File name: Pandora108s1_Egbert_20181202_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T090446.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v3d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20181202_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20181202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181202T124234.0Z 6910.529560 375 1 32.01 2 89.78 121.75 46.40 164.23 0.00 1 0.00 1 0 15 9.131e-02 8.587e-02 1.211e-01 1.171e-01 8.258398e+03 8.772657e+03 4.386521e+02 -6.000000e+00 5.040467e+03 274.47 -2.00 20.00 -2.00 505.33 0.00e+00 1.460453e-03 3.225251e-03 6.765347e-05 -6.000000e+00 2.535109e-03 274.47 -2.00 20.00 -2.00 499.85 0.00e+00 1.945895e+00 2.486423e+00 7.035314e-02 -6.000000e+00 1.821660e+00 222.23 -2.00 3.58 -2.00 501.53 0.00e+00 20.401 0.167 489.00 513.00 1 1.0107e+01 1.9049e-01 3.7009e-02 -6.0000e+00 1.3969e-01 1.4163e-01 4.7268e-02 2.4990e-03 -6.0000e+00 3.5724e-02 3.9540e-06 -6.5811e-03 1.1988e-02 2.6929e-05 -6.0000e+00 1.0061e-02 5.4501e-02 -3.6547e-04 12 9 8 11 8 0 25.78 19.99 3.72 0.05450 0.00885 8 2 1 4 0 4000.000 24.86 14.99 19.99 362 8774 -4660 9099 -920 -9995 2788 5809 4604 -10985 6979 -5704 683 -11613 -2559 -5931 9258 1451 -3484 25610 -8830 -395 -5523 8724 -558 2038 4179 12560 38 -8671 14926 -12893 2955 -3709 1537 -6443 4596 1450 3524 -735 -5848 17023 -1866 10632 -1398 4678 -6830 -5496 -12739 6751 4953 -1185 3790 6013 1802 -2520 13097 2518 -44 8303 -985 3985 -2219 5097 -7968 6123 -440 17791 -1937 -2468 -9330 -1607 7684 -4718 9358 -6194 10394 -3075 -4688 19391 5596 -11016 -16013 4174 -9721 8698 -5994 23583 -5467 9569 -2146 5652 6568 -9983 23413 -9452 15547 -7529 14223 -1466 8563 9970 12111 2236 -10159 17182 -2992 7254 4478 435 6557 8648 -6983 -14689 -3902 -18702 6732 -6972 17153 4335 5652 5826 15182 -655 -14512 4404 -9157 13416 -13948 3433 -4931 16863 -7247 -2319 6650 5215 1931 -16289 19380 -209 6253 2650 680 -2213 -1262 -3267 -6699 16769 -9412 12640 -1551 354 7902 -4896 8596 -991 -12090 3027 6205 4999 -13869 7270 -6647 735 -13944 -2779 -6650 8991 1551 -3999 22384 -10992 -454 -6680 9166 -646 2303 4612 12642 42 -10335 13705 -15481 3052 -4191 1696 -7850 5031 1625 3827 -824 -6867 15931 -2125 10795 -1616 5121 -8381 -6599 -16196 6914 5028 -1245 3715 5733 1814 -2714 12373 2690 -49 8430 -1095 4222 -2508 5355 -8819 6271 -440 15707 -1905 -2407 -9637 -1529 7191 -4681 8132 -6297 8862 -2949 -4496 15579 4771 -11108 -17066 3662 -9882 7416 -5946 17401 -5378 8080 -2041 5004 5815 -10476 17467 -9608 11981 -7098 10494 -1238 6459 7438 9035 1907 -10161 13382 -2870 6244 3928 396 5644 7373 -7042 -16137 -3871 -21618 6071 -7259 14062 4016 5097 5158 12073 -607 -15466 3899 -9309 10888 -14865 3068 -4770 12995 -7011 -2111 5506 4404 1710 -17627 14935 -199 5639 2498 658 -2213 -1252 -3294 -6919 13472 -9645 10259 -1449 SO 20181202T124654.1Z 6910.532570 379 1 32.15 2 89.13 122.51 46.22 165.68 0.00 1 0.00 1 0 15 6.754e-02 6.536e-02 9.763e-02 9.485e-02 1.070548e+04 7.232074e+03 5.335694e+02 -6.000000e+00 3.729074e+03 274.47 -2.00 20.00 -2.00 505.32 0.00e+00 -1.689323e-03 2.607785e-03 1.129032e-04 -6.000000e+00 1.875555e-03 274.47 -2.00 20.00 -2.00 499.75 0.00e+00 2.061662e+00 2.002935e+00 1.155668e-01 -6.000000e+00 1.347570e+00 222.23 -2.00 3.58 -2.00 501.46 0.00e+00 19.141 0.138 489.00 513.00 1 1.0098e+01 1.5339e-01 3.4069e-02 -6.0000e+00 1.0334e-01 1.2422e-01 3.7822e-02 2.9171e-03 -6.0000e+00 2.6419e-02 4.9252e-06 2.8374e-03 9.4838e-03 3.6478e-05 -6.0000e+00 7.4408e-03 -1.2941e-02 5.1803e-05 12 8 8 10 0 0 -13.95 19.97 6.91 -0.01294 0.00674 8 2 1 4 0 4000.000 24.86 15.00 19.97 12511 -4260 4225 -3195 1195 -4072 3008 -6137 4231 1961 -31 -4325 -7168 7174 -9630 -4096 -6362 6568 -3233 -3780 -3102 692 3717 -6075 -1722 -11828 8778 -5037 11017 1897 6511 4816 9762 10046 3151 2813 -2556 7573 -6944 6097 -3388 -974 4237 8997 4929 -10595 9995 -2820 7608 2657 9000 -6700 5002 -4755 3690 -3427 -1301 2958 4762 11225 -1083 4559 -6726 535 530 -2342 4871 -3996 -1398 -3453 13315 -1883 6548 -12592 -7470 -1576 -2212 1921 -7809 -2801 -3726 14171 -8149 12067 3985 4002 15388 -4834 -1850 -9784 924 -4126 -430 4069 -9190 21417 -3912 2985 -3210 2853 -4940 9520 -1486 10334 -7004 578 1593 2502 -847 3280 16891 -1993 11620 -2681 -1638 -5948 6198 -4517 6009 4184 -801 5993 -3749 -1553 -1313 1502 -950 1515 413 -5725 257 -7608 9698 -2000 12239 -1339 -1975 3400 843 3143 -5294 6899 -17301 7914 -13615 17082 -4588 3404 -610 -1228 3527 10888 -4427 4141 -3482 1283 -4714 3304 -7467 4647 2187 -35 -5007 -8418 7213 -11391 -4602 -7418 6881 -3824 -4568 -3748 807 4209 -7597 -2066 -15691 9420 -6129 11171 2052 6602 4964 9733 10271 3541 3209 -3067 8126 -8507 6491 -3950 -1110 4619 9426 5414 -13607 10387 -3288 7843 2806 8669 -7359 4818 -5062 3679 -3450 -1429 3149 4990 11002 -1098 4378 -7241 534 526 -2358 4490 -3962 -1331 -3316 11700 -1765 5681 -13361 -7579 -1501 -2091 1711 -7561 -2560 -3434 10975 -7952 9720 3519 3564 12276 -4717 -1749 -10002 852 -4027 -407 3656 -9253 15427 -3515 2427 -2710 2232 -4170 7079 -1278 8244 -6889 537 1468 2267 -788 2921 13214 -1899 9720 -2595 -1573 -5989 5568 -4548 5445 3824 -757 5199 -3542 -1432 -1210 1349 -876 1361 374 -5498 231 -7307 7737 -1781 9479 -1203 -1820 3028 784 2897 -5371 6252 -20100 7172 -15291 14025 -4620 3111 -571 -1151 3168 SO 20181202T125118.0Z 6910.535625 383 1 32.01 2 88.47 123.29 46.05 167.15 0.00 1 0.00 1 0 15 5.987e-02 5.789e-02 7.315e-02 7.191e-02 6.140162e+03 4.955585e+03 4.264334e+02 -6.000000e+00 3.307214e+03 274.47 -2.00 20.00 -2.00 505.33 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