File name: Pandora284s1_Downsview_20250428_L2Fit_fout2c2d20241105p1-8.txt File generation date: 20250905T152839.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v1d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250428_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0011 305.1417 305.2823 305.4229 305.5635 305.7040 305.8446 305.9851 306.1256 306.2662 306.4067 306.5471 306.6876 306.8281 306.9686 307.1090 307.2494 307.3899 307.5303 307.6707 307.8111 307.9515 308.0918 308.2322 308.3725 308.5129 308.6532 308.7935 308.9338 309.0741 309.2144 309.3547 309.4949 309.6352 309.7754 309.9156 310.0559 310.1961 310.3363 310.4764 310.6166 310.7568 310.8969 311.0371 311.1772 311.3173 311.4574 311.5975 311.7376 311.8777 312.0177 312.1578 312.2978 312.4378 312.5779 312.7179 312.8579 312.9978 313.1378 313.2778 313.4177 313.5577 313.6976 313.8375 313.9774 314.1173 314.2572 314.3970 314.5369 314.6768 314.8166 314.9564 315.0962 315.2360 315.3758 315.5156 315.6554 315.7951 315.9349 316.0746 316.2143 316.3541 316.4938 316.6335 316.7731 316.9128 317.0525 317.1921 317.3317 317.4714 317.6110 317.7506 317.8902 318.0297 318.1693 318.3089 318.4484 318.5879 318.7275 318.8670 319.0065 319.1460 319.2854 319.4249 319.5644 319.7038 319.8432 319.9827 320.1221 320.2615 320.4009 320.5402 320.6796 320.8189 320.9583 321.0976 321.2369 321.3762 321.5155 321.6548 321.7941 321.9333 322.0726 322.2118 322.3511 322.4903 322.6295 322.7687 322.9079 323.0470 323.1862 323.3253 323.4645 323.6036 323.7427 323.8818 324.0209 324.1600 324.2990 324.4381 324.5771 324.7162 324.8552 324.9942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250428T114815.1Z 9249.491841 96 1 29.60 2 74.27 85.07 76.70 74.28 0.00 1 0.00 1 0 17 2.660e-01 6.876e-03 2.064e-01 5.112e-03 5.528732e-01 2.643328e-03 6.349266e-03 -6.000000e+00 1.505513e-01 229.33 -2.00 3.57 -2.00 320.43 0.00e+00 5.900396e-05 9.680788e-04 5.644793e-04 -6.000000e+00 6.512734e-03 278.87 -2.00 20.00 -2.00 319.86 0.00e+00 3.623 0.001 302.00 328.00 3 3.5382e+00 7.9852e-03 4.6316e-02 -6.0000e+00 3.7599e-01 6.0608e-02 1.0106e-02 2.9712e-02 -6.0000e+00 4.0869e-01 -3.5754e-02 9.6374e-03 1.4935e-02 -6.0000e+00 2.4250e-01 6.8857e-03 4.8519e-03 4.3049e-03 -6.0000e+00 1.0245e-01 2.2582e-04 -4.8694e-04 1.4226e-04 4.9058e-05 -6.0000e+00 6.9526e-03 -3.1801e-02 5.7436e-05 11 8 0 10 0 0 89.12 21.86 0.41 -0.03180 -0.03546 15 15 1 5 0 1973.110 29.25 14.99 21.86 14.99 1.9 937.59 900000 -426 -53179 47371 -34663 -43198 -47019 253911 -19619 -64507 -44663 -60278 -65534 -27895 3097 14033 43857 -19378 -8967 4541 17030 -15904 -8466 5700 -1189 -11813 -12879 -22757 -11856 -28046 1387 -14321 -609 -9994 -9590 -5235 -3169 -16785 -703 -10450 2422 -1339 -2686 2832 6913 3334 1273 -3887 5823 -1544 3142 2490 4566 3682 4679 480 2501 3082 1244 1452 -867 1108 -732 5449 1107 1226 450 -1531 -243 -593 1442 358 392 -681 -45 407 -1341 -1337 -1682 -2513 107 -979 -1753 -764 -1220 -390 -107 162 522 1648 651 -288 428 -673 154 -1301 -420 623 452 -836 -488 520 -1003 -56 -1175 -363 206 -348 -355 768 492 472 392 687 393 -541 -665 -56 -103 168 -350 32 566 310 131 50 -696 -347 253 -596 388 -127 -131 69 -116 -11 53 242 412 96 -155 -196 -306 -136 900000 -2 -506 236 -267 -333 -422 1266 -176 -1029 -623 -1022 -1340 -487 49 245 656 -599 -273 129 450 -595 -295 185 -46 -548 -636 -1237 -550 -1496 59 -843 -36 -747 -736 -363 -218 -1498 -65 -1313 316 -201 -434 450 1068 539 213 -692 961 -283 586 519 1033 914 1241 139 742 933 380 429 -259 338 -251 1983 464 523 184 -624 -101 -275 755 207 233 -402 -25 204 -612 -569 -726 -1226 60 -638 -1298 -605 -1024 -316 -93 146 480 1486 566 -258 352 -533 124 -1189 -396 664 545 -1093 -626 611 -1076 -55 -1208 -401 239 -425 -461 1072 762 797 629 1180 642 -835 -982 -82 -160 277 -604 55 927 492 200 74 -983 -469 353 -939 673 -220 -238 130 -230 -24 118 548 946 221 -342 -410 -604 -262 SS 20250428T115400.8Z 