File name: Pandora284s1_Downsview_20250823_L2Fit_fwvt1c2d20241105p1-8.txt
File generation date: 20250905T161327.2Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: 
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 284
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora284_OF_v1d20240708.txt
Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt
Level 1 file used: Pandora284s1_Downsview_20250823_L1_smca1c2d20241105p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20250823
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off of session 1
First and last pixel inside fitting window: 1618 1768
Nominal wavelengths inside fitting window [nm]: 492.0083 492.1292 492.2500 492.3709 492.4917 492.6125 492.7332 492.8540 492.9747 493.0955 493.2162 493.3369 493.4575 493.5782 493.6988 493.8194 493.9401 494.0606 494.1812 494.3018 494.4223 494.5428 494.6633 494.7838 494.9043 495.0248 495.1452 495.2656 495.3860 495.5064 495.6268 495.7472 495.8675 495.9878 496.1081 496.2284 496.3487 496.4689 496.5892 496.7094 496.8296 496.9498 497.0700 497.1901 497.3102 497.4304 497.5505 497.6706 497.7906 497.9107 498.0307 498.1507 498.2707 498.3907 498.5107 498.6306 498.7506 498.8705 498.9904 499.1103 499.2301 499.3500 499.4698 499.5896 499.7094 499.8292 499.9490 500.0687 500.1885 500.3082 500.4279 500.5475 500.6672 500.7869 500.9065 501.0261 501.1457 501.2653 501.3848 501.5044 501.6239 501.7434 501.8629 501.9824 502.1018 502.2213 502.3407 502.4601 502.5795 502.6989 502.8182 502.9376 503.0569 503.1762 503.2955 503.4148 503.5340 503.6533 503.7725 503.8917 504.0109 504.1300 504.2492 504.3683 504.4874 504.6065 504.7256 504.8447 504.9637 505.0828 505.2018 505.3208 505.4398 505.5587 505.6777 505.7966 505.9155 506.0344 506.1533 506.2721 506.3910 506.5098 506.6286 506.7474 506.8662 506.9849 507.1037 507.2224 507.3411 507.4598 507.5785 507.6971 507.8158 507.9344 508.0530 508.1716 508.2901 508.4087 508.5272 508.6458 508.7643 508.8827 509.0012 509.1196 509.2381 509.3565 509.4749 509.5933 509.7116 509.8300 509.9483
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250823T105116.5Z 9366.452274 58 1 18.37 2 87.41 76.85 89.98 74.59 0.00 1 0.00 1 0 22 4.673e-03 4.587e-03 6.623e-04 6.604e-04 2.336764e+04 4.815227e+01 1.517671e+03 -6.000000e+00 2.514548e+02 286.82 -2.00 20.00 -2.00 505.41 0.00e+00 2.676764e-03 1.815153e-05 1.704738e-04 -6.000000e+00 1.298779e-04 286.82 -2.00 20.00 -2.00 500.89 0.00e+00 1.332786e+00 1.264324e-02 1.325682e-01 -6.000000e+00 9.080524e-02 231.19 -2.00 3.57 -2.00 502.41 0.00e+00 14.471 0.059 489.00 513.00 1 3.7558e+00 9.6603e-04 2.5015e-02 -6.0000e+00 6.9497e-03 -5.2925e-02 2.4589e-04 3.5996e-03 -6.0000e+00 1.8345e-03 5.1071e-03 1.5463e-04 4.8002e-05 1.6559e-04 -6.0000e+00 3.9884e-04 6.3396e-03 -1.9845e-04 12 9 1 12 1 1 94.32 22.35 2.58 0.00634 0.00741 25 42 1 4 0 706.200 29.50 15.00 22.35 24.53 1.5 975.92 900000 -941 -239 180 574 763 751 895 747 789 394 273 -2 -310 -430 -482 -295 116 297 388 396 308 303 376 374 628 577 311 -184 -454 -828 -828 -623 27 144 137 56 -115 -281 -569 -585 -454 -199 -92 266 214 254 144 61 -325 -694 -1018 -1100 -1094 -752 -164 -10 257 234 178 238 314 505 464 395 195 283 -31 -201 -137 -474 -365 -271 106 -46 60 -102 -410 -578 -555 -418 -439 -242 -74 -209 -243 -63 -226 -101 -148 54 635 603 698 817 687 495 381 -315 -734 -1154 -983 -835 -688 -273 -28 -8 -390 -386 -533 -393 -320 -46 110 240 577 788 790 500 482 -29 -173 -121 170 255 441 322 211 285 -16 -156 -173 -160 -526 -426 -308 -426 42 400 304 215 229 192 478 656 706 413 127 -174 -554 -455 900000 -850 -214 168 536 729 734 863 726 761 387 266 -2 -295 -406 -455 -281 113 289 386 397 309 305 380 370 625 576 310 -182 -446 -791 -788 -600 27 145 141 57 -117 -284 -571 -586 -457 -203 -93 271 221 262 148 61 -324 -695 -991 -1081 -1072 -729 -164 -10 263 241 183 244 324 525 485 413 202 288 -31 -200 -134 -474 -364 -272 104 -46 61 -102 -400 -571 -542 -406 -428 -238 -73 -204 -241 -63 -225 -99 -144 52 621 600 699 798 660 467 345 -288 -664 -1037 -889 -760 -647 -266 -28 -8 -391 -382 -527 -394 -328 -47 113 246 589 812 815 529 511 -30 -176 -123 171 259 452 324 214 289 -16 -159 -174 -162 -532 -432 -316 -437 44 413 320 231 244 206 515 706 757 441 137 -185 -585 -483
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SQ 20250823T111524.2Z 9366.469030 67 1 29.94 2 83.14 80.96 85.94 78.66 0.00 1 0.00 1 0 22 3.440e-03 3.393e-03 1.628e-03 1.622e-03 1.323501e+04 1.127127e+02 8.730612e+02 -6.000000e+00 1.850841e+02 286.82 -2.00 20.00 -2.00 505.32 0.00e+00 1.550944e-03 4.422354e-05 9.796323e-05 -6.000000e+00 9.559521e-05 286.82 -2.00 20.00 -2.00 500.56 0.00e+00 7.416539e-01 3.142933e-02 8.055360e-02 -6.000000e+00 6.681607e-02 231.19 -2.00 3.57 -2.00 502.12 0.00e+00 7.650 0.009 489.00 513.00 1 6.7087e+00 2.4033e-03 1.2994e-02 -6.0000e+00 5.1141e-03 -7.5748e-03 6.1815e-04 2.0770e-03 -6.0000e+00 1.3493e-03 7.4429e-04 -7.3122e-05 1.2751e-04 9.4396e-05 -6.0000e+00 2.9352e-04 -3.1615e-02 5.9076e-05 11 1 0 11 8 0 14.03 22.35 0.89 -0.03161 -0.03212 9 9 1 4 0 3326.340 29.50 14.99 22.35 25.46 1.4 979.33 900000 -707 -434 -70 -35 111 320 449 180 460 361 380 -258 -235 -20 -456 -233 208 -47 278 237 369 32 178 567 544 394 390 -76 -322 -180 -472 -334 -39 -8 143 151 149 -288 -546 -52 -598 -66 77 122 -37 485 536 -75 -136 -456 -940 -456 -639 -224 -145 -159 -65 111 57 300 483 310 694 231 29 31 -132 -197 77 -300 -219 -30 125 -61 -149 109 -116 -394 -352 -614 -498 -420 -336 -153 -125 257 -136 -150 -304 -248 904 109 459 388 88 410 370 -430 -374 -815 -555 -505 -166 -409 34 -266 -297 -230 -402 -132 -101 416 507 336 641 377 627 285 151 -74 156 106 -55 9 74 464 175 271 15 -284 95 222 -220 -550 -413 -331 315 187 188 329 22 266 316 305 19 -242 97 -521 -418 -102 900000 -652 -411 -69 -36 110 321 458 185 468 362 375 -253 -239 -20 -459 -236 203 -47 286 246 382 33 185 591 571 414 408 -79 -322 -173 -454 -324 -39 -8 152 161 156 -300 -563 -53 -618 -69 81 131 -40 520 569 -79 -140 -458 -919 -434 -606 -216 -145 -164 -68 117 59 314 505 328 734 244 30 32 -134 -198 77 -293 -213 -29 124 -61 -151 109 -113 -380 -336 -585 -477 -406 -326 -150 -125 257 -136 -150 -301 -246 894 110 469 391 86 386 336 -383 -326 -704 -481 -451 -156 -407 33 -261 -287 -231 -402 -127 -99 409 501 332 634 377 637 294 155 -75 153 102 -53 9 72 452 171 265 14 -279 92 209 -206 -515 -389 -318 310 186 190 338 23 278 332 321 20 -253 100 -523 -413 -100
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