File name: Pandora108s1_Egbert_20181224_L2Fit_fwvt1c5d20180328p1-8.txt File generation date: 20251214T091018.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alexander Cede Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 108 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora108_of_v3d20151204.txt Instrument calibration file used: Pandora108s1_CF_v5d20180328.txt Level 1 file used: Pandora108s1_Egbert_20181224_L1_smca1c5d20180328p1-8.txt Full location name: Center for Atmospheric Research Experiments (CARE) - Egbert Short location name: Egbert Country of location: Canada Location latitude [deg]: 44.2300 Location longitude [deg]: -79.7800 Location altitude [m]: 251 Local noon date: 20181224 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1652 1802 Nominal wavelengths inside fitting window [nm]: 492.0271 492.1480 492.2688 492.3897 492.5106 492.6314 492.7522 492.8730 492.9938 493.1146 493.2354 493.3561 493.4768 493.5975 493.7182 493.8389 493.9595 494.0802 494.2008 494.3214 494.4420 494.5626 494.6831 494.8036 494.9242 495.0447 495.1652 495.2856 495.4061 495.5265 495.6469 495.7674 495.8877 496.0081 496.1285 496.2488 496.3691 496.4894 496.6097 496.7300 496.8502 496.9705 497.0907 497.2109 497.3311 497.4513 497.5714 497.6915 497.8117 497.9318 498.0518 498.1719 498.2920 498.4120 498.5320 498.6520 498.7720 498.8920 499.0119 499.1319 499.2518 499.3717 499.4916 499.6114 499.7313 499.8511 499.9709 500.0907 500.2105 500.3303 500.4500 500.5698 500.6895 500.8092 500.9289 501.0485 501.1682 501.2878 501.4074 501.5270 501.6466 501.7662 501.8857 502.0052 502.1248 502.2443 502.3637 502.4832 502.6026 502.7221 502.8415 502.9609 503.0803 503.1996 503.3190 503.4383 503.5576 503.6769 503.7962 503.9154 504.0347 504.1539 504.2731 504.3923 504.5115 504.6306 504.7498 504.8689 504.9880 505.1071 505.2262 505.3452 505.4643 505.5833 505.7023 505.8213 505.9402 506.0592 506.1781 506.2971 506.4160 506.5348 506.6537 506.7726 506.8914 507.0102 507.1290 507.2478 507.3666 507.4853 507.6041 507.7228 507.8415 507.9602 508.0788 508.1975 508.3161 508.4347 508.5533 508.6719 508.7904 508.9090 509.0275 509.1460 509.2645 509.3830 509.5015 509.6199 509.7383 509.8567 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181224T125949.0Z 6932.541539 302 1 32.01 2 89.79 123.92 75.73 284.25 0.00 1 0.00 1 0 22 8.388e-02 8.139e-02 1.233e-01 1.193e-01 6.150493e+02 7.195138e+03 3.920565e+02 -6.000000e+00 4.593837e+03 272.40 -2.00 20.00 -2.00 505.25 0.00e+00 -5.820328e-04 3.232627e-03 5.345862e-05 -6.000000e+00 2.317547e-03 272.40 -2.00 20.00 -2.00 499.69 0.00e+00 2.994153e+00 2.502202e+00 8.001517e-02 -6.000000e+00 1.676530e+00 222.42 -2.00 3.58 -2.00 501.39 0.00e+00 20.460 0.168 489.00 513.00 1 1.0096e+01 1.9216e-01 3.7115e-02 -6.0000e+00 1.2846e-01 1.4992e-01 4.8383e-02 2.2244e-03 -6.0000e+00 3.2872e-02 3.8610e-06 4.1151e-03 1.2443e-02 6.6339e-05 -6.0000e+00 9.2381e-03 -2.5346e-02 1.1009e-04 12 8 8 10 0 0 -238.66 19.82 9.89 -0.02535 0.00320 8 2 1 4 0 4000.000 24.65 15.00 19.82 -5934 8690 -3090 -741 7164 -4488 -13580 2916 2131 13043 -8446 -694 -3741 7594 3509 -4379 -1395 -4721 11405 -4055 -1985 -2559 4453 -846 -9325 60 1747 9413 -5669 15246 -8718 2555 3326 -2821 -4157 6260 4223 -8289 8517 2494 9818 10981 17193 -2392 4602 -128 8221 -1349 -12332 -210 -3937 1235 -11939 128 -3196 16876 -1149 2404 5112 1438 15696 1358 19816 -9250 3659 -10768 -10915 -17827 10469 6214 3414 10128 -1572 -1534 -14229 6824 -256 9590 7323 -10822 4795 13584 7008 -812 10667 -1083 -2528 -8448 11850 3315 -14015 7688 14573 11854 5438 7751 -5297 6289 -8301 6177 10916 -9671 9100 -19778 4237 -740 20326 -6350 3621 2672 -126 -598 711 2639 -1972 7485 -7101 -1345 -2065 -1596 529 -7708 -370 -1216 10647 -3419 