9249.495842 100 1 10.92 2 73.23 86.04 75.72 75.15 0.00 1 0.00 1 0 17 1.490e-01 7.334e-03 5.652e-02 3.344e-03 5.237141e-01 1.695341e-03 6.141924e-03 -6.000000e+00 8.435029e-02 229.33 -2.00 3.57 -2.00 319.61 0.00e+00 1.351283e-03 4.851356e-04 6.131070e-04 -6.000000e+00 3.648820e-03 278.87 -2.00 20.00 -2.00 318.99 0.00e+00 3.412 0.001 302.00 328.00 3 2.5278e+00 4.8064e-03 4.3613e-02 -6.0000e+00 2.1066e-01 5.2198e-02 5.7079e-03 2.7771e-02 -6.0000e+00 2.2898e-01 -5.0917e-02 4.7605e-03 1.3932e-02 -6.0000e+00 1.3587e-01 1.7781e-02 2.4928e-03 4.1744e-03 -6.0000e+00 5.7397e-02 7.8515e-04 -5.0171e-04 9.0283e-05 4.3138e-05 -6.0000e+00 3.8953e-03 -3.1170e-02 8.1558e-05 12 9 1 12 1 1 98.83 21.85 0.31 -0.03117 -0.03494 12 36 1 5 0 839.980 29.25 15.00 21.85 15.41 1.9 939.45 900000 13114 -39554 -57833 -70339 -44766 -65819 -23321 -49476 -49589 -29438 -49402 -50367 -35568 -14744 -5686 4211 -8283 -1214 -7848 -3453 -9903 -817 -4618 -7674 -9355 -3432 -3422 -3621 -13431 -7060 -5633 804 577 -4363 -8178 -7442 -4203 -230 -820 -1316 1510 2548 377 2574 3760 1712 196 7 1931 1140 2431 1987 3392 1388 2756 1471 938 1824 -23 706 1067 1798 2505 2786 221 1105 -293 -801 551 1095 1374 561 -63 -227 -696 -1239 -1952 -1915 -1345 -1115 -987 -2088 -1622 -1813 -1315 -268 -115 193 840 980 690 -553 -277 -473 -579 -268 464 688 63 17 -597 -926 -785 -534 -637 -538 -442 -556 679 434 549 867 641 123 -328 12 -68 -166 43 160 74 452 200 294 104 -130 337 484 220 -108 121 -252 -301 -323 278 63 166 -30 102 18 -208 -228 -381 900000 128 -735 -1339 -1721 -774 -1417 -365 -1162 -1310 -672 -1418 -1659 -1253 -524 -224 173 -421 -63 -461 -204 -633 -48 -297 -556 -741 -269 -267 -269 -1078 -571 -524 81 66 -541 -990 -903 -557 -35 -156 -295 330 584 92 622 906 428 50 2 507 320 744 675 1230 552 1131 634 416 794 -10 299 470 868 1237 1509 125 586 -153 -430 325 739 930 396 -44 -162 -455 -728 -1075 -1061 -827 -802 -753 -1812 -1511 -1655 -1280 -275 -124 213 912 1015 663 -498 -254 -444 -562 -297 542 906 84 22 -774 -1085 -917 -599 -774 -688 -593 -744 973 648 888 1445 1051 192 -480 17 -101 -245 67 262 120 709 304 456 155 -185 459 683 347 -179 203 -443 -549 -589 538 128 327 -60 204 37 -400 -437 -713 SS 20250428T120340.7Z 9249.502554 106 1 28.41 2 71.49 87.68 74.06 76.61 0.00 1 0.00 1 0 25 3.239e-01 1.901e-02 2.962e-01 1.756e-02 4.758968e-01 9.196933e-03 5.558883e-03 -6.000000e+00 1.839650e-01 229.33 -2.00 3.57 -2.00 320.24 0.00e+00 4.002635e-03 3.118520e-03 2.794190e-04 -6.000000e+00 8.843682e-03 278.87 -2.00 20.00 -2.00 319.64 0.00e+00 3.110 0.001 302.00 328.00 3 5.4586e+00 2.7122e-02 3.9863e-02 -6.0000e+00 4.5874e-01 1.2222e-01 3.3270e-02 2.5785e-02 -6.0000e+00 4.9890e-01 -5.1343e-02 2.9517e-02 1.3220e-02 -6.0000e+00 2.9583e-01 5.7346e-03 1.5015e-02 5.6181e-03 -6.0000e+00 1.2636e-01 5.6024e-05 -1.1210e-03 5.1056e-04 5.2042e-05 -6.0000e+00 8.8336e-03 -3.0465e-02 4.7437e-05 12 8 8 10 0 0 99.34 21.83 1.16 -0.03046 -0.03889 8 8 1 5 0 3550.820 29.25 14.99 21.83 16.23 1.8 943.12 900000 -111141 -43860 900000 900000 900000 -49728 -134704 -106818 151740 -63870 900000 18956 -44387 120837 70745 119931 -53306 47287 -3470 4557 2349 -11046 36496 112588 -18000 -25154 -2297 10318 2161 3082 -21087 26259 43481 -8520 -1449 42161 32695 3136 -1710 9173 16043 18367 25558 -2898 7307 6377 5969 6253 6417 -368 7256 6954 3762 -4452 9317 1513 -2120 7691 -13013 1305 8321 7931 -5383 5404 -1229 3237 -5135 -32 -1835 -1564 -2491 -3621 3140 -791 36 -5522 188 1054 -1591 -7064 2083 -2306 -2002 -502 -2818 4002 746 1227 407 1987 1973 739 -1551 -2388 -2906 667 728 2108 1795 -663 -2427 -574 -528 -1817 -713 1520 -2217 -316 -142 834 -767 2086 1185 1211 -2241 637 898 -1770 431 -761 -316 1536 357 552 421 -857 -69 -1333 -142 76 1110 -1319 722 -561 1720 21 285 -1013 251 -1470 237 654 121 900000 -3632 -819 900000 900000 900000 -851 -5869 -3989 2597 -1789 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