File name: Pandora108s1_Egbert_20180531_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T083022.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v2d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20180531_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20180531 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180531T094555.0Z 6725.406887 239 1 32.01 2 89.78 58.83 77.64 223.25 0.00 1 0.00 1 0 22 3.353e-02 3.314e-02 3.988e-02 3.937e-02 2.723021e+04 3.398242e+03 1.729281e+03 -6.000000e+00 1.908835e+03 281.87 -2.00 20.00 -2.00 505.50 0.00e+00 2.795595e-03 1.103374e-03 1.560492e-04 -6.000000e+00 9.471549e-04 281.87 -2.00 20.00 -2.00 500.38 0.00e+00 1.699864e+00 8.061511e-01 1.661453e-01 -6.000000e+00 6.739933e-01 231.87 -2.00 3.58 -2.00 502.03 0.00e+00 20.156 0.161 489.00 513.00 1 8.9216e+00 6.1877e-02 3.8689e-02 -6.0000e+00 5.1770e-02 5.4322e-02 1.4905e-02 4.6466e-03 -6.0000e+00 1.3234e-02 1.2965e-05 2.5339e-03 3.5256e-03 1.0382e-04 -6.0000e+00 3.6970e-03 -1.6222e-02 7.7748e-05 12 8 8 10 0 0 -240.16 19.97 1.55 -0.01622 0.00135 8 2 1 4 0 4000.000 24.75 15.00 19.97 313 671 142 -3189 -1882 -4070 1095 -461 3943 -4385 2488 -3224 -261 3127 -2951 5902 -5157 6522 -3627 3421 -2037 1470 -2371 1227 -1972 1468 4734 124 4998 -3234 3037 -4337 2039 1300 -1400 5680 -5351 3750 -2904 1536 -1246 1394 -1819 385 245 -2265 4574 -1702 2584 -1578 4698 -3915 1251 -4894 -2137 4279 -5667 5025 -2051 1687 -1599 5693 -2355 -266 -3906 3849 1652 459 6149 -1404 2123 -2894 4101 -5057 4316 -1071 -607 -1822 -4078 2728 -1557 5006 -3404 5252 -1884 -1076 -1689 2737 4251 1163 5443 -3317 7267 -3420 4280 -928 -1036 -3703 -2283 4379 -5506 4612 -3417 394 1902 2787 1 -1304 1165 -8229 3428 -3675 3209 -4357 2860 1512 1379 1859 1865 -2374 -5058 4936 -4108 5064 -3948 3694 -4281 2890 896 2342 327 -843 1529 -4659 5295 56 4380 646 1080 12 2229 -1674 -4142 -765 -1655 1837 -1311 3282 -5027 -389 1092 287 619 135 -3255 -1954 -4426 1152 -498 4080 -4891 2557 -3460 -268 3071 -3064 5631 -5572 6405 -4033 3600 -2279 1594 -2678 1343 -2241 1617 5032 137 5137 -3516 3046 -4686 2103 1391 -1581 6057 -5833 4038 -3035 1665 -1274 1398 -1907 400 257 -2454 4618 -1812 2592 -1613 4395 -3903 1170 -4894 -2123 4100 -6141 4961 -2183 1730 -1697 5638 -2537 -280 -4245 3824 1652 457 5714 -1391 2014 -2884 3837 -5236 4093 -1068 -593 -1770 -3986 2465 -1462 4410 -3283 4694 -1830 -1044 -1651 2543 3854 1080 4848 -3242 6402 -3310 3716 -812 -866 -3060 -1813 3210 -4461 3455 -2900 341 1706 2563 1 -1266 1101 -8573 3207 -3722 3044 -4455 2722 1468 1361 1859 1883 -2488 -5350 4619 -4134 4624 -3961 3457 -4364 2750 870 2237 317 -816 1430 -4629 4801 54 4155 648 1098 13 2315 -1830 -4674 -836 -1819 1937 -1412 3335 -5495 -405 1130 SO 20180531T094958.5Z 6725.409705 243 1 6.94 2 89.16 59.53 