14985 -16031 9435 -9229 11608 6312 7914 16589 -11211 -1244 -406 1505 -5829 15146 -12037 11455 -3571 -1432 8557 -4621 -45 -266 7468 -13991 3307 -6298 8050 -3307 -800 7345 -5288 -17832 3278 2415 13138 -10407 -780 -4273 7649 3661 -4963 -1556 -5563 11694 -4924 -2375 -3084 5006 -1005 -12077 71 2011 9905 -6782 14398 -10271 2689 3530 -3273 -5010 6869 4709 -10362 8886 2736 9979 11061 16391 -2797 5050 -147 8650 -1541 -15417 -227 -4284 1244 -13529 129 -3392 15026 -1250 2551 5287 1539 14541 1454 17644 -10197 3785 -11780 -11759 -20248 9510 5812 3254 9018 -1471 -1448 -15330 5927 -235 7849 6055 -10665 4044 10550 5853 -739 8730 -1004 -2385 -8466 9699 2963 -14983 6677 11927 9999 4860 6668 -5087 5252 -7834 4953 8296 -9127 7296 -21803 3751 -692 15278 -6151 3145 2343 -114 -554 659 2425 -1911 6626 -7294 -1303 -2001 -1520 486 -7596 -337 -1118 8714 -3226 11764 -17137 7801 -9172 9306 5271 6411 12192 -10861 -1101 -363 1345 -5696 12143 -12767 9662 -3519 -1387 7504 -4593 -42 -244 6237 -14372 2873 SO 20181224T130406.0Z 6932.544514 306 1 32.01 2 89.16 124.67 76.44 284.91 0.00 1 0.00 1 0 15 1.104e-01 1.012e-01 9.954e-02 9.491e-02 -2.177910e+03 5.888933e+03 2.278900e+02 -6.000000e+00 6.047882e+03 272.40 -2.00 20.00 -2.00 505.31 0.00e+00 1.210277e-03 2.595305e-03 7.121363e-05 -6.000000e+00 3.054805e-03 272.40 -2.00 20.00 -2.00 499.64 0.00e+00 6.375076e+00 2.027736e+00 1.011669e-01 -6.000000e+00 2.222680e+00 222.42 -2.00 3.58 -2.00 501.35 0.00e+00 19.256 0.140 489.00 513.00 1 9.7532e+00 1.5509e-01 3.3817e-02 -6.0000e+00 1.7004e-01 6.7813e-02 3.9248e-02 2.3235e-03 -6.0000e+00 4.4013e-02 4.8693e-06 1.2785e-03 9.8097e-03 5.7988e-05 -6.0000e+00 1.2223e-02 -1.5231e-02 3.8342e-04 12 9 8 11 8 0 -133.58 19.87 -1.32 -0.01523 -0.00636 8 2 1 4 0 4000.000 24.75 15.00 19.87 6050 -8904 3742 3715 -5043 3920 -5421 15260 -12214 15752 -16510 13003 6578 -6059 1227 1910 13465 -6045 11948 -10770 18698 -4098 2456 -2880 2433 222 -428 11765 -12488 5103 -5461 16915 -7298 -1580 2075 -146 4317 -8089 12211 -8651 14806 -12120 11239 -1496 6458 486 -3151 7988 -8855 3176 -10957 5366 1826 5912 -9315 -141 11397 -9319 5465 -4020 16872 -10464 17759 -7580 5764 -5962 5687 9209 -1722 1876 -14049 16639 -12027 13100 -61 4161 -5948 -133 10709 -6050 18463 -7178 25978 -4478 30599 -949 10933 -2574 -3387 11251 -8801 17998 -8175 9879 -4224 13950 -3102 4217 3717 -3532 14386 1583 12500 -19137 5413 -4422 2948 -2760 6606 5275 -5574 13312 -18755 24570 -3001 15917 -7755 8300 -5204 8833 -6793 -10625 12638 -19692 9838 -5371 -3583 -11332 20252 -13628 2558 5836 83 34299 -14385 23022 -16969 16694 -5186 4024 2296 -4951 7781 -6731 25071 1796 15862 -11051 13333 -4325 900000 5677 -9861 3765 3863 -5884 4275 -6599 15223 -16004 15448 -22053 12751 6785 -7017 1317 2051 13090 -7307 12323 -14113 18336 -5058 2845 -3531 2839 264 -510 12234 -16153 5393 -6325 15730 -8823 -1856 2403 -174 4891 -10257 12491 -10824 14645 -15779 11687 -1784 7153 571 -3809 8508 -10929 3383 -13061 5307 1852 5798 -9961 -154 11273 -10471 5775 -4268 15833 -11839 16515 -8282 5450 -6238 5200 7993 -1641 1701 -14807 14067 -12489 10659 -57 3676 -5716 -118 8465 -5627 13449 -6787 17716 -4164 20155 -860 8812 -2374 -3150 9068 -8730 13808 -8236 8345 -4092 11135 -2885 3562 3082 -3093 10479 1325 9590 -20614 4614 -4147 2536 -2481 5376 4374 -5227 10522 -20783 17898 -2907 12828 -7933 7204 -5121 7461 -6633 -10704 10088 -21822 8157 -5202 -3415 -11680 15223 -14362 2279 4975 74 21530 -14715 16413 -18410 13195 -5185 3710 2171 -5064 7055 -7094 19234 1725 13030 -11647 10849 -4190 900000 SO 20181224T130814.0Z 6932.547384 310 1 32.01 2 88.55 125.40 77.14 285.55 0.00 1 0.00 1 0 15 5.409e-02 5.244e-02 8.250e-02 8.049e-02 4.359861e+03 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