File name: Pandora108s1_Egbert_20180830_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T085159.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v2d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20180830_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20180830 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20180830T104611.0Z 6816.448738 284 1 32.00 2 89.73 77.77 53.09 230.88 0.00 1 0.00 1 0 15 9.975e-02 9.384e-02 1.123e-01 1.084e-01 3.807411e+03 7.652200e+03 3.554833e+01 -6.000000e+00 5.760286e+03 285.58 -2.00 20.00 -2.00 505.27 0.00e+00 1.693192e-03 3.073822e-03 8.794385e-05 -6.000000e+00 2.849572e-03 285.58 -2.00 20.00 -2.00 499.78 0.00e+00 2.862454e+00 2.284306e+00 7.895222e-02 -6.000000e+00 2.013821e+00 230.52 -2.00 3.58 -2.00 501.47 0.00e+00 19.986 0.157 489.00 513.00 1 9.9634e+00 1.7539e-01 3.5859e-02 -6.0000e+00 1.5465e-01 1.3015e-01 4.4397e-02 2.2857e-03 -6.0000e+00 3.9967e-02 4.4992e-06 -5.4126e-03 1.1264e-02 4.5752e-05 -6.0000e+00 1.1058e-02 -4.3798e-02 5.2320e-04 12 8 8 10 0 0 77.92 19.35 3.80 -0.04380 -0.08134 8 2 1 4 0 4000.000 24.14 15.00 19.35 -1832 -6761 4154 -8853 -4222 -3537 8853 -10101 2964 8396 -6668 7403 -9642 13356 -9315 21239 -2147 10831 12082 1030 -2448 -1412 20609 -5091 5197 -7660 16954 457 7183 856 -6460 110 -12032 5000 -13529 9084 -12998 19555 -192 17456 -534 -148 5091 -7234 16366 -361 12518 -7469 -2761 -16164 -14359 -3591 -2445 16757 -2503 6592 -9540 6404 -8655 15336 -3202 18428 1413 -6339 11664 1920 8732 -8334 18127 397 2248 -9074 12647 8284 -3534 3648 4261 8651 -5569 6482 -10140 7748 151 -119 9791 -10572 7579 -11235 19373 -7905 9908 -10021 7692 -2470 -12689 8767 -539 877 -5572 31075 -5487 5814 -11003 18195 -5301 477 15695 -7455 13773 -12715 2109 -7716 23301 162 4734 24517 12866 -3202 -7910 13755 -16212 9855 -966 2885 -9720 3593 -7481 -8388 9687 -5188 -2975 -7776 11787 3222 17372 -2191 4459 4308 -4510 -3239 -13408 9752 -7290 1974 -6848 1430 9792 2893 2071 2199 900000 -1858 -7246 4092 -10258 -4810 -4098 9232 -12874 3320 8837 -8048 7649 -11638 12638 -10974 18457 -2384 10772 12133 1174 -2907 -1663 19502 -6243 5771 -9690 16698 525 7560 933 -7423 118 -14755 5311 -17766 9649 -17195 18505 -219 16518 -603 -167 5505 -8941 16119 -422 12813 -9231 -3199 -19171 -16268 -3884 -2573 14562 -2683 6619 -10555 6678 -9653 14660 -3373 17082 1425 -6901 11488 1886 7883 -8778 15753 373 2049 -9237 10411 7185 -3472 3326 3809 7274 -5324 5451 -10052 6446 136 -109 8146 -10854 6507 -11634 14747 -7906 8331 -10378 6740 -2405 -13590 7449 -491 768 -5080 19254 -4857 4632 -10615 13528 -5115 440 12364 -7324 10850 -13055 1885 -7717 17324 154 4316 18446 10932 -3202 -8261 11444 -17937 8287 -898 2579 -9894 3212 -7483 -8464 8146 -5051 -2818 -7640 9389 2767 12916 -1997 3868 3813 -4431 -3183 -14716 8546 -7614 1887 -7152 1367 8493 2637 1870 1966 900000 SO 20180830T105028.0Z 6816.451713 288 1 32.00 2 88.98 78.51 53.67 231.97 0.00 1 0.00 1 0 22 5.247e-02 5.047e-02 6.983e-02 6.829e-02 2.759967e+03 4.691785e+03 1.998776e+02 -6.000000e+00 3.028465e+03 285.58 -2.00 20.00 -2.00 505.29 0.00e+00 1.769733e-03 1.925056e-03 9.873066e-05 -6.000000e+00 1.496163e-03 285.58 -2.00 20.00 -2.00 499.82 0.00e+00 2.830690e+00 1.427857e+00 2.281335e-02 -6.000000e+00 1.050281e+00 230.52 -2.00 3.58 -2.00 501.51 0.00e+00 18.518 0.125 489.00 513.00 1 9.6996e+00 1.0996e-01 3.1174e-02 -6.0000e+00 8.0802e-02 1.1621e-01 2.7380e-02 1.7695e-03 -6.0000e+00 2.0622e-02 7.2557e-06 7.9727e-03 7.1740e-03 3.9959e-05 -6.0000e+00 5.7868e-03 -2.5497e-04 -1.2763e-05 12 8 8 10 0 0 70.83 19.35 -0.53 -0.00025 0.05505 8 2 1 4 0 4000.000 24.25 15.00 19.35 551 -3841 2741 -3318 1003 -3933 -2395 1429 18 5509 -4181 7840 -2829 6478 -933 264 -3184 1211 466 495 3050 2644 2251 -4225 2368 -8909 4304 -2074 -1350 5714 825 3049 -8087 9188 -4565 4526 -7576 2801 1683 3291 5064 -7697 9044 -2109 5030 -6957 2698 -3532 2579 -26 -2225 841 -2940 10959 -924 1623 -4241 4342 1019 3089 1965 -3812 8614 -3082 -1927 -1752 7727 -1592 4753 -4833 -8918 7335 -26 3260 -6922 7770 -3660 4533 -5201 435 1844 -5010 468 -1854 4476 -1196 6372 -8134 3010 -2198 -1497 -2761 -7497 10437 -529 4990 -6430 10223 459 9171 -9535 3391 -2916 -3028 603 -6191 12325 1381 5976 -5297 13860 -3685 2979 4586 -5738 9570 834 9253 -1722 -4729 -5037 -1510 -108 2590 542 189 -2713 -428 2440 -1493 -1682 -5366 3100 -6346 5087 6328 -1314 8636 -3907 9890 -8672 4930 -2724 -3542 -4823 2823 -3501 -8299 10319 -857 11593 540 -3996 2751 -3654 1086 -4569 -2783 1608 20 5864 -4832 7917 -3132 6463 -999 281 -3564 1326 524 563 3395 2959 2534 -5089 2679 -11273 4739 -2398 -1511 5805 868 3154 -9544 9390 -5471 4984 -9356 3084 1853 3544 5361 -9317 9353 -2463 5508 -8591 3003 -4125 2777 -28 -2382 855 -3076 10067 -978 1718 -4446 4596 1115 3307 1950 -4018 8751 -3214 -1967 -1759 6938 -1545 4267 -4716 -9001 6299 -25 2964 -6986 6716 -3490 3918 -4902 386 1615 -4721 420 -1716 3919 -1114 5507 -8119 2685 -2071 -1411 -2663 -7651 8905 -499 4369 -6167 8095 391 7057 -8826 2798 -2634 -2820 551 -6076 9966 1232 5065 -5051 11052 -3555 2724 4168 -5824 8378 800 8153 -1680 -4694 -4943 -1415 -99 2325 498 175 -2587 -399 2205 -1398 -1566 -5117 2680 -5980 4284 5328 -1216 7368 -3834 8549 -9092 4536 -2719 -3575 -4922 2645 -3436 -8376 8516 -788 9503 SO 20180830T105447.0Z 6816.454711 292 1 32.00 2 88.22 79.26 54.26 233.05 0.00 1 0.00 1 0 15 3.131e-02 3.066e-02 3.647e-02 3.586e-02 5.281581e+03 2.550145e+03 3.137107e+02 -6.000000e+00 1.807210e+03 285.58 -2.00 20.00 -2.00 505.30 0.00e+00 6.467981e-04 1.007862e-03 3.107542e-05 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