File name: Pandora284s1_Downsview_20250923_L2Fit_fout2c2d20241105p1-8.txt File generation date: 20250924T061503.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Vitali Fioletov Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 284 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora284_OF_v3d20240708.txt Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt Level 1 file used: Pandora284s1_Downsview_20250923_L1_smca1c2d20241105p1-8.txt Full location name: Environment Canada HQ - Downsview Short location name: Downsview Country of location: Canada Location latitude [deg]: 43.7810 Location longitude [deg]: -79.4680 Location altitude [m]: 187 Local noon date: 20250923 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based off of session 1 First and last pixel inside fitting window: 195 338 Nominal wavelengths inside fitting window [nm]: 305.0011 305.1417 305.2823 305.4229 305.5635 305.7040 305.8446 305.9851 306.1256 306.2662 306.4067 306.5471 306.6876 306.8281 306.9686 307.1090 307.2494 307.3899 307.5303 307.6707 307.8111 307.9515 308.0918 308.2322 308.3725 308.5129 308.6532 308.7935 308.9338 309.0741 309.2144 309.3547 309.4949 309.6352 309.7754 309.9156 310.0559 310.1961 310.3363 310.4764 310.6166 310.7568 310.8969 311.0371 311.1772 311.3173 311.4574 311.5975 311.7376 311.8777 312.0177 312.1578 312.2978 312.4378 312.5779 312.7179 312.8579 312.9978 313.1378 313.2778 313.4177 313.5577 313.6976 313.8375 313.9774 314.1173 314.2572 314.3970 314.5369 314.6768 314.8166 314.9564 315.0962 315.2360 315.3758 315.5156 315.6554 315.7951 315.9349 316.0746 316.2143 316.3541 316.4938 316.6335 316.7731 316.9128 317.0525 317.1921 317.3317 317.4714 317.6110 317.7506 317.8902 318.0297 318.1693 318.3089 318.4484 318.5879 318.7275 318.8670 319.0065 319.1460 319.2854 319.4249 319.5644 319.7038 319.8432 319.9827 320.1221 320.2615 320.4009 320.5402 320.6796 320.8189 320.9583 321.0976 321.2369 321.3762 321.5155 321.6548 321.7941 321.9333 322.0726 322.2118 322.3511 322.4903 322.6295 322.7687 322.9079 323.0470 323.1862 323.3253 323.4645 323.6036 323.7427 323.8818 324.0209 324.1600 324.2990 324.4381 324.5771 324.7162 324.8552 324.9942 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-387: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250923T125111.3Z 9397.535547 98 1 30.39 2 72.28 108.30 91.92 103.41 0.00 1 0.00 1 0 25 5.378e-02 6.613e-03 4.643e-02 3.703e-03 3.976562e-01 1.857112e-03 4.751559e-03 -6.000000e+00 3.030472e-02 228.09 -2.00 3.57 -2.00 319.42 0.00e+00 1.224808e-03 4.964884e-04 3.141233e-04 -6.000000e+00 1.345182e-03 283.87 -2.00 20.00 -2.00 318.68 0.00e+00 3.240 0.001 302.00 328.00 3 3.6522e+00 5.2433e-03 3.8006e-02 -6.0000e+00 7.5332e-02 2.8418e-02 6.1542e-03 2.1124e-02 -6.0000e+00 8.1901e-02 -9.4071e-03 4.7274e-03 1.0482e-02 -6.0000e+00 4.8789e-02 -2.7299e-03 2.4854e-03 3.1054e-03 -6.0000e+00 2.0750e-02 3.6115e-04 -7.5715e-04 1.0584e-04 3.2949e-05 -6.0000e+00 1.4063e-03 -2.9688e-02 6.8744e-06 11 9 0 11 8 0 99.98 21.96 0.52 -0.02969 -0.03538 35 35 1 5 0 868.220 29.25 15.00 21.96 25.77 1.3 979.90 900000 -39318 9652 -22137 1938 5572 21398 -9903 6755 5300 -6000 -9597 -18123 -16199 -3411 -3568 2505 -8072 -1949 165 4683 6443 4254 -4121 30 -3701 -1053 2041 -5230 87 -1951 3932 5019 -1703 445 -4092 -2144 -2487 -2847 1897 -290 1506 -399 -584 -267 -230 -871 -1006 -1205 -738 99 1159 902 -119 2243 -1748 337 -368 729 714 878 -959 1180 2063 3313 2003 -1236 -1410 -1066 956 2410 231 1045 1457 1096 -1506 -805 -1898 -265 -1700 -1266 -173 -1391 -2244 -1183 -1330 270 63 734 729 499 495 526 -162 -26 -543 -352 396 852 370 -644 -348 -994 -833 -780 -537 -85 -1013 -608 586 656 1043 516 437 99 -227 -172 -133 -278 -496 136 -356 -357 552 645 265 -223 200 129 223 49 31 -110 199 -340 -23 -47 340 215 185 10 7 -398 -396 900000 -1306 216 -696 44 111 363 -254 168 149 -197 -329 -746 -784 -175 -216 160 -612 -149 13 369 505 340 -375 3 -386 -111 207 -538 8 -195 417 595 -240 62 -559 -290 -379 -522 404 -73 409 -116 -176 -81 -70 -271 -311 -373 -229 32 399 340 -49 950 -799 155 -175 338 324 396 -460 607 1167 1999 1222 -727 -790 -600 583 1506 160 745 1019 731 -947 -495 -1085 -147 -1048 -899 -126 -1139 -1983 -1088 -1316 282 70 822 812 532 488 476 -138 -22 -509 -372 468 1123 476 -820 -447 -1167 -922 -899 -671 -111 -1404 -813 828 1007 1707 867 712 152 -323 -233 -181 -399 -763 219 -580 -568 845 948 373 -329 281 186 322 77 53 -192 356 -643 -46 -92 677 437 377 20 14 -778 -758 SS 20250923T130614.4Z 9397.545999 104 1 29.91 2 69.72 111.22 89.40 105.98 0.00 1 0.00 1 0 17 2.014e-02 5.512e-03 4.634e-03 9.242e-04 3.546603e-01 4.616012e-04 4.264399e-03 -6.000000e+00 1.135114e-02 228.09 -2.00 3.57 -2.00 318.11 0.00e+00 7.675118e-04 8.344614e-05 2.473150e-04 -6.000000e+00 5.037064e-04 283.87 -2.00 20.00 -2.00 317.34 0.00e+00 2.856 0.000 302.00 328.00 3 1.9557e+00 1.2402e-03 3.3532e-02 -6.0000e+00 2.8217e-02 8.1594e-03 1.4088e-03 1.8591e-02 -6.0000e+00 3.0675e-02 -9.6992e-03 9.0735e-04 9.1099e-03 -6.0000e+00 1.8273e-02 9.8638e-05 4.6858e-04 2.5822e-03 -6.0000e+00 7.7736e-03 3.0288e-03 -3.8790e-04 2.5688e-05 2.7106e-05 -6.0000e+00 5.2658e-04 -3.0483e-02 4.5702e-05 10 0 0 10 0 0 98.71 21.95 0.37 -0.03048 -0.03340 101 101 1 5 0 296.070 29.25 14.99 21.95 26.11 1.3 981.41 900000 -4566 -4208 -4893 -10010 -9486 -6317 -7923 -3539 -2763 -5094 -4865 -5439 -2561 -1506 -1011 -561 1204 149 1249 727 175 678 364 278 -974 -1109 -1010 -2002 -2037 -619 618 1128 213 -1723 -2576 -3242 -1622 -425 437 416 -365 -203 -172 -292 649 -4 -727 -429 -113 436 1162 1139 1135 886 1053 1275 561 630 174 452 1083 1376 1780 1574 492 -27 -498 7 653 657 