File name: Pandora284s1_Downsview_20250503_L2Fit_fout2c2d20241105p1-8.txt File generation date: 20250905T152947.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v1d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250503_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250503 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0011 305.1417 305.2823 305.4229 305.5635 305.7040 305.8446 305.9851 306.1256 306.2662 306.4067 306.5471 306.6876 306.8281 306.9686 307.1090 307.2494 307.3899 307.5303 307.6707 307.8111 307.9515 308.0918 308.2322 308.3725 308.5129 308.6532 308.7935 308.9338 309.0741 309.2144 309.3547 309.4949 309.6352 309.7754 309.9156 310.0559 310.1961 310.3363 310.4764 310.6166 310.7568 310.8969 311.0371 311.1772 311.3173 311.4574 311.5975 311.7376 311.8777 312.0177 312.1578 312.2978 312.4378 312.5779 312.7179 312.8579 312.9978 313.1378 313.2778 313.4177 313.5577 313.6976 313.8375 313.9774 314.1173 314.2572 314.3970 314.5369 314.6768 314.8166 314.9564 315.0962 315.2360 315.3758 315.5156 315.6554 315.7951 315.9349 316.0746 316.2143 316.3541 316.4938 316.6335 316.7731 316.9128 317.0525 317.1921 317.3317 317.4714 317.6110 317.7506 317.8902 318.0297 318.1693 318.3089 318.4484 318.5879 318.7275 318.8670 319.0065 319.1460 319.2854 319.4249 319.5644 319.7038 319.8432 319.9827 320.1221 320.2615 320.4009 320.5402 320.6796 320.8189 320.9583 321.0976 321.2369 321.3762 321.5155 321.6548 321.7941 321.9333 322.0726 322.2118 322.3511 322.4903 322.6295 322.7687 322.9079 323.0470 323.1862 323.3253 323.4645 323.6036 323.7427 323.8818 324.0209 324.1600 324.2990 324.4381 324.5771 324.7162 324.8552 324.9942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250503T133933.9Z 9254.569142 213 1 28.93 2 53.19 104.16 102.66 39.22 0.00 1 0.00 1 0 17 2.305e-02 8.783e-03 2.494e-02 7.196e-03 2.411741e-01 3.579239e-03 2.939450e-03 -6.000000e+00 1.306982e-02 229.79 -2.00 3.57 -2.00 317.66 0.00e+00 8.703308e-04 5.485550e-04 1.129643e-04 -6.000000e+00 5.656269e-04 279.45 -2.00 20.00 -2.00 316.94 0.00e+00 1.665 0.000 302.00 328.00 3 6.0846e+00 9.5288e-03 2.0779e-02 -6.0000e+00 3.2671e-02 3.3735e-02 1.0752e-02 1.2754e-02 -6.0000e+00 3.5495e-02 5.2419e-03 6.5729e-03 6.2444e-03 -6.0000e+00 2.1060e-02 -5.0339e-03 3.2649e-03 1.8324e-03 -6.0000e+00 8.8944e-03 1.7413e-04 4.1622e-05 2.0510e-04 1.8736e-05 -6.0000e+00 6.0244e-04 -3.2051e-02 1.0077e-04 11 8 0 10 0 0 99.75 21.71 0.53 -0.03205 -0.03174 8 8 1 5 0 3615.500 29.25 15.00 21.71 14.83 1.9 936.23 900000 5135 3094 2718 -4855 -10018 -6960 7162 4774 -7109 -3499 -4041 2968 -5375 1499 2748 -3302 -5863 5702 -1677 5 2506 1137 -491 1919 -3159 -630 2044 1190 228 -692 4037 807 417 1159 -5795 -3047 -4087 2058 948 1235 -276 454 -1729 -1600 -1301 2577 -1600 -734 -594 763 2244 649 -1164 1198 273 2085 1013 -1939 -664 2847 -762 2289 1144 1633 651 -801 -431 -117 33 2474 1452 -399 321 -594 -795 -196 -444 -2391 -2791 232 -1045 -1377 -2078 -763 308 -926 319 529 219 849 -1030 2198 -272 -73 -1014 -749 724 318 276 355 -1449 -1310 -1111 6 -882 264 -423 228 280 1027 424 508 874 1099 -311 -55 -635 -507 -509 -657 299 -333 170 1114 -171 -308 426 654 -161 126 -462 -271 458 -35 430 -319 723 113 141 392 -651 -601 -344 900000 482 316 277 -483 -933 -617 658 509 -938 -454 -513 369 -826 247 507 -697 -1308 1176 -386 1 577 262 -118 477 -867 -173 535 291 53 -162 963 215 121 331 -1635 -836 -1262 708 396 589 -144 243 -969 -898 -727 1380 -870 -385 -304 389 1198 377 -724 762 179 1371 682 -1331 -440 1822 -526 1658 909 1361 534 -607 -301 -80 25 2040 1309 -379 299 -536 -664 -145 -298 -1569 -1957 179 -912 -1323 -2126 -807 346 -1127 403 623 258 1045 -1188 2224 -257 -67 -1010 -822 870 423 386 483 -1865 -1543 -1247 7 -1128 351 -592 331 427 1504 655 786 1285 1639 -429 -71 -834 -698 -754 -1037 477 -527 260 1610 -238 -406 530 819 -218 181 -702 -420 715 -57 742 -528 1215 196 244 726 -1173 -1043 -584 SS 20250503T134430.2Z 9254.572571 