File name: Pandora108s1_Egbert_20181112_L2Fit_fout2c5d20180328p1-8.txt File generation date: 20251214T090244.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v3d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20181112_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20181112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 231 373 Nominal wavelengths inside fitting window [nm]: 305.0568 305.1976 305.3385 305.4793 305.6201 305.7609 305.9017 306.0425 306.1833 306.3241 306.4648 306.6056 306.7463 306.8871 307.0278 307.1685 307.3092 307.4499 307.5905 307.7312 307.8719 308.0125 308.1531 308.2937 308.4344 308.5750 308.7155 308.8561 308.9967 309.1372 309.2778 309.4183 309.5588 309.6993 309.8399 309.9803 310.1208 310.2613 310.4017 310.5422 310.6826 310.8231 310.9635 311.1039 311.2443 311.3846 311.5250 311.6654 311.8057 311.9461 312.0864 312.2267 312.3670 312.5073 312.6476 312.7879 312.9281 313.0684 313.2086 313.3488 313.4891 313.6293 313.7695 313.9096 314.0498 314.1900 314.3301 314.4703 314.6104 314.7505 314.8906 315.0307 315.1708 315.3109 315.4509 315.5910 315.7310 315.8711 316.0111 316.1511 316.2911 316.4311 316.5710 316.7110 316.8510 316.9909 317.1308 317.2707 317.4106 317.5505 317.6904 317.8303 317.9702 318.1100 318.2498 318.3897 318.5295 318.6693 318.8091 318.9489 319.0886 319.2284 319.3682 319.5079 319.6476 319.7873 319.9270 320.0667 320.2064 320.3461 320.4857 320.6254 320.7650 320.9047 321.0443 321.1839 321.3235 321.4630 321.6026 321.7422 321.8817 322.0213 322.1608 322.3003 322.4398 322.5793 322.7188 322.8582 322.9977 323.1371 323.2765 323.4160 323.5554 323.6948 323.8342 323.9735 324.1129 324.2522 324.3916 324.5309 324.6702 324.8095 324.9488 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 97-239: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 240-382: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20181112T121925.0Z 6890.513484 503 1 32.01 2 89.44 115.80 134.40 76.79 0.00 1 0.00 1 0 53 9.091e-01 8.842e-01 9.674e-01 8.958e-01 5.761717e-01 5.868993e-01 1.298650e-02 -6.000000e+00 6.423029e-01 222.72 -2.00 3.58 -2.00 311.89 0.00e+00 -9.951569e-03 2.903124e-02 5.241787e-04 -6.000000e+00 3.083714e-02 276.80 -2.00 20.00 -2.00 311.37 0.00e+00 19.765 0.152 302.00 328.00 3 -6.4452e+00 1.4268e+00 2.4201e-01 -6.0000e+00 1.5618e+00 3.6135e+00 1.5445e+00 5.1020e-02 -6.0000e+00 1.7133e+00 -1.0845e+00 9.2884e-01 1.9153e-02 -6.0000e+00 1.0313e+00 1.6058e-01 4.3629e-01 4.6249e-03 -6.0000e+00 4.4550e-01 3.1092e-07 -2.0558e-02 2.7400e-02 2.3230e-04 -6.0000e+00 3.3141e-02 7.4239e-02 -6.0851e-03 12 9 8 11 8 0 -292.27 19.85 -22.91 0.07424 -0.08024 8 2 1 5 0 4000.000 24.65 15.00 19.85 900000 -44572 900000 900000 8237 56640 -24842 50758 -87153 100985 -25539 900000 900000 900000 -14376 173223 900000 -43036 900000 1441 900000 900000 900000 33449 900000 -7183 -44762 900000 900000 900000 -3160 151546 -128651 208782 44197 900000 900000 1541 900000 -66888 900000 -14613 140435 900000 42714 900000 157915 -23295 6830 900000 42547 900000 14378 900000 17202 85482 900000 124190 900000 29446 900000 -99790 900000 -11318 900000 -65148 900000 9696 238819 900000 25645 900000 2142 900000 -71472 900000 29317 900000 207104 -11750 900000 -43117 900000 -47670 900000 -82635 900000 133803 -62282 900000 79186 210452 -47294 900000 -44967 900000 107832 900000 -19804 3525 52924 2275 900000 -25044 900000 10859 900000 -23493 900000 -14720 190932 149476 -45147 900000 -36843 900000 -74102 82550 -47416 900000 -34540 -10801 233040 8008 153158 -82246 78093 -59143 55079 -83455 28102 112900 145972 41550 -42769 900000 -19295 900000 10106 81544 -2221 900000 900000 900000 -38325 900000 900000 7083 48701 -21360 43643 -93671 86830 -21960 900000 900000 900000 -12361 148943 900000 -41938 900000 1239 900000 900000 900000 28760 900000 -6176 -38488 900000 900000 900000 -2717 130304 -235986 179518 38002 900000 900000 1325 900000 -99688 900000 -13463 120750 900000 36727 900000 135780 -20030 5873 900000 36583 900000 12362 900000 14791 73500 900000 106782 900000 25319 900000 -171604 900000 -9732 900000 -72021 900000 8337 205345 900000 22051 900000 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900000 -38453 900000 -41932 900000 -32594 900000 37671 -90474 78023 216856 900000 -21276 900000 -23674 105348 49250 29029 71700 -25026 53907 53675 17553 23922 900000 25091 76148 -64466 -4100 10231 35624 126025 900000 100548 900000 -66 -107207 900000 75723 900000 -14715 900000 -89261 900000 900000 900000 98109 900000 900000 900000 900000 -52864 900000 900000 132105 900000 900000 -20758 -5371 106697 -41983 900000 -61340 -5855 -46096 900000 900000 134523 -79473 -32279 900000 -41425 900000 8380 900000 900000 900000 125567 29879 -85105 -27620 900000 -84993 900000 900000 164747 2353 14735 900000 -56354 900000 -66174 900000 -66662 900000 -60204 -11253 -75225 154433 -17603 -928 -13519 159757 900000 76222 900000 -92334 49151 900000 -32767 -53512 -47484 900000 -79735 900000 62940 900000 -28 146572 28677 30734 60551 42531 900000 -114321 900000 40421 900000 -85786 900000 -127443 -10879 152502 -79397 900000 23408 900000 38317 174765 2513 175565 -33446 -91450 900000 -41987 900000 -51892 900000 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