 9.283496e+01 4.441052e+02 -6.000000e+00 1.670005e+02 277.83 -2.00 20.00 -2.00 505.29 0.00e+00 7.808749e-04 4.107838e-05 4.868613e-05 -6.000000e+00 8.735462e-05 277.83 -2.00 20.00 -2.00 500.57 0.00e+00 3.033761e-01 2.980060e-02 4.144139e-02 -6.000000e+00 6.254748e-02 228.51 -2.00 3.57 -2.00 502.14 0.00e+00 3.444 0.001 489.00 513.00 1 5.4450e+00 2.2713e-03 6.1148e-03 -6.0000e+00 4.7727e-03 -1.4079e-02 5.9305e-04 1.0744e-03 -6.0000e+00 1.2619e-03 5.0094e-03 -1.9772e-04 1.2547e-04 6.2750e-05 -6.0000e+00 2.7412e-04 -2.1815e-02 -2.8566e-06 12 1 1 12 1 1 92.82 21.61 0.81 -0.02182 -0.02319 3 28 1 4 0 1056.890 29.25 15.00 21.61 23.32 1.5 974.03 900000 -542 -459 -372 90 442 105 427 334 275 194 40 150 49 -421 -248 -62 60 80 55 260 334 126 290 316 212 351 106 145 -472 -401 -404 76 155 -95 395 -152 -87 -345 -110 -431 -250 -73 388 398 275 363 15 44 27 -370 -304 -612 -593 -171 -91 -108 279 73 90 82 344 103 366 451 66 286 -210 -265 -10 -782 -64 44 -118 -228 -236 -321 51 -596 -462 -342 -320 -204 -52 -168 -209 -84 43 156 -294 38 298 321 333 494 424 271 445 -358 -652 -543 -861 -500 -180 -470 -103 -53 -323 -29 -366 -404 -123 168 378 92 663 553 534 523 418 192 -58 421 276 352 169 -12 133 302 18 55 298 -329 -280 -376 -341 -261 -128 259 258 203 51 131 25 365 382 55 -166 -255 -597 -390 900000 -519 -441 -371 91 452 108 443 349 285 197 40 153 49 -418 -246 -62 61 82 56 267 343 130 299 326 221 364 110 147 -477 -401 -400 75 155 -98 414 -160 -90 -354 -111 -434 -252 -75 398 414 282 381 16 45 27 -370 -302 -596 -574 -168 -91 -108 284 75 92 84 350 106 377 464 68 285 -207 -265 -10 -765 -62 43 -117 -224 -234 -321 50 -575 -442 -326 -308 -198 -51 -165 -205 -83 42 152 -288 37 295 323 332 499 419 268 428 -345 -615 -503 -804 -478 -175 -471 -103 -53 -318 -29 -360 -402 -122 168 381 94 672 565 540 531 421 194 -58 419 274 346 167 -12 132 298 18 55 290 -322 -271 -361 -329 -257 -126 259 256 203 52 133 26 374 391 56 -165 -253 -583 -381 SQ 20250419T123035.2Z 9240.521241 237 1 30.70 2 68.91 94.42 78.79 209.48 0.00 1 0.00 1 0 15 3.834e-03 3.821e-03 2.628e-03 2.616e-03 4.902625e+03 1.570033e+02 3.683813e+02 -6.000000e+00 1.992411e+02 277.83 -2.00 20.00 -2.00 505.23 0.00e+00 6.844638e-04 6.951716e-05 3.772981e-05 -6.000000e+00 1.042212e-04 277.83 -2.00 20.00 -2.00 500.34 0.00e+00 2.075381e-01 5.126382e-02 3.128727e-02 -6.000000e+00 7.467190e-02 228.51 -2.00 3.57 -2.00 501.92 0.00e+00 2.753 0.000 489.00 513.00 1 8.1425e+00 3.9153e-03 4.8046e-03 -6.0000e+00 5.6973e-03 3.1269e-03 1.0259e-03 8.3635e-04 -6.0000e+00 1.5075e-03 3.7567e-04 7.3304e-04 2.1523e-04 5.1151e-05 -6.0000e+00 3.2713e-04 -2.7295e-02 -1.6813e-05 11 8 0 10 0 0 99.98 21.62 0.62 -0.02730 -0.02221 13 13 1 4 0 2361.330 29.00 14.99 21.62 24.05 1.5 976.49 900000 -633 -434 -10 -671 -11 178 873 12 568 -63 -292 -446 -217 -34 51 302 545 256 484 531 41 378 751 54 775 -144 339 -415 -289 -128 -301 165 -102 69 -85 192 -308 -145 -481 -559 -491 113 -140 36 159 210 195 -150 20 -367 -712 -657 -409 -804 22 -65 30 191 -93 578 359 20 699 197 -543 356 822 -3 459 -226 -89 246 -388 -85 -596 183 -471 -187 -656 -197 -383 -522 -12 -381 -138 623 -512 238 -338 264 387 408 46 458 289 625 49 -271 -115 -1016 -156 -802 -519 -72 -280 129 -466 -131 -186 -337 -175 28 247 395 483 334 10 570 225 -221 697 73 128 359 274 18 -269 199 -106 375 173 -133 487 -106 -418 -589 37 297 432 374 172 230 -139 205 369 -501 -342 -246 -278 -280 900000 -580 -408 -10 -681 -11 186 925 13 601 -66 -302 -456 -218 -34 50 300 550 267 516 568 44 405 802 59 836 -157 364 -442 -296 -127 -296 164 -104 73 -93 209 -331 -154 -505 -584 -514 119 -149 39 173 228 210 -159 21 -371 -699 -630 -388 -781 22 -67 32 201 -97 602 377 21 738 208 -572 364 825 -3 452 -221 -86 240 -386 -86 -607 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