881 436 156 84 -350 -576 -1512 -1263 -1259 -1267 -1202 -1496 -1818 -1610 -842 -448 -140 325 483 527 524 136 -19 23 22 107 608 383 -15 -292 -571 -793 -387 -490 -692 -598 -588 -269 286 479 660 620 482 22 21 52 9 196 71 90 -72 163 275 438 256 -102 292 394 169 300 -16 -116 -152 -15 -99 -187 304 60 -45 -69 -326 -231 -305 900000 -279 -279 -331 -653 -555 -357 -501 -246 -211 -414 -393 -480 -259 -179 -139 -85 190 23 199 122 30 114 64 53 -199 -236 -212 -397 -386 -119 130 264 56 -461 -647 -826 -456 -141 161 177 -170 -91 -80 -137 302 -2 -341 -199 -52 207 592 630 670 516 633 787 355 395 107 276 687 950 1349 1198 375 -20 -360 5 480 552 752 387 137 70 -289 -426 -1109 -905 -982 -1060 -1069 -1479 -1810 -1682 -938 -503 -165 391 577 602 586 140 -19 23 23 117 745 497 -19 -394 -719 -962 -443 -587 -855 -778 -802 -365 412 710 1039 991 746 32 29 73 12 276 108 137 -111 245 403 644 359 -144 393 541 241 441 -26 -187 -240 -25 -167 -333 552 111 -84 -125 -566 -400 -518 SS 20250923T131548.9Z 9397.552650 107 1 30.05 2 68.13 113.13 87.82 107.64 0.00 1 0.00 1 0 17 1.676e-02 5.670e-03 2.674e-03 7.136e-04 3.311625e-01 3.557857e-04 4.004295e-03 -6.000000e+00 9.442484e-03 228.09 -2.00 3.57 -2.00 317.63 0.00e+00 6.945651e-04 5.589895e-05 1.733392e-04 -6.000000e+00 4.190615e-04 283.87 -2.00 20.00 -2.00 316.86 0.00e+00 2.660 0.000 302.00 328.00 3 1.7130e+00 9.4589e-04 3.1239e-02 -6.0000e+00 2.3472e-02 4.3894e-03 1.0687e-03 1.7306e-02 -6.0000e+00 2.5518e-02 -1.0183e-02 6.5857e-04 8.4821e-03 -6.0000e+00 1.5201e-02 1.4122e-03 3.3235e-04 2.3995e-03 -6.0000e+00 6.4661e-03 4.8067e-03 -4.4614e-04 1.9730e-05 2.4858e-05 -6.0000e+00 4.3810e-04 -3.0380e-02 2.3780e-05 11 1 0 11 8 0 94.42 21.95 0.30 -0.03038 -0.03373 144 144 1 5 0 208.670 29.25 15.00 21.95 26.75 1.3 984.97 900000 -2337 -3238 -3447 -6343 -6179 -8259 -4875 -2895 -2811 -4202 -6594 -3735 -3287 -1076 431 -16 16 602 842 702 251 542 974 652 208 -235 -646 -1414 -1456 -284 549 1410 487 -1576 -3301 -3114 -1706 -396 472 437 -138 -19 -181 78 536 78 -222 -173 -306 450 797 1090 1066 874 743 921 453 496 153 720 981 1519 1891 1468 788 -46 -723 -126 423 581 531 179 248 71 -177 -471 -1454 -1383 -1166 -1136 -1159 -1642 -1939 -1477 -1145 -471 -206 295 489 421 529 140 -3 102 42 42 384 485 73 -248 -473 -814 -485 -440 -719 -607 -577 -267 385 577 566 605 423 38 -15 171 122 228 116 54 60 131 229 324 251 -37 316 476 355 259 11 -20 -147 -75 -40 -98 225 74 -73 -49 -328 -363 -430 900000 -200 -303 -326 -563 -492 -668 -419 -279 -300 -470 -750 -445 -457 -157 72 -3 3 122 178 155 56 120 224 161 55 -64 -175 -361 -353 -70 147 416 146 -485 -959 -909 -551 -151 199 214 -68 -10 -96 42 286 42 -118 -91 -160 240 457 674 655 569 500 635 320 346 105 489 694 1092 1487 1167 623 -36 -536 -93 341 502 470 165 225 65 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