File name: Pandora284s1_Downsview_20260117_L2Fit_fwvt1c2d20241105p1-8.txt
File generation date: 20260118T053535.8Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c2p1-8
Local principal investigator: Vitali Fioletov
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 284
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora284_OF_v3d20240708.txt
Instrument calibration file used: Pandora284s1_CF_v2d20241105.txt
Level 1 file used: Pandora284s1_Downsview_20260117_L1_smca1c2d20241105p1-8.txt
Full location name: Environment Canada HQ - Downsview
Short location name: Downsview
Country of location: Canada
Location latitude [deg]: 43.7810
Location longitude [deg]: -79.4680
Location altitude [m]: 187
Local noon date: 20260117
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: OoB session based off of session 1
First and last pixel inside fitting window: 1618 1768
Nominal wavelengths inside fitting window [nm]: 492.0083 492.1292 492.2500 492.3709 492.4917 492.6125 492.7332 492.8540 492.9747 493.0955 493.2162 493.3369 493.4575 493.5782 493.6988 493.8194 493.9401 494.0606 494.1812 494.3018 494.4223 494.5428 494.6633 494.7838 494.9043 495.0248 495.1452 495.2656 495.3860 495.5064 495.6268 495.7472 495.8675 495.9878 496.1081 496.2284 496.3487 496.4689 496.5892 496.7094 496.8296 496.9498 497.0700 497.1901 497.3102 497.4304 497.5505 497.6706 497.7906 497.9107 498.0307 498.1507 498.2707 498.3907 498.5107 498.6306 498.7506 498.8705 498.9904 499.1103 499.2301 499.3500 499.4698 499.5896 499.7094 499.8292 499.9490 500.0687 500.1885 500.3082 500.4279 500.5475 500.6672 500.7869 500.9065 501.0261 501.1457 501.2653 501.3848 501.5044 501.6239 501.7434 501.8629 501.9824 502.1018 502.2213 502.3407 502.4601 502.5795 502.6989 502.8182 502.9376 503.0569 503.1762 503.2955 503.4148 503.5340 503.6533 503.7725 503.8917 504.0109 504.1300 504.2492 504.3683 504.4874 504.6065 504.7256 504.8447 504.9637 505.0828 505.2018 505.3208 505.4398 505.5587 505.6777 505.7966 505.9155 506.0344 506.1533 506.2721 506.3910 506.5098 506.6286 506.7474 506.8662 506.9849 507.1037 507.2224 507.3411 507.4598 507.5785 507.6971 507.8158 507.9344 508.0530 508.1716 508.2901 508.4087 508.5272 508.6458 508.7643 508.8827 509.0012 509.1196 509.2381 509.3565 509.4749 509.5933 509.7116 509.8300 509.9483
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20260117T204157.5Z 9513.862471 311 1 5.95 2 78.20 225.71 89.82 230.53 0.00 1 0.00 1 0 15 2.553e-03 2.538e-03 1.134e-04 1.133e-04 1.790679e+03 6.055187e+00 1.390560e+02 -6.000000e+00 1.293610e+02 271.77 -2.00 20.00 -2.00 505.29 0.00e+00 1.238618e-03 2.975916e-06 6.569999e-05 -6.000000e+00 6.837400e-05 271.77 -2.00 20.00 -2.00 500.61 0.00e+00 6.762975e-01 2.172394e-03 1.732299e-02 -6.000000e+00 4.952861e-02 223.49 -2.00 3.57 -2.00 502.18 0.00e+00 4.739 0.002 489.00 513.00 1 6.7179e-01 1.6539e-04 6.9504e-03 -6.0000e+00 3.7736e-03 -1.2593e-02 4.3481e-05 5.1643e-04 -6.0000e+00 9.9826e-04 4.8410e-01 1.6244e-04 9.4604e-06 2.8573e-05 -6.0000e+00 2.1758e-04 -1.9575e-02 -1.2055e-05 10 0 0 10 0 0 26.02 20.86 0.85 -0.01958 -0.01845 566 54 1 4 0 10.500 28.50 15.00 20.86 6.11 2.1 893.13 900000 -617 -343 -194 156 269 333 407 330 293 162 16 -78 -195 -272 -239 -51 43 34 176 209 164 193 288 251 396 393 295 9 -60 -367 -415 -151 -47 25 149 154 -72 -169 -237 -222 -184 -21 88 178 242 218 215 94 -124 -247 -534 -608 -483 -364 -150 -45 112 54 99 116 183 285 271 273 161 131 30 -142 -182 -254 -295 -146 4 -46 -74 -53 -181 -325 -380 -352 -387 -321 -161 -215 -82 -54 -47 -71 -81 30 173 203 241 363 286 151 42 -252 -388 -559 -514 -326 -286 -237 -83 -137 -274 -265 -285 -226 -44 125 234 368 539 560 480 390 363 190 122 229 108 111 268 157 147 272 175 45 76 -17 -221 -160 -169 -242 -77 95 85 70 160 153 207 222 158 -3 -142 -274 -400 -415 900000 -591 -328 -193 156 274 337 419 342 301 164 16 -79 -194 -267 -235 -50 44 35 183 218 170 201 300 256 406 402 301 10 -60 -364 -410 -151 -47 25 155 159 -74 -170 -243 -227 -189 -21 89 184 252 227 221 95 -127 -245 -530 -590 -466 -358 -148 -45 114 55 101 117 185 291 278 279 163 130 30 -141 -178 -246 -285 -142 4 -46 -72 -52 -176 -312 -362 -336 -372 -312 -157 -211 -82 -53 -45 -69 -79 29 171 205 240 371 288 150 41 -244 -368 -536 -494 -311 -277 -240 -82 -135 -274 -260 -278 -224 -44 125 237 376 552 576 486 395 372 192 121 229 105 110 267 156 146 269 174 45 75 -16 -215 -154 -164 -239 -76 95 87 71 161 155 211 227 161 -3 -144 -271 -388 -404
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SQ 20260117T204209.5Z 9513.862610 311 3 5.95 2 78.22 225.75 89.85 230.57 0.00 1 0.00 1 0 15 2.550e-03 2.533e-03 1.139e-04 1.138e-04 1.802840e+03 6.075308e+00 1.395690e+02 -6.000000e+00 1.292377e+02 271.77 -2.00 20.00 -2.00 505.28 0.00e+00 1.230158e-03 2.988984e-06 6.547450e-05 -6.000000e+00 6.830995e-05 271.77 -2.00 20.00 -2.00 500.61 0.00e+00 6.794701e-01 2.178273e-03 1.739446e-02 -6.000000e+00 4.948377e-02 223.49 -2.00 3.57 -2.00 502.17 0.00e+00 4.749 0.002 489.00 513.00 1 6.8015e-01 1.6587e-04 6.9633e-03 -6.0000e+00 3.7701e-03 -1.2724e-02 4.3679e-05 5.1790e-04 -6.0000e+00 9.9740e-04 4.7936e-01 2.4157e-04 9.5093e-06 2.8605e-05 -6.0000e+00 2.1739e-04 -1.9700e-02 -1.4437e-05 10 0 0 10 0 0 31.10 20.86 0.85 -0.01970 -0.01802 566 54 1 4 0 10.500 28.50 15.00 20.86 6.11 2.1 893.13 900000 -574 -352 -169 174 278 348 407 334 303 174 17 -75 -203 -251 -259 -84 58 65 175 200 150 189 284 260 377 395 277 6 -72 -379 -406 -170 -49 5 153 167 -82 -156 -214 -230 -206 -23 75 179 233 213 188 100 -126 -240 -540 -588 -470 -380 -173 -11 101 48 145 121 196 286 275 252 182 102 36 -167 -211 -232 -296 -151 -9 -37 -63 -51 -178 -323 -422 -346 -404 -319 -172 -216 -59 -62 -35 -109 -71 29 161 182 226 373 255 153 53 -236 -387 -573 -526 -340 -289 -214 -74 -146 -269 -242 -281 -239 -31 117 238 382 536 562 460 394 377 199 124 231 90 115 250 155 130 284 198 38 86 3 -246 -159 -166 -233 -64 97 68 65 146 154 232 223 155 9 -145 -261 -402 -406 900000 -547 -335 -167 173 282 351 417 344 310 175 18 -76 -201 -246 -254 -83 59 66 181 207 155 196 295 272 385 403 289 6 -72 -375 -399 -169 -49 6 158 172 -83 -162 -218 -234 -210 -24 76 184 242 221 193 101 -129 -238 -534 -569 -452 -373 -171 -11 102 49 146 121 198 291 281 257 183 104 36 -165 -206 -224 -284 -146 -9 -37 -63 -50 -173 -308 -412 -337 -387 -308 -167 -212 -58 -62 -35 -108 -71 29 159 183 231 379 256 151 53 -228 -365 -547 -503 -323 -279 -216 -74 -147 -268 -237 -274 -236 -31 117 240 388 547 577 476 407 385 200 122 231 90 114 248 153 129 280 196 38 85 3 -239 -153 -160 -229 -63 97 69 65 147 155 235 227 158 9 -147 -257 -389 -394
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