File name: Pandora108s1_Egbert_20181028_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T090010.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v3d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20181028_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20181028 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181028T115706.0Z 6875.497986 275 1 32.01 2 89.77 108.82 50.81 259.29 0.00 1 0.00 1 0 22 4.549e-02 4.368e-02 6.538e-02 6.392e-02 4.118303e+03 4.386849e+03 2.091339e+02 -6.000000e+00 2.554598e+03 278.74 -2.00 20.00 -2.00 505.29 0.00e+00 3.624566e-04 1.764316e-03 3.170516e-05 -6.000000e+00 1.275778e-03 278.74 -2.00 20.00 -2.00 499.76 0.00e+00 2.079866e+00 1.330706e+00 4.343167e-02 -6.000000e+00 9.057599e-01 224.12 -2.00 3.58 -2.00 501.47 0.00e+00 20.254 0.163 489.00 513.00 1 9.5008e+00 1.0205e-01 3.6285e-02 -6.0000e+00 6.9568e-02 1.5060e-01 2.5609e-02 2.1578e-03 -6.0000e+00 1.7736e-02 7.5305e-06 1.5359e-03 6.6147e-03 1.2397e-05 -6.0000e+00 5.0139e-03 1.7599e-02 -6.2069e-06 12 8 8 10 0 0 -82.36 19.92 3.61 0.01760 0.02825 8 2 1 4 0 4000.000 24.75 14.99 19.92 -4768 2611 -282 -1386 -212 2517 119 486 -5881 -5433 -2475 -913 4468 -507 -517 1507 -260 -3182 971 1308 331 -3851 -413 2759 -6085 6556 -1108 4571 -3807 1650 -1135 -2601 708 -1601 817 3279 7504 -2710 37 -1320 2594 -1583 -2729 4265 -1577 4571 -1581 10153 -848 2383 -2584 -1239 5550 -2525 1175 -65 6920 -5183 -487 3537 8977 3102 -2503 -729 -5637 6194 -2016 4678 -6052 2573 2920 1151 -3740 -3879 -84 -1732 6582 -4911 5506 1881 1931 -2226 -963 2786 -4845 852 -4445 -63 -1836 10100 -5460 2071 4051 2363 7713 459 927 -5147 2638 -2775 9046 -643 1538 -3335 7270 2176 3358 522 -6935 8259 -10542 8650 -2873 705 -904 5731 -7298 706 2931 -4297 12080 -1217 9973 -1939 5360 7396 -3050 1337 -6688 -5385 -13945 -639 -6586 8087 -5837 3464 -134 -7722 2087 -1764 5858 -3541 9332 -1118 1506 -5150 3178 66 -1618 3603 -1069 -4969 2558 -292 -1500 -233 2751 135 556 -7166 -6527 -2846 -1019 4656 -549 -556 1596 -284 -3660 1095 1490 382 -4649 -482 3127 -7554 7167 -1299 4997 -4422 1766 -1228 -2858 766 -1823 930 3678 8033 -3179 42 -1496 2821 -1803 -3170 4663 -1841 5023 -1837 10348 -947 2510 -2781 -1284 5309 -2631 1204 -69 7014 -5491 -538 3746 8996 3304 -2587 -738 -5943 5723 -1989 4248 -6034 2324 2606 1046 -3592 -3766 -79 -1646 5668 -4666 4656 1640 1683 -2033 -874 2458 -4653 778 -4292 -58 -1725 8435 -5358 1902 3679 2183 6683 419 822 -4728 2190 -2390 6893 -547 1316 -3099 6223 1976 2998 474 -6733 6897 -10730 7359 -2774 663 -868 5175 -7542 674 2723 -4239 9963 -1131 8225 -1802 4644 6292 -2882 1208 -6528 -5172 -14485 -573 -6188 6500 -5393 2947 -120 -7618 1895 -1685 5228 -3493 8134 -1086 1422 -5161 2887 60 -1486 3122 -976 SO 20181028T120121.0Z 6875.500937 279 1 32.00 2 89.05 109.56 