File name: Pandora284s1_Downsview_20250513_L2Fit_fout2c2d20241105p1-8.txt File generation date: 20250905T153409.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v1d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250513_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250513 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0011 305.1417 305.2823 305.4229 305.5635 305.7040 305.8446 305.9851 306.1256 306.2662 306.4067 306.5471 306.6876 306.8281 306.9686 307.1090 307.2494 307.3899 307.5303 307.6707 307.8111 307.9515 308.0918 308.2322 308.3725 308.5129 308.6532 308.7935 308.9338 309.0741 309.2144 309.3547 309.4949 309.6352 309.7754 309.9156 310.0559 310.1961 310.3363 310.4764 310.6166 310.7568 310.8969 311.0371 311.1772 311.3173 311.4574 311.5975 311.7376 311.8777 312.0177 312.1578 312.2978 312.4378 312.5779 312.7179 312.8579 312.9978 313.1378 313.2778 313.4177 313.5577 313.6976 313.8375 313.9774 314.1173 314.2572 314.3970 314.5369 314.6768 314.8166 314.9564 315.0962 315.2360 315.3758 315.5156 315.6554 315.7951 315.9349 316.0746 316.2143 316.3541 316.4938 316.6335 316.7731 316.9128 317.0525 317.1921 317.3317 317.4714 317.6110 317.7506 317.8902 318.0297 318.1693 318.3089 318.4484 318.5879 318.7275 318.8670 319.0065 319.1460 319.2854 319.4249 319.5644 319.7038 319.8432 319.9827 320.1221 320.2615 320.4009 320.5402 320.6796 320.8189 320.9583 321.0976 321.2369 321.3762 321.5155 321.6548 321.7941 321.9333 322.0726 322.2118 322.3511 322.4903 322.6295 322.7687 322.9079 323.0470 323.1862 323.3253 323.4645 323.6036 323.7427 323.8818 324.0209 324.1600 324.2990 324.4381 324.5771 324.7162 324.8552 324.9942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250513T112614.5Z 9264.476556 244 1 28.92 2 75.20 78.37 104.65 248.48 0.00 1 0.00 1 0 25 2.272e-01 1.353e-02 2.643e-01 1.122e-02 5.433011e-01 5.892370e-03 6.342896e-03 -6.000000e+00 1.305964e-01 230.69 -2.00 3.57 -2.00 320.69 0.00e+00 2.607438e-03 2.316415e-03 1.230360e-03 -6.000000e+00 5.789158e-03 280.59 -2.00 20.00 -2.00 320.10 0.00e+00 3.837 0.001 302.00 328.00 3 4.2767e+00 1.8314e-02 4.7965e-02 -6.0000e+00 3.2804e-01 1.2125e-01 2.3182e-02 2.9891e-02 -6.0000e+00 3.5656e-01 -1.4120e-01 2.1531e-02 1.5539e-02 -6.0000e+00 2.0984e-01 5.2042e-02 1.0749e-02 5.0325e-03 -6.0000e+00 8.8225e-02 8.9308e-05 -7.7488e-04 3.2212e-04 6.2464e-05 -6.0000e+00 6.1458e-03 -3.0827e-02 1.4603e-04 12 8 8 10 0 0 98.00 21.73 0.46 -0.03083 -0.03665 12 12 1 5 0 2409.230 29.25 15.00 21.73 21.55 1.6 965.37 900000 -154523 -42600 6294 900000 -56008 -46833 900000 -58031 900000 42386 -70452 -62874 -81436 -8065 -65504 -2692 -19315 43319 -30281 6499 35275 -8929 -17775 -14783 -3165 17771 8603 3871 -8705 9233 -53569 32209 -6297 4661 18477 -9446 -18836 -542 -16649 -585 -1659 17463 4317 10407 18740 11511 11603 3997 2037 7100 4033 4074 606 3171 5370 -3177 7945 -8573 5057 -4156 9607 6100 1825 6571 2313 584 -6261 5106 -241 -36 -2028 310 -1949 826 -1883 7550 -3190 3475 -1932 -775 123 -3497 -4383 2280 -414 761 1441 1664 1073 603 369 -3878 447 -2655 -598 -1183 1619 110 -344 -250 -213 -1156 -1088 -1788 -1262 239 -2614 208 -66 285 1018 107 52 1004 -688 386 -1218 850 588 -689 449 460 821 661 357 -974 1444 423 -853 1058 -272 -191 258 -93 41 -59 387 33 -241 -127 65 -655 -114 900000 -4607 -466 69 900000 -612 -512 900000 -807 900000 463 -1330 -1250 -2428 -144 -2539 -64 -595 775 -1204 187 771 -302 -689 -602 -123 583 308 138 -346 363 -4626 1373 -447 306 990 -671 -1647 -47 -2093 -73 -232 2138 628 1445 2417 1623 1649 625 334 1172 758 846 141 773 1338 -892 2041 -2568 1283 -1145 2405 1747 615 2327 872 213 -2375 1769 -98 -17 -1053 163 -1027 399 -852 2781 -1217 1250 -819 -382 69 -2305 -3148 1615 -323 625 1236 1461 941 508 289 -2938 308 -1930 -474 -1081 1646 128 -433 -310 -245 -1210 -1056 -1798 -1367 269 -3183 262 -90 431 1664 184 87 1594 -1038 551 -1782 1279 945 -1172 751 745 1280 993 515 -1365 1897 583 -1328 1797 -506 -373 520 -198 85 -129 860 75 -547 -278 134 -1409 -237 SS 20250513T120556.5Z 9264.504126 266 1 27.17 2 68.11 84.89 111.24 254.39 0.00 1 0.00 1 0 17 2.730e-02 5.926e-03 1.785e-02 2.315e-03 3.726709e-01 1.162479e-03 4.436748e-03 -6.000000e+00 1.553463e-02 230.69 -2.00 3.57 -2.00 318.74 0.00e+00 1.094396e-03 2.500168e-04 3.115269e-04 -6.000000e+00 6.734625e-04 280.59 -2.00 20.00 -2.00 318.04 0.00e+00 2.659 0.000 302.00 328.00 3 3.4773e+00 3.1967e-03 3.2834e-02 -6.0000e+00 3.8902e-02 9.9280e-03 3.6571e-03 1.9802e-02 -6.0000e+00 4.2230e-02 -1.7205e-03 2.5517e-03 9.7325e-03 -6.0000e+00 2.5054e-02 -3.9572e-03 1.3400e-03 2.8360e-03 -6.0000e+00 1.0569e-02 7.6026e-04 -3.2971e-04 6.5014e-05 2.9159e-05 -6.0000e+00 7.1407e-04 -3.1393e-02 6.0712e-05 12 1 1 12 1 1 99.78 21.69 0.34 -0.03139 -0.03387 21 24 1 5 0 1234.670 29.25 15.00 21.69 22.55 1.6 969.78 900000 -3904 -8841 3430 -10075 -15198 -1730 -4560 -10600 -10483 -4449 -6528 -5279 -7815 -2186 -2430 1501 471 1124 1450 -2936 -3596 416 1947 -1885 -2458 2149 -1774 -1858 -452 -2886 584 745 1171 -908 -5226 -4046 -132 -601 295 -1119 620 -1076 235 60 224 1003 -8 -1167 -506 222 1538 419 -46 1465 689 146 681 665 722 857 1028 1509 2458 1182 481 115 -1161 431 951 689 674 485 1140 126 -864 -225 -1354 -2004 -1222 -1038 -1717 -1145 -2112 -1006 -959 -788 70 284 633 976 895 -214 -494 -642 -587 -54 618 857 136 238 -581 -980 -533 -474 -561 -774 -402 -164 203 714 907 551 369 274 -166 -214 -226 10 68 109 -59 -23 164 491 238 -322 -380 403 180 537 -249 11 -321 -204 135 -133 235 101 -88 145 -155 -261 -230 900000 -146 -381 133 -412 -590 -59 -175 -495 -544 -226 -339 -295 -533 -168 -220 145 49 123 167 -369 -461 51 246 -266 -371 322 -273 -269 -62 -419 91 130 226 -181 -1012 -780 -27 -150 89 -361 214 -397 88 23 85 382 -3 -447 -193 87 645 193 -23 757 372 82 385 372 395 467 583 931 1658 796 324 79 -764 280 621 516 549 409 943 100 -637 -161 -898 -1313 -865 -775 -1464 -1078 -1979 -980 -1003 -880 82 339 749 1100 933 -224 -481 -626 -574 -60 755 1084 184 314 -717 -1189 -608 -565 -727 -982 -532 -229 300 1061 1434 890 578 431 -242 -295 -315 15 107 168 -92 -34 258 741 342 -444 -501 539 264 852 -394 17 -540 -359 252 -245 443 195 -170 270 -277 -477 -411 SS 20250513T121239.1Z 9264.508786 270 1 14.83 2 66.90 86.01 112.37 255.38 0.00 1 0.00 1 0 25 2.923e-02 6.136e-03 1.846e-02 3.116e-03 3.540112e-01 1.567408e-03 4.214175e-03 -6.000000e+00 1.663026e-02 230.69 -2.00 3.57 -2.00 318.40 0.00e+00 8.559757e-04 3.007388e-04 1.998949e-04 -6.000000e+00 7.210297e-04 280.59 -2.00 20.00 -2.00 317.69 0.00e+00 2.529 0.000 302.00 328.00 3 3.6417e+00 4.2510e-03 3.1167e-02 -6.0000e+00 4.1646e-02 1.5285e-02 4.8280e-03 1.8716e-02 -6.0000e+00 4.5209e-02 -1.0149e-02 3.2110e-03 9.1479e-03 -6.0000e+00 2.6822e-02 1.4931e-03 1.6681e-03 2.6159e-03 -6.0000e+00 1.1314e-02 7.4831e-04 -2.9979e-04 8.7329e-05 2.6052e-05 -6.0000e+00 7.6452e-04 -3.1297e-02 4.5883e-05 12 1 1 12 1 1 97.70 21.69 0.34 -0.03130 -0.03355 9 20 1 5 0 1482.820 29.25 14.99 21.69 22.82 1.6 971.40 900000 -15205 -2842 -6448 -10356 -7085 -14294 2074 -9761 3191 -4860 -6558 -8640 -7954 -1101 7555 -1247 -1720 -1331 100 -969 1562 938 477 2921 884 -1516 207 -1200 -4420 -1154 1667 2495 2496 -1681 -2623 -1554 -4053 -1256 349 -326 1135 61 -839 -600 533 -71 104 -1264 -645 -202 1047 996 1102 1563 800 780 227 87 788 518 787 1987 2456 1434 259 -241 -902 -88 536 1249 780 -242 -298 -259 123 -521 -1805 -881 -1622 -1346 -918 -1105 -2183 -916 -1040 -404 202 282 1243 191 646 61 -290 -593 241 -29 711 485 191 122 -582 -686 -580 -506 -782 -224 -465 -626 309 649 632 485 916 71 -530 16 -251 -22 25 -181 202 71 251 521 -311 103 498 56 184 -73 259 -234 -332 -2 243 -242 102 225 182 130 -280 -252 -448 900000 -859 -155 -368 -563 -336 -725 98 -596 190 -325 -444 -648 -698 -107 785 -156 -229 -187 14 -148 236 142 75 485 159 -290 38 -211 -766 -199 310 512 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