78.13 224.05 0.00 1 0.00 1 0 29 1.095e-02 1.068e-02 3.654e-03 3.620e-03 3.673777e+04 3.086533e+02 2.355403e+03 -6.000000e+00 6.232597e+02 281.87 -2.00 20.00 -2.00 505.55 0.00e+00 4.485819e-03 1.017918e-04 2.849653e-04 -6.000000e+00 3.092561e-04 281.87 -2.00 20.00 -2.00 501.11 0.00e+00 1.126775e+00 7.141409e-02 2.123635e-01 -6.000000e+00 2.200762e-01 231.87 -2.00 3.58 -2.00 502.61 0.00e+00 19.013 0.135 489.00 513.00 1 5.6000e+00 5.4642e-03 3.7754e-02 -6.0000e+00 1.6904e-02 -5.3131e-02 1.3163e-03 5.8744e-03 -6.0000e+00 4.3215e-03 4.2419e-04 2.4347e-03 2.9463e-04 2.2085e-04 -6.0000e+00 1.2073e-03 6.2852e-03 -6.1621e-05 12 9 9 12 1 1 999.00 19.98 5.77 0.00629 0.02317 2 3 1 4 0 2312.583 24.86 15.00 19.98 -1635 -733 321 1138 2131 2824 2631 1938 2766 1857 1602 146 -25 -237 -435 -767 -1014 751 132 480 471 557 487 1012 1351 276 1277 -272 -476 -1474 -595 -1981 -1120 -1357 -349 431 133 -61 -1393 -671 -711 81 5 333 653 442 1254 -741 244 -1469 -1211 -2228 -1962 -2492 -1282 -667 9 426 127 1176 148 1685 -113 786 -40 374 342 -235 -610 -1400 -302 -1299 28 -945 9 -479 -677 -894 -1005 -696 -865 -13 -662 192 -687 -536 -1422 -1022 106 -407 672 217 957 341 1127 436 724 -279 -1029 -1818 -3093 -1712 -1817 -1201 -1484 319 -697 -79 -350 -251 -783 -807 470 178 1511 1622 2463 1536 769 -278 -252 70 -356 1562 1046 2464 1314 1195 -216 -61 -416 -646 -720 -478 -692 -972 887 12 993 631 739 -57 518 839 957 1240 646 473 -929 -1058 -869 -1405 -632 283 1031 1972 2664 2379 1786 2531 1702 1455 133 -23 -211 -388 -689 -928 691 125 460 455 540 475 989 1327 276 1261 -271 -466 -1421 -559 -1894 -1082 -1356 -356 442 137 -62 -1436 -685 -729 83 5 331 657 449 1265 -756 243 -1460 -1246 -2268 -1975 -2540 -1244 -663 9 436 132 1207 154 1739 -119 825 -42 389 350 -239 -615 -1408 -299 -1298 27 -960 9 -486 -678 -882 -977 -667 -826 -13 -637 185 -678 -534 -1429 -1014 103 -393 643 210 919 324 1088 402 631 -236 -854 -1506 -2606 -1463 -1637 -1149 -1426 314 -708 -80 -357 -257 -816 -849 489 185 1553 1678 2579 1571 805 -294 -262 75 -375 1603 1085 2543 1385 1268 -220 -62 -422 -650 -720 -478 -702 -1007 921 13 1069 696 831 -66 598 966 1098 1409 733 532 -1054 -1204 -998 SO 20180531T095424.0Z 6725.412778 247 1 32.01 2 88.47 60.29 78.67 224.92 0.00 1 0.00 1 0 22 9.582e-03 9.365e-03 7.411e-03 7.350e-03 3.291199e+04 6.389569e+02 2.121674e+03 -6.000000e+00 5.455073e+02 281.87 -2.00 20.00 -2.00 505.53 0.00e+00 3.100265e-03 2.065183e-04 2.026457e-04 -6.000000e+00 2.706230e-04 281.87 -2.00 20.00 -2.00 500.84 0.00e+00 1.405675e+00 1.471738e-01 1.878218e-01 -6.000000e+00 1.924435e-01 231.87 -2.00 3.58 -2.00 502.38 0.00e+00 17.310 0.102 489.00 513.00 1 7.5792e+00 1.1231e-02 3.2554e-02 -6.0000e+00 1.4784e-02 -1.4755e-02 2.7357e-03 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