51.53 260.11 0.00 1 0.00 1 0 22 4.280e-02 4.191e-02 4.588e-02 4.490e-02 2.389439e+03 2.953823e+03 1.655952e+02 -6.000000e+00 2.403633e+03 278.74 -2.00 20.00 -2.00 505.26 0.00e+00 1.056863e-03 1.237110e-03 2.742820e-05 -6.000000e+00 1.200676e-03 278.74 -2.00 20.00 -2.00 499.75 0.00e+00 2.153190e+00 9.329741e-01 1.487513e-02 -6.000000e+00 8.531662e-01 224.12 -2.00 3.58 -2.00 501.45 0.00e+00 18.856 0.132 489.00 513.00 1 9.3189e+00 7.1490e-02 3.1955e-02 -6.0000e+00 6.5518e-02 1.4355e-01 1.8005e-02 1.7919e-03 -6.0000e+00 1.6725e-02 1.0832e-05 4.5305e-03 4.7073e-03 1.7491e-05 -6.0000e+00 4.7171e-03 -7.5950e-03 6.3693e-05 12 8 8 10 0 0 -195.06 19.88 1.76 -0.00759 0.02383 8 2 1 4 0 4000.000 24.75 15.00 19.88 -4911 -148 -68 2357 -4743 4227 -2662 5533 -3750 5 -1097 -1528 588 -636 328 -7840 4070 -3952 6398 1836 -152 671 2155 635 1276 3673 -2506 4513 -4242 2775 -25 895 2321 -3832 7130 -3992 5633 -818 4466 -7568 2081 -3802 943 -557 -3601 6004 -3449 6256 -1909 6385 -7632 3200 -4930 -133 1976 1839 4618 -1441 7302 -1843 2102 -5562 -177 -837 -1381 4343 -4089 7118 -4133 5666 -6219 3600 -2492 1559 -1120 6726 2310 -971 4500 -5448 4484 -6775 1021 -1846 2180 1163 -1796 2964 -4591 -3223 -2588 7275 -624 6313 -1689 2497 3156 1497 406 -9546 6655 -3124 7274 -4740 -1915 -6745 2203 2680 -4099 3025 -4287 9387 363 3727 -5163 8983 -3580 509 576 -718 5827 -722 5258 -1595 6126 -4164 3826 -1562 3046 2735 -5568 6207 -7163 5991 -8191 3469 -7703 2797 -3278 942 -275 -5026 7535 -2026 8136 -2589 1232 -3951 723 -1899 1218 -5147 -150 -71 2471 -5483 4565 -3130 6043 -4485 6 -1246 -1717 637 -690 350 -9126 4265 -4584 6833 2078 -176 773 2448 734 1470 4129 -2977 4929 -4938 2930 -26 949 2470 -4460 7615 -4806 6129 -939 4806 -9112 2273 -4425 1056 -640 -4292 6509 -4083 6632 -2154 6462 -8639 3175 -5245 -135 2015 1927 4803 -1608 7477 -1892 2261 -5935 -179 -850 -1398 4092 -4123 6316 -4046 4965 -6088 3195 -2367 1435 -1064 5869 2075 -887 3845 -5114 3814 -6484 910 -1706 1951 1058 -1686 2652 -4427 -3072 -2467 6349 -595 5625 -1617 2252 2765 1301 348 -8891 5247 -2749 5921 -4485 -1798 -6678 1980 2368 -3848 2651 -4087 7917 340 3402 -5188 7872 -3570 487 547 -682 5107 -667 4550 -1480 5279 -3985 3381 -1455 2703 2427 -5328 5212 -6776 4921 -7749 2951 -7456 2482 -3137 874 -260 -5013 6659 -1976 7160 -2516 1134 -3752 644 -1727 1081 SO 20181028T120527.0Z 6875.503785 283 1 32.01 2 88.36 110.28 52.23 260.90 0.00 1 0.00 1 0 15 4.363e-02 4.256e-02 3.356e-02 3.286e-02 2.893354e+03 2.177172e+03 1.563555e+02 -6.000000e+00 2.450096e+03 278.74 -2.00 20.00 -2.00 505.26 0.00e+00 6.918217e-04 9.072114e-04 2.884163e-05 -6.000000e+00 1.224070e-03 278.74 -2.00 20.00 -2.00 499.78 0.00e+00 1.728699e+00 6.821945e-01 3.167513e-02 -6.000000e+00 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