216 1 28.94 2 52.32 105.19 102.13 40.18 0.00 1 0.00 1 0 17 1.206e-02 5.836e-03 7.014e-03 2.595e-03 2.371164e-01 1.299921e-03 2.869569e-03 -6.000000e+00 6.838029e-03 229.79 -2.00 3.57 -2.00 317.07 0.00e+00 3.743216e-04 1.713968e-04 9.650611e-05 -6.000000e+00 2.959573e-04 279.45 -2.00 20.00 -2.00 316.38 0.00e+00 1.632 0.000 302.00 328.00 3 4.8435e+00 3.4320e-03 2.0341e-02 -6.0000e+00 1.7093e-02 2.6981e-02 3.8511e-03 1.2406e-02 -6.0000e+00 1.8571e-02 -2.9975e-03 2.2754e-03 6.0693e-03 -6.0000e+00 1.1019e-02 -3.0282e-03 1.1003e-03 1.6986e-03 -6.0000e+00 4.6534e-03 6.3175e-04 -9.7580e-05 7.2962e-05 1.8083e-05 -6.0000e+00 3.1521e-04 -3.2278e-02 8.0022e-05 10 0 0 10 0 0 99.89 21.71 0.32 -0.03228 -0.03301 11 11 1 5 0 2630.960 29.25 15.00 21.71 15.01 1.9 937.17 900000 -2333 514 -31 -3025 -6689 -2855 -4712 -602 2531 -2024 -2156 -895 136 -916 -794 1442 296 866 1618 1885 1242 -1064 1530 68 -205 -705 7 -825 -1173 -1618 780 1425 540 -470 -2352 -2952 -1163 -824 1399 -402 -288 -522 -627 -307 227 -211 -658 -1086 -954 -248 1526 1664 1131 723 396 1569 223 301 637 514 824 1118 1403 1293 63 102 -1162 -552 173 841 398 52 705 663 -389 -233 -1531 -1985 -1641 -1465 -862 -1548 -1727 -1036 -680 -36 -256 68 801 505 582 -5 -40 -237 -306 289 212 735 70 -250 -584 -824 -457 -286 -505 -408 -459 -241 211 432 750 726 527 -121 -29 -390 -145 174 -152 4 78 394 173 334 34 111 -132 127 -74 487 84 222 66 -220 46 -38 211 7 95 -401 -218 -38 -446 900000 -328 75 -5 -409 -833 -336 -614 -85 383 -327 -339 -145 25 -193 -189 361 77 232 445 535 357 -309 446 21 -68 -241 2 -255 -340 -469 235 462 190 -167 -782 -987 -425 -356 645 -216 -166 -313 -385 -189 138 -129 -391 -629 -539 -140 902 1050 755 508 286 1140 167 222 459 370 615 899 1218 1185 57 84 -895 -415 141 770 363 49 657 592 -354 -189 -1137 -1417 -1240 -1250 -819 -1488 -1759 -1098 -771 -43 -325 88 1032 624 662 -5 -42 -240 -303 314 256 973 90 -342 -744 -965 -510 -334 -644 -547 -643 -325 297 646 1173 1139 791 -168 -40 -509 -190 238 -207 6 116 572 245 489 47 146 -166 160 -100 701 128 317 96 -332 74 -64 363 13 167 -695 -363 -60 -703 SS 20250503T165834.2Z 9254.707341 343 1 30.07 2 28.10 171.73 74.46 72.97 0.00 1 0.00 1 0 17 8.009e-03 6.002e-03 2.425e-03 1.507e-03 1.681185e-01 7.653166e-04 2.051655e-03 -6.000000e+00 4.542947e-03 229.80 -2.00 3.57 -2.00 315.40 0.00e+00 3.009245e-04 6.935597e-05 3.095767e-05 -6.000000e+00 1.965590e-04 279.46 -2.00 20.00 -2.00 314.80 0.00e+00 1.133 0.000 302.00 328.00 3 4.6648e+00 1.9805e-03 1.4223e-02 -6.0000e+00 1.1357e-02 2.5400e-02 2.2056e-03 8.7562e-03 -6.0000e+00 1.2337e-02 -3.8597e-04 1.2589e-03 4.2762e-03 -6.0000e+00 7.3200e-03 -3.6306e-03 5.6158e-04 1.1949e-03 -6.0000e+00 3.0922e-03 1.3939e-03 -2.0512e-05 4.1736e-05 1.4653e-05 -6.0000e+00 2.0935e-04 -3.3239e-02 1.1330e-04 10 0 0 10 0 0 99.95 21.72 0.34 -0.03324 -0.03339 21 21 1 5 0 1431.740 29.25 15.00 21.72 19.01 1.7 955.06 900000 42 311 -1247 -2594 -1662 -1415 -80 347 994 -525 -1621 -69 -75 825 -136 70 314 354 994 832 987 598 944 666 328 166 -488 -1089 -444 164 968 1565 767 -954 -2547 -2442 -1799 -904 347 -133 -188 -736 -848 -689 -295 -450 -436 -926 -561 -55 870 546 901 878 916 993 523 67 984 630 876 1338 1818 1267 61 -313 -933 -501 244 759 616 250 587 326 -178 -159 -958 -1083 -1358 -1252 -1380 -1660 -1806 -1157 -710 -649 84 180 457 334 472 122 -166 -313 -285 139 675 569 373 30 -350 -559 -278 -408 -671 -331 -287 -403 166 396 583 619 375 -93 -76 -16 -341 97 22 183 -81 -21 389 424 139 67 183 407 241 143 18 -78 -179 -47 202 -139 250 92 85 152 -352 -331 -676 900000 12 92 -370 -700 -430 -355 -21 104 294 -160 -479 -23 -25 302 -56 30 138 158 454 392 466 279 447 332 171 89 -256 -528 -198 71 434 739 389 -487 -1209 -1151 -933 -547 227 -100 -139 -563 -663 -537 -228 -345 -349 -715 -416 -40 666 445 706 715 759 834 447 56 810 520 749 1225 1779 1302 61 -284 -779 -438 211 738 650 255 591 341 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